Highly efficient utilization of hydrogen peroxide for selective oxygenation of alkanes catalyzed by diiron-substituted polyoxometalate precursor

Journal of the American Chemical Society

Volumn 120, Issue 36, 1998, Pages 9267-9272

  Mizuno, Noritaka ^a   Nozaki, Chika ^a   Kiyoto, Ikuro ^a   Misono, Makoto ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; HYDROGEN PEROXIDE; IRON; POLYOXOMETALATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; OXYGENATION;

EID: 0032538023     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja980006c     Document Type: Article

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60. In the present paper, it is not intended to report a detailed analysis of the exact reaction mechanism of the oxygenation process. The additional kinetic, mechanistic, and inhibitor studies are in progress and will be reported in due course.
61. The oxygenation of cyclohexane was carried out under the following conditions: hydrogen peroxide, 1 mmol; cyclohexane, 2 mmol; I, 8 μmol; acetonitrile, 6 mL; reaction temperature, 356 K. The conversion and the efficiency of hydrogen peroxide for the first run (24 h) were 34% and 96%, respectively.