New octahedral rhenium(I) tricarbonyl amido complexes

Organometallics

Volumn 21, Issue 9, 2002, Pages 1966-1974

  Hevia, Eva ^a   Pérez, Julio ^a   Riera, Víctor ^a   Miguel, Daniel ^b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; NITROGEN; RHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

NUCLEOPHILICITY;

ORGANOMETALLICS;

EID: 0000307724     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0110383     Document Type: Article

References (48)

1. (a) Chisholm, M. H. Comprehensive Inorganic Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 2, pp 161-188.
2. (b) Bryndza, H. E.; Tam, W. Chem, Rev. 1988, 88, 1163-1188.
3. (c) Fryzuk, M. D.; Montgomery, C. D. Coord. Chem. Rev. 1989, 95, 1-40.
4. Re(I) amido complexes: (a) Dewey, M. A.; Arif, A. M.; Gladyez, J. A. J. Chem. Soc., Chem. Commun. 1991, 712-714.
5. (b) Dewey, M. A.; Knight, D. A.; Arif, A.; Gladysz, J. A. Chem. Ber. 1992, 125, 815-824.
6. (c) Dewey, M. A.; Stark, G. A.; Gladyaz, J. A. Organometallics 1996, 15, 4798-4807.
7. (d) Simpson R. D.; Bergman, R. G. Organometallics 1992, 11, 3980-3993.
8. Ru(II) amido complexes: (a) Bryndza, H. E.; Fong, L. K; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456.
9. (b) Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 2717-2719.
10. (c) Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. Organometallics 1991, 10, 1875-1887.
11. (d) Joslin, F. L.; Johnson, M. P.; Mague, J. T.; Roundhill, D. M. Organometallics 1991, 10, 2781-2794.
12. (e) Hsu, G. C.; Kosar, W. P.; Jones, W. D. Organometallics 1994, 13, 385-396.
13. (f) Kaplan, A. W.; Ritter, J. C. M.; Bergman, R. G. J. Am. Chem. Soc. 1998, 120, 6828-6829.
14. (g) Boncella, J. M.; Eve, T. M.; Rickman, B.; Abboud, K. A. Polyhedron 1998, 17, 725-736.
15. (h) Fulton, J. R.; Bouwkamp, M. W.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 8799-8800.
16. Jayaprakash, K. N.; Gunnoe, T. B.; Boyle, P. D. Inorg. Chem. 2001, 40, 6481-6486.
17. Os(II) amido complexes: Flood, T. C.; Lim, J. K.; Deming, M. A.; Keung, W. Organometallics 2000, 19, 1166-1174.
18. Ir(III) amido complexes: (a) Glueck, D. S.; Winalow, L. J. N.; Bergman, R. G. Organometallics 1991, 10, 1462-1479.
19. (b) Glueck, D. S.; Bergman, R. G. Organometallics 1991, 10, 1479-1486.
20. Woerpel, K. A.; Bergman, R. G. J. Am. Chem. Soc. 1993, 115, 7888-7889.
21. We are aware of only two exceptions; see refs 2a-c and 3i.
22. See for instance: (a) Stufkens, D. J.; Vlcek, A., Jr. Coord. Chem. Rev. 1998, 177, 127-179.
23. (b) Farrell, I. R.; Vlcek, A., Jr. Coord. Chem. Rev. 2000, 208, 87-101.
24. Striplin, D. R.; Crosby, G. A. Coord. Chem. Rev. 2001, 211, 163-175.
25. (a) Kutal, C.; Weber, M. A.; Ferraudi, G.; Geiger, D. Organometallics 1985, 4, 2161-2166.
26. (b) Sullivan, B. P.; Meyer, T. J. Organometallics 1986, 5, 1500-1505.
27. (c) Kutal, C.; Corbin, J.; Ferraudi, G. Organometallics 1987, 6, 553-557.
28. Scheiring, T.; Klein, A.; Kaim, W. J. Chem. Soc., Perkin Trans. 2 1997, 2569-2571.
29. Gibson, D. H.; Sleaad, B. A.; Yin, X.; Vij, A. Organometallics 1998, 17, 2689-2691.
30. Triflato complexes of this kind have been previously prepared. See for instance: Guerrero, J.; Pino, O. E.; Wolcan, E.; Feliz, M. R.; Ferraudi, G.; Moya, S. A. Organometallics 2001, 20, 2842-2853.
31. Klein, A.; Vogler, C.; Kaim, W. Organometallics 1996, 15, 236-244.
32. Martin, G. C.; Palenik, G. J.; Boncella, J. M. Inorg. Chem. 1990, 29. 2027-2030.
33. The chemical shift of N-H hydrogens of amido complexes has been reported to appear over a wide range of values; see for instance: (a) Powell, K. R.; Pérez, P. J.; Luan, L.; Feng, S. G. White, P. S.; Brookhart, M.; Templeton, J. L. Organometallics 1994, 13, 1851-1864
34. 2].
35. See ref 2d and: (a) Buhro, W. E.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107,3346-3348.
36. (b) Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1985, 24, 3507-3508.
37. Buhro, W. E.; Zwick, B. D.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 2427-2439, and references therein.
38. Holland, P. L.; Andersen, R. A.; Bergman, R. G. Comments Inorg. Chem. 1999, 21, 115-129.
39. Rossi, R.; Marchi, A.; Duatti, A.; Magon, L.; Casellato, U.; Graziani, E. Inorg. Chim. Acta 1988, 142, 23-25.
40. 1H NMR spectra of 4a are given as Supporting Information.
41. Albéniz, A. C.; Calle, V.; Espinet, P.; Gómez, S. Inorg. Chem. 2001, 40, 4211-4216.
42. Similar distances have been found in a search through the Cambridge Structural Database for three-center interactions between a nitrogen, a carbonyl ligand, and an ortho phenyl hydrogen; see, for instances: (a) Alonso, F. J. G.; Sanz, M. G.; Riera, V.; Abril, A. A.; Tiripicchio A.; Ugozzoli, U. Organometallics 1992, 11, 801-806.
43. (b) Gargulak, J. D.; Gladefelter, W. L. Inorg. Chem. 1994, 33, 253-257.
44. (c) Cook, J.; Davison, A.; Davis, W. M.; Jones, A. G. Organometallics 1995, 14, 650-654.
45. Coel, S. C.; Chiang, M. Y.; Rauscher, D. J.; Buhro W. E. J. Am. Chem. Soc. 1993, 115, 160-169.
46. SAINT+. SAX area detector integration program, Version 6.02; Bruker AXS, Inc.: Madison, WI, 1999.
47. Sheldrick, G. M. SHELXTL, An integrated system for solving, refining, and displaying crystal structures from diffraction data. Version 5.1; Bruker AXS, Inc.: Madison, WI, 1998.
48. Sheldrick, G. M. SADABS, Empirical Absorption Correction Program; University of Göttingen: G̈ttingen, Germany, 1997.