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Conjugated copolymers containing phosphole units have been reported by several groups. For example, see
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Very few attempts were reported for cross coupling of α-halophospholes.
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2-Stannylphosphole was previously reported
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2-Stannylphosphole was previously reported.
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Pd-catalyzed homocoupling of stannylarenes was reported previously. For example, see
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Pd-catalyzed homocoupling of stannylarenes was reported previously. For example, see
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77953001218
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note
-
Density functional theory (DFT) calculations (B3LYP/6-31G*) on 7 showed that there was little difference in free energies between the respective diastereomers. For details, see the Supporting Information.
-
-
-
-
48
-
-
77953008537
-
-
note
-
In this polymerization, a small amount of 3 (5 mol % per 4b) was added as an end-cap unit for the purpose of controlling the molecular weight.
-
-
-
-
49
-
-
77953005788
-
-
note
-
Attempts to prepare 9 by the homocoupling of 4b resulted in failure probably due to its inefficiency compared to the heterocoupling of 4b / 6b.
-
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