-
1
-
-
77149167053
-
Asymmetric Organic Reactions
-
Ed, J. D. Morrison, Academic Press, New York
-
Asymmetric Organic Reactions, Vol. 5, Catalysis, (Ed.: J. D. Morrison), Academic Press, New York, 1985.
-
(1985)
Catalysis
, vol.5
-
-
-
4
-
-
0003445429
-
-
Vols. I-III, Eds, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer, Heidelberg, New York
-
Comprehensive Asymmetric Catalysis, Vols. I-III, (Eds.: E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Heidelberg, New York, 1999.
-
(1999)
Comprehensive Asymmetric Catalysis
-
-
-
5
-
-
0004069938
-
-
Eds, Y. Izumi, A. Tai, Kodansha, Tokyo and Academic Press, New York
-
Stereo-Differentiating Reactions, (Eds.: Y. Izumi, A. Tai), Kodansha, Tokyo and Academic Press, New York, 1977.
-
(1977)
Stereo-Differentiating Reactions
-
-
-
6
-
-
85050296727
-
-
Eds, N. L. Allinger, E. L. Eliel, Wiley, New York
-
H. B. Kagan, J. C. Fiaud, in: Topics in Stereochemistry, (Eds.: N. L. Allinger, E. L. Eliel), Wiley, New York, 1988; Vol. 18, pp 249-330.
-
(1988)
Topics in Stereochemistry
, vol.18
, pp. 249-330
-
-
Kagan, H.B.1
Fiaud, J.C.2
-
8
-
-
21344465658
-
-
Angew. Chem. Int. Ed. 2005, 44, 3974-4001.
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 3974-4001
-
-
-
10
-
-
0002178750
-
-
J. M. Keith, J. F. Larrow, E. N. Jacobsen, Adv. Synth. Catal. 2001, 343, 5-26.
-
(2001)
Adv. Synth. Catal
, vol.343
, pp. 5-26
-
-
Keith, J.M.1
Larrow, J.F.2
Jacobsen, E.N.3
-
11
-
-
77149162144
-
-
[11] For example, multi-step total syntheses of natural products are commonly qualified as enantioselective because the final product has been synthesized as a single enantiomer. The expression enantioselectivity will be used in the present article when meaning that an achiral starting material is transformed in one step into an enantioenriched product. Often a given reaction involves several consecutive steps and one is stereodeterminating. We will not use the word selection in a mechanistic discussion but only when comparing the starting material to the product (see some examples in Scheme 1).
-
[11] For example, multi-step total syntheses of natural products are commonly qualified as enantioselective because the final product has been synthesized as a single enantiomer. The expression " enantioselectivity" will be used in the present article when meaning that an achiral starting material is transformed in one step into an enantioenriched product. Often a given reaction involves several consecutive steps and one is stereodeterminating. We will not use the word "selection" in a mechanistic discussion but only when comparing the starting material to the product (see some examples in Scheme 1).
-
-
-
-
12
-
-
0036154455
-
-
For the misuse of stereochemical words see: a
-
For the misuse of stereochemical words see: a) K. Mislow, Chirality 2002, 14, 126-134;
-
(2002)
Chirality
, vol.14
, pp. 126-134
-
-
Mislow, K.1
-
13
-
-
0003942864
-
-
Wiley, New York
-
b) E. L. Eliel, S. H. Wilen, L. N. Mander, Stereochemistry of Organic Compounds, Wiley, New York, 1994.
-
(1994)
