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For examples of metal catalyzed alkylation of benzylic C-H bonds, see:. Yasuda M., Somyo T., and Baba A. Angew. Chem., Int. Ed. 45 (2006) 793
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note
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The production of 3a in the absence of oxygen and NHPI suggest a diphenylmethane carbocation intermediate and subsequent attack by the iron enolate. This carbocation formation could be assisted by the Lewis acids in the mixture.
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57
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74049124570
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note
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5NNa: 426.1317; found: 426.1310.
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