Synthesis and structures of cis- and trans-[Os(Bcat)(aryl)(CO)2(PPh3)2]: Compounds of relevance to the metal-catalyzed hydroboration reaction and the metal-mediated borylation of arenes

Angewandte Chemie - International Edition

Volumn 38, Issue 8, 1999, Pages 1110-1113

  Rickard, Clifton E F ^a   Roper, Warren R ^a   Williamson, Alex ^a   Wright, L James ^a  

^a UNIVERSITY OF AUCKLAND   (New Zealand)

Author keywords

B ligands; Boron; Hydroborations; Osmium

Indexed keywords

BORON DERIVATIVE; OSMIUM;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; SYNTHESIS;

EID: 0033583490     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1110::AID-ANIE1110>3.0.CO;2-L     Document Type: Article

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16. 2 = 0.1640 for all data. Programs used: SHELXS-97 (structure solution) and SHELXL-97 (structure refinement). Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-104125 (3) and CCDC-104126 (7a). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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