Stereochemistry of Organic Compounds
-
-
Eliel, E.L.1
Wilen, S.H.2
Mander, L.N.3
-
15
-
-
0001711008
-
-
S. El Baba, J. C. Poulin, H. B. Kagan, Tetrahedron 1984, 40, 4275-4284.
-
(1984)
Tetrahedron
, vol.40
, pp. 4275-4284
-
-
El Baba, S.1
Poulin, J.C.2
Kagan, H.B.3
-
16
-
-
0000321590
-
-
a) C. Bolm, G. Schlingloff, K. Weickhard, Angew. Chem. 1994, 106, 1944-1946;
-
(1994)
Angew. Chem
, vol.106
, pp. 1944-1946
-
-
Bolm, C.1
Schlingloff, G.2
Weickhard, K.3
-
19
-
-
0001158187
-
-
a) A. Gusso, C. Baccin, F. Pinna, G. Strukul, Organometallics 1994, 13, 3442-3451;
-
(1994)
Organometallics
, vol.13
, pp. 3442-3451
-
-
Gusso, A.1
Baccin, C.2
Pinna, F.3
Strukul, G.4
-
20
-
-
0001469331
-
-
b) G. Strukul, Angew. Chem. 1998, 110, 1256-1267;
-
(1998)
Angew. Chem
, vol.110
, pp. 1256-1267
-
-
Strukul, G.1
-
21
-
-
0001614716
-
-
Angew. Chem. Int. Ed. 1998, 37, 1199-1209.
-
(1998)
Angew. Chem. Int. Ed
, vol.37
, pp. 1199-1209
-
-
-
22
-
-
0037124439
-
-
A. Watanabe, T. Uchida, K. Ito, T. Katsuki, Tetrahedron Lett. 2002, 43, 4481-4485.
-
(2002)
Tetrahedron Lett
, vol.43
, pp. 4481-4485
-
-
Watanabe, A.1
Uchida, T.2
Ito, K.3
Katsuki, T.4
-
25
-
-
0001664728
-
-
T. Honda, N. Sano, K. Kanai, Heterocycles 1995, 41, 425-429.
-
(1995)
Heterocycles
, vol.41
, pp. 425-429
-
-
Honda, T.1
Sano, N.2
Kanai, K.3
-
26
-
-
0001649755
-
-
S. F. Martin, M. R. Spaller, S. Liras, B. Hartmann, J. Am. Chem. Soc. 1994, 116, 4493-4494.
-
(1994)
J. Am. Chem. Soc
, vol.116
, pp. 4493-4494
-
-
Martin, S.F.1
Spaller, M.R.2
Liras, S.3
Hartmann, B.4
-
27
-
-
0000738573
-
-
M. P. Doyle, A. B. Dyatkin, A. V. Kalinin, D. A. Ruppar, J. Am. Chem. Soc. 1995, 117, 11021-11022.
-
(1995)
J. Am. Chem. Soc
, vol.117
, pp. 11021-11022
-
-
Doyle, M.P.1
Dyatkin, A.B.2
Kalinin, A.V.3
Ruppar, D.A.4
-
29
-
-
0031592577
-
-
G. Dawson, C. A. Durrant, G. G. Kirk, R. J. Whitby, R. V. H. Jones, M. C. H. Standen, Tetrahedron Lett. 1997, 38, 2335-2338.
-
(1997)
Tetrahedron Lett
, vol.38
, pp. 2335-2338
-
-
Dawson, G.1
Durrant, C.A.2
Kirk, G.G.3
Whitby, R.J.4
Jones, R.V.H.5
Standen, M.C.H.6
-
30
-
-
0002050576
-
-
S. Masamune, W. Choy, J. S. Peterson, L. R. Sita, Angew. Chem. 1985, 97, 1-31;
-
(1985)
Angew. Chem
, vol.97
, pp. 1-31
-
-
Masamune, S.1
Choy, W.2
Peterson, J.S.3
Sita, L.R.4
-
33
-
-
0037012863
-
-
and references cited therein
-
D. L. Hughes, M. Palucki, N. Yasuda, R. A. Reamer, P. J. Reider, J. Org. Chem, 2002, 67, 2762-2768, and references cited therein.
-
(2002)
J. Org. Chem
, vol.67
, pp. 2762-2768
-
-
Hughes, D.L.1
Palucki, M.2
Yasuda, N.3
Reamer, R.A.4
Reider, P.J.5
-
35
-
-
0033790767
-
-
O. Loiseleur, M. C. Elliott, P. von Matt, A. Pfaltz, Helv. Chim. Acta 2000, 83, 2287-2294.
-
(2000)
