Mechanistic investigation of intramolecular aminoalkene and aminoalkyne hydroamination/cyclization catalyzed by highly electrophilic, tetravalent constrained geometry 4d and 5f complexes. Evidence for an M-N σ-bonded insertive pathway

Journal of the American Chemical Society

Volumn 129, Issue 19, 2007, Pages 6149-6167

  Stubbert, Bryan D ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINATION; CATALYSTS; CYCLIZATION; NITROGEN COMPOUNDS; PHASE TRANSITIONS; ZIRCONIUM COMPOUNDS;

AMINOALKENE; AMINOALKYNE; HYDROAMINATION; TRANSITION STATE;

OLEFINS;

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; DEUTERIUM; LANTHANIDE;

AMINATION; ARTICLE; CATALYSIS; CYCLIZATION; DEAMINATION; ENZYME SUBSTRATE; GEOMETRY; MOLECULAR MECHANICS; RING CLOSING METATHESIS; SUBSTITUTION REACTION;

EID: 34249082758     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0675898     Document Type: Article

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