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1H NMR signals for the equatorial and axial protons of the methylene bridges as well resolved doublets at σ ∼3 and σ ∼4, respectively. Moreover, the signals for the carbon atoms of the methylene groups connecting two adjacents phenyl rings in a syn orientation (e.g. in the cone conformation) appear at σ ∼31.
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The n -propylation of the lower rim hydroxy groups inhibits the oxygen-through-the-annulus-rotation and allows the isolation of the blocked cone conformational isomer. See
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