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note
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The electronic spectra are complicated for these systems, with many chromophores in the visible region, thus the Stokes shift calculated are phenomenological.
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note
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These data pertain to solution-phase spectra, and some of the reorganization energy that leads to the Stokes shift will be reduced in the film phase because reorganization of the solvent cage will not be present. Thus, the band gaps will be smaller than estimated by our method. To obtain more accurate estimates of the band gaps is a topic of current investigation.
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