Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

Inorganic Chemistry

Volumn 43, Issue 15, 2004, Pages 4558-4560

  Tachi, Yoshimitsu ^a   Aita, Kazuki ^a   Teramae, Shinichi ^b   Tani, Fumito ^c   Naruta, Yoshinori ^c   Fukuzumi, Shunichi ^b   Itoh, Shinobu ^a  

^a Osaka Prefecture University   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; LIGAND; OXYGEN; OXYGEN DERIVATIVE; PYRIDINE DERIVATIVE;

ARTICLE; BINDING SITE; CHEMICAL STRUCTURE; COMPLEX FORMATION; LOW TEMPERATURE; REACTION ANALYSIS; SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 3242772925     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049524g     Document Type: Article

References (34)

1. Itoh, S. In Comprehensive Coordination Chemistry II; Que, L., Jr., Tolman, W. B., Eds.; Elsevier: Amsterdam, 2004; Vol. 8, pp 369-393.
2. Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P. Chem. Rev. 2004, 104, 1013-1045.
3. Lewis, E. A.; Tolman, W. B. Chem. Rev. 2004, 104, 1047-1076.
4. Jacobson, R. R.; Tyeklar, Z.; Farooq, A.; Karlin, K. D.; Liu, S.; Zubieta, J. J. Am. Chem. Soc. 1988, 110, 3690-3692.
5. Komiyama, K.; Furutachi, H.; Nagatomo, S.; Hashimoto, A.; Hayashi, H.; Fujinami, S.; Suzuki, M.; Kitagawa, T. Bull. Chem. Soc. Jpn. 2004, 77, 59-72.
6. Bol, J. E.; Driessen, W. L.; Ho, R. Y. N.; Maase, B.; Que, L., Jr.; Reedijk, K. Angew. Chem., Int. Ed. 1997, 36, 998-1000
7. Schindler, S. Eur. J. Inorg. Chem. 2000, 2311-2326.
8. The structure of the active oxygen intermediate is largely altered by steric effects of the supporting ligands: (a) Hayashi, H.; Fujinami, S.; Nagatomo, S.; Ogo, S.; Suzuki, M.; Uehara, A.; Watanabe, Y.; Kitagawa, T. J. Am. Chem. Soc. 2000, 122, 2124-2125.
9. (b) Hayashi, H.; Uozumi, K.; Fujinami, S.; Nagatomo, S.; Shiren, K.; Furutachi, H.; Suzuki, M.; Uehara, A.; Kitagawa, T. Chem. Lett. 2002, 416-417.
10. Kitajima, N.; Fujisawa, K.; Moro-oka, Y. J. Am. Chem. Soc. 1989, 111, 8975-8976.
11. Lam, B. M. T.; Halfen, J. A.; Young, V. G., Jr.; Hagadorn, J. R.; Holland, P. L.; Lledós, A.; Cucurull-Sánchez, L.; Novoa, J. J.;, Alvarez, S.; Tolman, W. B. Inorg. Chem. 2000, 39, 4059-4072.
12. Kodera, M.; Katayama, K.; Tachi, Y.; Kano, K.; Hirota, S.; Fujinami, S.; Suzuki, M. J. Am. Chem. Soc. 1999, 121, 11006-11007.
13. Kodera, M.; Kajita, Y.; Tachi, Y.; Katayama, K.; Kano, K.; Hirota, S.; Fujinami, S.; Suzuki, M. Angew. Chem., Int. Ed. 2004, 43, 334-337.
14. Karlin, K. D.; Kaderli, S.; Zuberbühler, A. D. Acc. Chem. Res. 1997, 30, 139-147.
15. Itoh, S.; Fukuzumi, S. Bull. Chem. Soc. Jpn. 2002, 75, 2081-2095.
16. Depending on the ligands and reaction conditions (especially solvents and counteranions), O-O bond homolysis of the peroxo complex takes place to give bis(μ-oxo)dicopper(III) complexes: Que, L., Jr.; Tolman, W. B. Angew. Chem., Int. Ed. 2002, 41, 1114-1137.
17. The experimental details for the syntheses and the measurements are described in the Supporting Information.
18. Handbook on Metalloproteins; Bertini, I., Sigel, A., Sigel, H., Eds.; Marcel Dekker: New York, 2001.
19. For dicopper-dioxygen complexes with asymmetric coordination environments, see: (a) Nasir, M. S.; Karlin, K. D.; McGowty, D.; Zubieta, J. J. Am. Chem. Soc. 1991, 113, 698-700.
20. (b) Mahroof-Tahir, M.; Karlin, K. D. J. Am. Chem. Soc. 1992, 114, 7599-7601.
21. (c) Murthy, N. N.; Mahroof-Tahir, M.; Karlin, K. D. Inorg. Chem. 2001, 40, 628-635.
22. (d) Zhang, C. X.; Liang, H.-C.; Kim, E.; Gan, Q.-F.; Tyeklar, Z.: Lam, K.-C.; Rheingold, A. L.; Kaderli, S.; Zuberbühler, A. D.; Karlin, K. D. Chem. Commun. 2001, 631-632.
23. (e) Aboelella, N. W.; Lewis, E. A.; Reynolds, A. M.; Brennessel, W. W.; Cramer, C. J.; Tolman, W. B. J. Am. Chem. Soc. 2002, 124, 10660-10661.
24. (f) Teramae, S.; Osako, T.; Nagatomo, S.; Kitagawa, T.; Fukuzumi, S.; Itoh, S. J. Inorg. Biochem. 2004, 98, 746-757.
25. 2L are provided in the Supporting Information as a CIF file.
26. 2L and the related dicopper(I) complexes will be reported elsewhere.
27. -1. The biphasic kinetics indicates that the peroxo intermediate is formed via at least two steps, although the mechanistic details are not known at present.
28. Gavrilova, A. L.; Qin, C. J.; Sommer, R. D.; Rheingold, A. L.; Bosnich, B. J. Am. Chem. Soc. 2002, 124, 1714-1722.
29. Chishiro, T.; Shimazaki, Y.; Tani, F.; Tachi, Y.; Naruta, Y.; Karasawa, S.; Hayami, S.; Maeda, Y. Angew. Chem., Int. Ed. 2003, 42, 2788-2791.
30. Sucha, V.; Sivak, M.; Tyrselova, J.; Marek, J. Polyhedron 1997, 16, 2837-2842.
31. Bennett, M. J.; Donaldson, P. B. Inorg. Chem. 1977, 16, 1585-1589.
32. Miyaji, T.; Kujime, M.; Hikichi, S.; Moro-oka, Y.; Akita, M. Inorg. Chem. 2002, 41, 5286-5295.
33. Paul, P. P.; Tyeklar, Z.; Jacobson, R. R.; Karlin, K. D. J. Am. Chem. Soc. 1991, 113, 5322-5332.
34. 3P and phenols did not proceed with the (trans-μ-1,2-peroxo)dicopper(II) complex A.27