Iridium-catalyzed anti -diastereo- and enantioselective carbonyl (Trimethylsilyl)allylation from the alcohol or aldehyde oxidation level

Journal of the American Chemical Society

Volumn 132, Issue 26, 2010, Pages 9153-9156

  Han, Soo Bong ^a   Gao, Xin ^a   Krische, Michael J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2-PROPANOL; [CARBONYL; ALCOHOL OXIDATION; ALLYL ACETATE; ALLYLATIONS; ALLYLIC ALCOHOL; ALLYLIC TRANSPOSITION; DESILYLATION; DIASTEREO-SELECTIVITY; ENANTIOSELECTIVE; ISOLATED YIELD; NITROBENZOIC ACIDS; OXIDATION LEVEL; PRECATALYSTS; REACTION CONDITIONS; SEGPHOS; SYNTHETIC UTILITY; TRANSFER HYDROGENATIONS; TRIMETHYLSILYL;

ALDEHYDES; CARBONYLATION; CARBOXYLIC ACIDS; ENANTIOSELECTIVITY; OXIDATION; STEREOSELECTIVITY;

IRIDIUM;

2 PROPANOL; ACETIC ACID DERIVATIVE; ALCOHOL DERIVATIVE; ALDEHYDE DERIVATIVE; ALLYL COMPOUND; CARBONYL DERIVATIVE; ETHYLENE OXIDE DERIVATIVE; IRIDIUM; ISOCYANIC ACID DERIVATIVE; NITROBENZOIC ACID DERIVATIVE; TRIMETHYLSILYL DERIVATIVE; ALDEHYDE; ALLYL ACETATE; SILICON;

ALLYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CYCLOADDITION; DESILYLATION; DIASTEREOISOMER; ENANTIOSELECTIVITY; HYDROGENATION; ISOLATION PROCEDURE; OXIDATION; STEREOCHEMISTRY; SYNTHESIS; CHEMISTRY; ENZYME SPECIFICITY; OXIDATION REDUCTION REACTION; STEREOISOMERISM;

ACETATES; ALCOHOLS; ALDEHYDES; ALLYL COMPOUNDS; CATALYSIS; IRIDIUM; NITROBENZOATES; OXIDATION-REDUCTION; SILICON; STEREOISOMERISM; SUBSTRATE SPECIFICITY; TRIMETHYLSILYL COMPOUNDS;

EID: 77954263506     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja103299f     Document Type: Article

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