Helv. Chim. Acta
, vol.83
, pp. 2287-2294
-
-
Loiseleur, O.1
Elliott, M.C.2
von Matt, P.3
Pfaltz, A.4
-
36
-
-
9344260830
-
-
H. Daimon, R. Ogawa, S. Itagaki, I. Shimizu, Chem. Lett. 2004, 33, 1222-1223.
-
(2004)
Chem. Lett
, vol.33
, pp. 1222-1223
-
-
Daimon, H.1
Ogawa, R.2
Itagaki, S.3
Shimizu, I.4
-
38
-
-
44349116637
-
-
O. Jacquet, J. Y. Legros, M. Coliboeuf, J.-C. Fiaud, Tetrahedron 2008, 64, 6530-6536.
-
(2008)
Tetrahedron
, vol.64
, pp. 6530-6536
-
-
Jacquet, O.1
Legros, J.Y.2
Coliboeuf, M.3
Fiaud, J.-C.4
-
39
-
-
62849108749
-
-
R. Webster, C. Böig, M. Lautens, J. Am. Chem. Soc. 2009, 131, 444-445.
-
(2009)
J. Am. Chem. Soc
, vol.131
, pp. 444-445
-
-
Webster, R.1
Böig, C.2
Lautens, M.3
-
40
-
-
77149131646
-
-
For examples of regiodivergent kinetic resolutions of allylic epoxides see refs.[34-36
-
[34-36]
-
-
-
-
41
-
-
21344466856
-
-
F. Bertozzi, P. Crotti, F. Macchia, M. Pineschi, B. L. Feringa, Angew. Chem. 2001, 113, 956-958;
-
(2001)
Angew. Chem
, vol.113
, pp. 956-958
-
-
Bertozzi, F.1
Crotti, P.2
Macchia, F.3
Pineschi, M.4
Feringa, B.L.5
-
42
-
-
0035793666
-
-
Angew. Chem. Int. Ed. 2001, 40, 930-932.
-
(2001)
Angew. Chem. Int. Ed
, vol.40
, pp. 930-932
-
-
-
43
-
-
1642332478
-
-
M. Pineschi, F. Del Moro, F. Crotti, V. Di Bussolo, F. Macchia, J. Org. Chem. 2004, 69, 2099-2105.
-
(2004)
J. Org. Chem
, vol.69
, pp. 2099-2105
-
-
Pineschi, M.1
Del Moro, F.2
Crotti, F.3
Di Bussolo, V.4
Macchia, F.5
-
46
-
-
33947647266
-
-
A. Gansuer, C.-A. Fan, F. Keller, J. Keil, J. Am. Chem. Soc. 2007, 129, 3484-3485.
-
(2007)
J. Am. Chem. Soc
, vol.129
, pp. 3484-3485
-
-
Gansuer, A.1
Fan, C.-A.2
Keller, F.3
Keil, J.4
-
47
-
-
0029833299
-
-
M. P. Doyle, A. V. Kalinin, D. G. Ene, J. Am. Chem. Soc. 1996, 118, 8837-8846.
-
(1996)
J. Am. Chem. Soc
, vol.118
, pp. 8837-8846
-
-
Doyle, M.P.1
Kalinin, A.V.2
Ene, D.G.3
-
48
-
-
0035977255
-
-
M. P. Doyle, S. B. Davies, E. J. May, J. Org. Chem. 2001, 66, 8112-8119.
-
(2001)
J. Org. Chem
, vol.66
, pp. 8112-8119
-
-
Doyle, M.P.1
Davies, S.B.2
May, E.J.3
-
50
-
-
34548348368
-
-
Angew. Chem. Int. Ed. 2007, 46, 6542-6544.
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 6542-6544
-
-
-
53
-
-
0028872072
-
-
S. Zhang, C. Girard, H. B. Kagan, Tetrahedron: Asymmetry 1995, 6, 2637-2640.
-
(1995)
Tetrahedron: Asymmetry
, vol.6
, pp. 2637-2640
-
-
Zhang, S.1
Girard, C.2
Kagan, H.B.3
-
54
-
-
0034846889
-
-
C. Bolm, I. Schiffers, C. L. Dinter, L. Defrère, A. Gerlach, C. Raabe, Synthesis 2001, 1719-1730.
-
(2001)
