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Volumn 352, Issue 2-3, 2010, Pages 231-242

Regioselective reactions on a chiral substrate controlled by the configuration of a chiral catalyst

Author keywords

Asymmetric catalysis; Match mismatch; Regiodivergence; Regioselectivity; Site selection; Steroids

Indexed keywords


EID: 77149133688     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.200900822     Document Type: Review
Times cited : (53)

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    • [11] For example, multi-step total syntheses of natural products are commonly qualified as enantioselective because the final product has been synthesized as a single enantiomer. The expression enantioselectivity will be used in the present article when meaning that an achiral starting material is transformed in one step into an enantioenriched product. Often a given reaction involves several consecutive steps and one is stereodeterminating. We will not use the word selection in a mechanistic discussion but only when comparing the starting material to the product (see some examples in Scheme 1).
    • [11] For example, multi-step total syntheses of natural products are commonly qualified as enantioselective because the final product has been synthesized as a single enantiomer. The expression " enantioselectivity" will be used in the present article when meaning that an achiral starting material is transformed in one step into an enantioenriched product. Often a given reaction involves several consecutive steps and one is stereodeterminating. We will not use the word "selection" in a mechanistic discussion but only when comparing the starting material to the product (see some examples in Scheme 1).
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    • The oxidation of enantiomeric aryl-substituted allylic alcohols by iodosyl benzene catalyzed by a chiral Fe-(III) porphyrin complex has been described.[54] There is a competition between the C=C epoxidation and the allylic oxidation into enone. The chemoselectivity is slightly different according to the absolute configuration of the substrate
    • [54] There is a competition between the C=C epoxidation and the allylic oxidation into enone. The chemoselectivity is slightly different according to the absolute configuration of the substrate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.