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Volumn 49, Issue 5, 2010, Pages 2471-2478

Epoxidation of alkenes with hydrogen peroxide catalyzed by selenium-containing dinuclear peroxotungstate and kinetic, spectroscopic, and theoretical investigation of the mechanism

Author keywords

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Indexed keywords


EID: 77649130237     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic902381b     Document Type: Article
Times cited : (60)

References (102)
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    • note
    • 2, specific solvents and ligands, and microwave is required.
  • 91
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    • 4, suggesting that the Lewis acidity of W atoms has an important role for epoxidation.
    • 4, suggesting that the Lewis acidity of W atoms has an important role for epoxidation.
  • 98
    • 77649162019 scopus 로고    scopus 로고
    • note
    • 77Se NMR signal at 1046 ppm was not observed. All of these kinetic and NMR results suggest that epoxidation with II leads to irreversible catalyst inactivation.
  • 99
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    • note
    • -1. The kinetics and activation parameters with la were almost the same as those with 3a, suggesting that the mechanism, of epoxidation of la is the same as that of 3a.


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