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35948996233
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To avoid irreproducible results often obtained with commercial ILs of unknown purity, the solvents were synthesized and purified following the procedure indicated in the Supporting Information
-
To avoid irreproducible results often obtained with commercial ILs of unknown purity, the solvents were synthesized and purified following the procedure indicated in the Supporting Information.
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33
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35949000537
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-] at T = 50°C) slower reaction rates were generally observed, leading to cyclooctene epoxide (99%) after 18 h and to 1,2-epoxyoctane (51%) after 66 h (compare with data in Table 2).
-
-] at T = 50°C) slower reaction rates were generally observed, leading to cyclooctene epoxide (99%) after 18 h and to 1,2-epoxyoctane (51%) after 66 h (compare with data in Table 2).
-
-
-
-
34
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35948999329
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2 is soluble in all hydrophilic ILs, while a highly dispersed emulsion is formed within hydrophobic ILs.
-
2 is soluble in all hydrophilic ILs, while a highly dispersed emulsion is formed within hydrophobic ILs.
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35
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35948994638
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2 in the form of urea complex (UHP) was not fully soluble in the IL-phase.
-
2 in the form of urea complex (UHP) was not fully soluble in the IL-phase.
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38
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9644307998
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Protonation equilibria and the extent of ion-pair association are known to influence POMs reactivity and their physical-chemical properties, a Musaev, D. G, Morokuma, K, Geletii, Y. V, Hill, C. L. Inorg. Chem. 2004, 43, 7702-7708
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35948990501
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At long reaction time, H2O2 decomposition becomes a competing process
-
2 decomposition becomes a competing process.
-
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41
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33746304454
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Evolution of 1 to dimeric complexes has been reported to occur in nonaqueous environment. Yoshida, A.; Yoshimura, M.; Uehara, K.; Hikichi, S.; Mizuno, N. Angew. Chem., Int. Ed. 2006, 45, 1956-1960.
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In the absence of simultaneous cooling, the yield of epoxide was negligible
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In the absence of simultaneous cooling, the yield of epoxide was negligible.
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2 competes with catalytic epoxidation, so both the presence of a layered substrate phase and a higher catalyst loading are instrumental for higher epoxide yields.
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2 competes with catalytic epoxidation, so both the presence of a layered substrate phase and a higher catalyst loading are instrumental for higher epoxide yields.
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