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It is known that an isolated tetramer of guanine complexed with the metal center is not thermodynamically stable in solution, thus octameric or larger G4-based stacks intercalated by cations are typically formed. In STM imaging at the solid, liquid interface, it is very difficult to perform a tomography of a molecular assembly in order to unambiguously determine, in our case, if the observed packing in Figure 1b corresponds to a single layer or double-decker i.e, octamer
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4-based stacks intercalated by cations are typically formed. In STM imaging at the solid - liquid interface, it is very difficult to perform a "tomography" of a molecular assembly in order to unambiguously determine, in our case, if the observed packing in Figure 1b corresponds to a single layer or double-decker (i.e., octamer).
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If different areas are occupied by single molecules of the reactant and product that self-assemble at the solid, liquid interface in a reaction or switching process, the total number of molecules at the surface will changed, thus requiring the occurrence of a desorption and/or re-adsorption process. However, STM imaging at the solid, liquid interface cannot offer realtime monitoring of the reaction process in its intermediate states, thus the occurrence of the reaction at the surface or through a desorption/re-adsorption process cannot be unambiguously determined
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If different areas are occupied by single molecules of the reactant and product that self-assemble at the solid - liquid interface in a reaction or switching process, the total number of molecules at the surface will changed, thus requiring the occurrence of a desorption and/or re-adsorption process. However, STM imaging at the solid - liquid interface cannot offer realtime monitoring of the reaction process in its intermediate states, thus the occurrence of the reaction at the surface or through a desorption/re-adsorption process cannot be unambiguously determined.
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