Modified cerium(IV)-based antioxidant capacity (CERAC) assay with selectivity over citric acid and simple sugars

Journal of Food Composition and Analysis

Volumn 23, Issue 3, 2010, Pages 282-288

  Ozyurt, Dilek ^a   Demirata, Birsen ^a   Apak, Resat ^b  

^a ISTANBUL TECHNICAL UNIVERSITY   (Turkey)

^b ISTANBUL UNIVERSITY   (Turkey)

Author keywords

Antioxidant capacity assay; CERAC; Cerium; Citric acid; Food analysis; Food composition; Oxidation potential; Sodium sulphate; Spectrophotometry; Sulphuric acid

Indexed keywords

EID: 77950296640     PISSN: 08891575     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jfca.2009.09.005     Document Type: Article

References (25)

1. Aly F.A., Alarfaj N.A., and Alwarthan A.A. Flow-injection chemiluminometric analysis of some benzamides by their sensitizing effect on the cerium-sulphite reaction. Talanta 54 (2001) 715-725
2. Apak R., Güçlü K., Özyürek M., and Karademir S.E. A Novel total antioxidant capacity index for dietary polyphenols, vitamins C and E, using their cupric ion reducing capability in the presence of neocuproine: CUPRAC method. Journal of Agricultural and Food Chemistry 52 (2004) 7970-7981
3. Apak R., Güclü K., Ozyurek M., Karademir S.E., and Altun M. Total antioxidant capacity assay of human serum using copper(II)-neocuproine as chromogenic oxidant: The CUPRAC method. Free Radical Research 39 (2005) 949-961
4. Apak R., Güçlü K., Demirata B., Özyürek M., Çelik S.E., Bektaşoǧlu B., Berker K.I., and Ozyurt D. Comparative evaluation of various total antioxidant capacity assays applied to phenolic compounds with the CUPRAC assay. Molecules 12 (2007) 1496-1547
5. Benzie I.F.F., and Szeto Y.T. Total antioxidant capacity of teas by the ferric reducing/antioxidant power assay. Journal of Agricultural and Food Chemistry 47 (1999) 633-636
6. Blasco A.J., Rogerio M.C., Gonzales M.C., and Escarpa A. Electrochemical index" as a screening method to determine "total polyphenolics" in foods: a proposal. Analytica Chimica Acta 539 (2005) 237-244
7. Blasco A.J., Crevillen A.G., Gonzalez M.C., and Escarpa A. Direct electrochemical sensing and detection of natural antioxidants and antioxidant capacity in vitro systems. Electroanalysis 19 22 (2007) 2275-2286
8. Bompadre S., Leone L., Politi A., and Battino M. Improved FIA-ABTS method for antioxidant determination in different biological samples. Free Radical Research 38 8 (2004) 831-838
9. Cho L.Y., Madurro J.M., and Romero J.R. Electrooxidation of β-dicarbonyl compounds using ceric methanesulfonate as mediator: some kinetics and spectroscopic studies. Journal of Catalysis 186 (1999) 31-35
10. Colucci J., Montalvo V., Hernandez R., and Poullet C. Electrochemical oxidation potential of photocatalyst reducing agents. Electrochimica Acta 44 (1999) 2507-2514
11. Czappa, D.J., 1974. The Role of Acid in the Cerium(IV) Oxidation of Carbohydrates. PhD Thesis. The Institute of Paper Chemistry, Appleton, Wisconsin.
12. Fang B., Iwasa S., Wei Y., Arai T., and Kumagai M. A study of the Ce(III)/Ce(IV) redox couple for redox flow battery application. Electrochim Acta 47 (2002) 3971-3976
13. Gülçin I., Küfrevioǧlu I., Oktay M., and Büyükokuroǧlu M.E. Antioxidant, antimicrobial, antiulcer and analgesic activities of nettle (Urtica diocia L.). Journal of Ethnopharmacology 90 (2004) 205-215
14. Halliwell B., and Gutteridge J.M.C. Free Radicals in Biology and Medicine (1989), Oxford University Press, Oxford
15. Llesuy S., Evelson P., Campos A.M., and Lissi E. Methodologies for evaluation of total antioxidant activities in complex mixtures: a critical review. Biological Research 34 (2001) 51-73
16. Magalhães L.M., Segundo M.A., Reis S., and Lima J.L.F.C. Automatic method for determination of total antioxidant capacity using 2.2-diphenyl-1-picrylhydrazyl assay. Analytica Chimica Acta 558 (2006) 310-318
17. Miller N.J., Rice-Evans C.A., Davies M.J., Gopinathan V., and Milner A. A novel method for measuring antioxidant capacity and its application to monitoring the antioxidant status in premature neonates. Clinical Science 84 (1993) 407-412
18. Ozyurt D., Demirata B., and Apak R. Determination of total antioxidant capacity by a new spectrophotometric method based on Ce(IV) reducing capacity measurement. Talanta 71 (2007) 1155-1165
19. Pizzocaro F., Torreggiani D., and Gilardi G. Inhibition of apple polyphenol oxidase (PPO) by ascorbic acid, citric acid and sodium chloride. Journal of Food Processing and Preservation 17 (1993) 21-30
20. Prior R.L., Hoang H., Gu L., Wu X., Bacchiocca M., Howard L., Hampsch-Woodill M., Huang D., Ou B., and Jacob R. Assays for hydrophilic and lipophilic antioxidant capacity (oxygen radical absorbance capacity (ORAC)) of plasma and other biological and food samples. Journal of Agricultural and Food Chemistry 51 (2003) 3273-3279
21. Qu B., Huang D., Hampsch-Woodill M., Flanagan J.A., and Deemer E.K. Analysis of antioxidant activities of common vegetables employing oxygen radical absorbance capacity (ORAC) and ferric reducing antioxidant power (FRAP) assays: a comparative study. Journal of Agricultural and Food Chemistry 50 (2002) 3122-3128
22. Re R., Pellegrini N., Proteggente A., Pannala A., Yang M., and Rice-Evans C. Antioxidant activity applying an improved ABTS radical cation decolorization assay. Free Radical Biology and Medicine 26 (1999) 1231-1237
23. Rice-Evans C.A., Miller N.J., and Paganga G. Structure-antioxidant activity relationships of flavonoids and phenolic acids. Free Radical Biology and Medicine 20 (1996) 933-956
24. Sun T., and Tanumihardjo S.A. An integrated approach to evaluate food antioxidant capacity. Journal of Food Science 72 9 (2007) 159-165
25. Yang B., Kotani A., Aral K., and Kusu F. Estimation of the antioxidant activities of flavonoids from their oxidation potentials. Analytical Sciences 17 (2001) 599-604