Synthesis
, pp. 1719-1730
-
-
Bolm, C.1
Schiffers, I.2
Dinter, C.L.3
Defrère, L.4
Gerlach, A.5
Raabe, C.6
-
55
-
-
0034693091
-
-
C. Bolm, I. Schiffers, C. L. Dinter, A. Gerlach, J. Org. Chem. 2000, 65, 6984-6991.
-
(2000)
J. Org. Chem
, vol.65
, pp. 6984-6991
-
-
Bolm, C.1
Schiffers, I.2
Dinter, C.L.3
Gerlach, A.4
-
56
-
-
33845374872
-
-
Y. Ishii, K. Osakada, T. Ikariya, M. Saburi, S. Yoshikawa, J. Org. Chem. 1986, 51, 2034-2039.
-
(1986)
J. Org. Chem
, vol.51
, pp. 2034-2039
-
-
Ishii, Y.1
Osakada, K.2
Ikariya, T.3
Saburi, M.4
Yoshikawa, S.5
-
57
-
-
0011249788
-
-
I. Iwasaki, T. Maki, W. Nakashima, O. Onomura, Y. Matsumura, Org. Lett. 1999, 1, 969-972.
-
(1999)
Org. Lett
, vol.1
, pp. 969-972
-
-
Iwasaki, I.1
Maki, T.2
Nakashima, W.3
Onomura, O.4
Matsumura, Y.5
-
58
-
-
33646461546
-
-
C. Mazet, S. Roseblade, V. Köhler, A. Pfaltz, Org. Lett. 2006, 8, 1879-1882.
-
(2006)
Org. Lett
, vol.8
, pp. 1879-1882
-
-
Mazet, C.1
Roseblade, S.2
Köhler, V.3
Pfaltz, A.4
-
60
-
-
33748581386
-
-
Angew. Chem. Int. Ed. 2006, 45, 5616-5619.
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 5616-5619
-
-
-
61
-
-
38049013578
-
-
Y. Zhao, A. W. Mitra, A. H. Hoveyda, M. L. Snapper, Angew. Chem. 2007, 119, 8623-8626;
-
(2007)
Angew. Chem
, vol.119
, pp. 8623-8626
-
-
Zhao, Y.1
Mitra, A.W.2
Hoveyda, A.H.3
Snapper, M.L.4
-
62
-
-
36148978554
-
-
Angew. Chem. Int. Ed. 2007, 46, 8471-8474.
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 8471-8474
-
-
-
64
-
-
0000425928
-
-
b) M. T. Reetz, Angew. Chem. 2002, 114, 1391-1394;
-
(2002)
Angew. Chem
, vol.114
, pp. 1391-1394
-
-
Reetz, M.T.1
-
65
-
-
0037090667
-
-
Angew. Chem. Int. Ed. 2002, 41, 1335-1338.
-
(2002)
Angew. Chem. Int. Ed
, vol.41
, pp. 1335-1338
-
-
-
66
-
-
0001753183
-
-
M. T. Reetz, M. H. Becker, H. W. Klein, D. Stöckigt, Angew. Chem. 1999, 111, 1872-1875;
-
(1999)
Angew. Chem
, vol.111
, pp. 1872-1875
-
-
Reetz, M.T.1
Becker, M.H.2
Klein, H.W.3
Stöckigt, D.4
-
67
-
-
0033553835
-
-
Angew. Chem. Int. Ed. 1999, 38, 1758-1761.
-
(1999)
Angew. Chem. Int. Ed
, vol.38
, pp. 1758-1761
-
-
-
68
-
-
77149149501
-
-
The oxidation of enantiomeric aryl-substituted allylic alcohols by iodosyl benzene catalyzed by a chiral Fe-(III) porphyrin complex has been described.[54] There is a competition between the C=C epoxidation and the allylic oxidation into enone. The chemoselectivity is slightly different according to the absolute configuration of the substrate
-
[54] There is a competition between the C=C epoxidation and the allylic oxidation into enone. The chemoselectivity is slightly different according to the absolute configuration of the substrate.
-
-
-
-
69
-
-
0035976095
-
-
W. Adam, S. Prikhodovski, K. J. Roschmann; C. R. Saha-Möller, Tetrahedron: Asymmetry 2001, 12, 2677-2681.
-
(2001)
Tetrahedron: Asymmetry
, vol.12
, pp. 2677-2681
-
-
Adam, W.1
Prikhodovski, S.2
Roschmann, K.J.3
Saha-Möller, C.R.4
-
70
-
-
72949121472
-
-
B. Wu, J. R. Parquette, T. V. RajanBabu, Science 2009, 326, 1662.
-
(2009)
Science
, vol.326
, pp. 1662
-
-
Wu, B.1
Parquette, J.R.2
RajanBabu, T.V.3
|