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Volumn 27, Issue 22, 2008, Pages 5737-5740

Synthesis and reactivity of iridium (III) dihydrido aminocarbenes

Author keywords

[No Author keywords available]

Indexed keywords

AMINOCARBENES; C-H ACTIVATIONS; IRIDIUM COMPLEXES; METHYL AMINES;

EID: 57049104605     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8009365     Document Type: Article
Times cited : (37)

References (49)
  • 3
    • 0000802181 scopus 로고
    • For leading references, see: a
    • For leading references, see: (a) Fischer, E. O. Pure Appl. Chem. 1970, 24, 407.
    • (1970) Pure Appl. Chem , vol.24 , pp. 407
    • Fischer, E.O.1
  • 8
    • 0003818422 scopus 로고
    • Seyferth, D, Ed, Verlag Chemie: Weinheim, Germany
    • (f) Transition Metal Carbene Complexes; Seyferth, D., Ed.; Verlag Chemie: Weinheim, Germany, 1983.
    • (1983) Transition Metal Carbene Complexes
  • 13
    • 1442360753 scopus 로고    scopus 로고
    • Grubbs, R. H, Ed, Wiley-VCH: Weinheim, Germany
    • (k) Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany, 2003.
    • (2003) Handbook of Metathesis
  • 14
    • 18744387806 scopus 로고    scopus 로고
    • Fischer Type Carbene Complexes
    • Beller, M, Bolm, C, Eds, Wiley-VCH: Weinheim, Germany
    • Doetz, K. H.; Minatti, A. Fischer Type Carbene Complexes. In Transition Metals for Organic Synthesis; Beller, M., Bolm, C., Eds.; Wiley-VCH: Weinheim, Germany, 2004; Vol. 2, pp 397-425.
    • (2004) Transition Metals for Organic Synthesis , vol.2 , pp. 397-425
    • Doetz, K.H.1    Minatti, A.2
  • 27
    • 57049099346 scopus 로고    scopus 로고
    • Although the formation of complexes 2 and 3 was quantitative, as judged by 31P and 1H NMR spectroscopy, the difficulty in crystallizing pure 2anti and 3 to remove norbornane and residual amine resulted in low isolated yields 35% and 13, respectively
    • anti and 3 to remove norbornane and residual amine resulted in low isolated yields (35% and 13%, respectively).
  • 32
    • 57049171538 scopus 로고    scopus 로고
    • 1H NMR chemical shifts for the methylene protons on the morpholine ring.
    • 1H NMR chemical shifts for the methylene protons on the morpholine ring.
  • 33
    • 0000227804 scopus 로고    scopus 로고
    • Representative examples: (a) Threlkel, R. S.; Bercaw, J. E. J. Am. Chem. Soc. 1981, 103, 2650.
    • Representative examples: (a) Threlkel, R. S.; Bercaw, J. E. J. Am. Chem. Soc. 1981, 103, 2650.
  • 43
    • 0000707521 scopus 로고    scopus 로고
    • CO insertion into metal-amide bonds: (a) Beers, O. C. P.; Delis, J. G. P.; Mul, W. P.; Vrieze, K.; Elsevier, C. J.; Smeets, W. J. J.; Spek, A. L. Inorg. Chem. 1993, 32, 3640.
    • CO insertion into metal-amide bonds: (a) Beers, O. C. P.; Delis, J. G. P.; Mul, W. P.; Vrieze, K.; Elsevier, C. J.; Smeets, W. J. J.; Spek, A. L. Inorg. Chem. 1993, 32, 3640.
  • 46
    • 57049134814 scopus 로고    scopus 로고
    • The related reversible insertion of CO into M-X bonds has been reported: (a) Saruyama, T.; Yamamoto, T.; Yamamoto, A. Bull. Chem. Soc. Jpn. 1976, 49, 546.
    • The related reversible insertion of CO into M-X bonds has been reported: (a) Saruyama, T.; Yamamoto, T.; Yamamoto, A. Bull. Chem. Soc. Jpn. 1976, 49, 546.
  • 48
    • 57049147038 scopus 로고    scopus 로고
    • Reference 12a
    • (c) Reference 12a.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.