SCOPUS 정보 검색 플랫폼

Synlett

Volumn , Issue 3, 2007, Pages 435-438

Copper-catalyzed kinetic resolution of 1,3-cyclohexadiene monoepoxide with grignard reagents

(2) Millet, Renaud a Alexakis, Alexandre a

a UNIVERSITY OF GENEVA (Switzerland)

Author keywords

Asymmetric synthesis; Catalysis; Copper; Epoxides; Grignard reagents

Indexed keywords

1,3 CYXLOHEXADINE MONOEPOXIDE; COPPER; EPOXIDE; FERROCENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENANTIOSELECTIVITY; GAS CHROMATOGRAPHY; GRIGNARD REACTION; KINETICS; MASS SPECTROMETRY;

EID: 33847372041 PISSN: 09365214 EISSN: None Source Type: Journal
DOI: 10.1055/s-2007-967945 Document Type: Article

Times cited : (19)

References (16)

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14
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- 3, whereas MTBE has to be distilled over Na/benzophenone.
- 3, whereas MTBE has to be distilled over Na/benzophenone.

15
- 33847401863
- Typical Procedure: In a dried Schlenk tube under N2 atmosphere were placed CuBr (1.4 mg, 0.01 mmol) and (R,S)-L11 (7.0 mg, 0.011 mmol, Et2O was added (6 mL) and the mixture was stirred at r.t. for 20 min. The tube was cooled to -78°C and 1,3-cyclohexadiene monoepoxide (1; 100 μL, 1 mmol) was added. BuMgCl (250 μL, 2.0 M in Et2O, 0.5 mmol) was added dropwise over a period of 3 min. The reaction was stirred for 1 h and quenched with MeOH and (NH4) 2SO4 before being allowed to reach r.t. The aqueous phase was extracted with Et2O and the organic layers were dried over Na2SO4 and the solvent was removed on a rotary evaporator (45% conversion, 90% ee, The crude was poured in Ac2O (1 mL, 10 mmol) in the presence of Et3N (100 μL) and DMAP (a few mg, The mixture was stirred overnight at r.t. The reaction was quenched with MeOH 100
- 3, ee = 90%).

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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.