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Volumn 695, Issue 1, 2010, Pages 53-61

Tricarbonylrhenium(I) and manganese(I) complexes of 2-(pyrazolyl)-4-toluidine

Author keywords

Electrochemistry; Group 7 amidos; Group 7 metal tricarbonyls; IR spectroscopy; NMR spectroscopy

Indexed keywords

CENTROSYMMETRIC; DIMERIC SPECIES; ELECTROACTIVE; GROUP 7 AMIDOS; GROUP 7 METAL TRICARBONYLS; IONIC SPECIES; IR SPECTROSCOPY; METALLACYCLES; NMR SPECTROSCOPY; PYRAZOLYL; SINGLE CRYSTAL X-RAY DIFFRACTION; SOLID-STATE STRUCTURES;

EID: 70350757825     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.09.027     Document Type: Article
Times cited : (9)

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    • See Supporting information regarding pitfalls of another route.
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    • The electrochemical behavior of aniline derivatives relies on the availability of the lone pair of electrons on the NH2 moiety to be in conjugation with the aryl π-system rendering the aromatic molecule electron-rich. Upon binding to Lewis acids, the nitrogen becomes quartenary and its lone pair of electrons is less energetically accessible. As will be detailed elsewhere, the oxidation potentials of the protonated ligand [H2(pzAnMe, BF4) and even that of the cationic [Me2C(N,N-pzAnMe, BF4, with an sp2-hybridized amino nitrogen) occur above 2.3 V
    • 2-hybridized amino nitrogen) occur above 2.3 V.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.