Pyrazole-tethered heteroditopic ligands and their transition metal complexes: Synthesis, structure, and reactivity

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2005, Pages 1254-1263

  Mukherjee, Anuradha ^a   Subramanyam, U ^b   Puranik, Vedavati G ^b   Mohandas, Thekke P ^b   Sarkar, Amitabha ^a  

^a DEPARTMENT OF MATERIALS SCIENCE   (India)

^b NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Cobalt; Copper; Hemilabile ligands; Nickel; Oligomerization; Pyrazole

Indexed keywords

CHELATION; COBALT COMPOUNDS; COPPER COMPOUNDS; ETHYLENE; METAL COMPLEXES; NICKEL COMPOUNDS; OLIGOMERIZATION; OLIGOMERS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

ACTIVE CATALYST; HEMILABILE LIGAND; N-DONOR LIGANDS; OLIGOMERIZATIONS; P-N LIGANDS; PHOSPHANE OXIDE; PHOSPHANES; PYRAZOLES; SYNTHESISED; TRANSITION-METAL COMPLEX;

LIGANDS;

2 (3 METHYL 5 PHENYLPYRAZOL 1 YL)PHENYLAMINE; 2 (3,5 DIMETHYLPYRAZOL 1 YL)PHENYLAMINE; 3 METHYL 1 (2 NITROPHENYL) 5 PHENYL 1H PYRAZOLE; 3,5 DIMETHYL 1 (2 NITROPHENYL) 1H PYRAZOLE; COBALT DERIVATIVE; COPPER; DIMETHYL [2 (3 METHYL 5 PHENYLPYRAZOL 1 YL)PHENYL]AMINE; ETHYLENE; LIGAND; METAL COMPLEX; NICKEL COMPLEX; PYRAZOLE DERIVATIVE; TRANSITION ELEMENT; UNCLASSIFIED DRUG; [2 (3,5 DIMETHYLPYRAZOL 1 YL)PHENYL]DIMETHYLAMINE;

ARTICLE; CATALYST; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTALLOGRAPHY; OLIGOMERIZATION; OXIDATION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 17644420002     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400818     Document Type: Article

References (54)

1. a) S. Trofimenko, J. Am. Chem. Soc. 1966, 88, 1842-1844;
2. b) S. Trofimenko, J. Am. Chem. Soc. 1967, 89, 3170-3177;
3. c) S. Trofimenko, J. Am. Chem. Soc. 1967, 89, 6288-6294.
4. a) S. Trofimenko, Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands, Imperial College Press, London, 1999;
5. b) S. Trofimenko, Chem. Rev. 1993, 93, 943-980.
6. a) V. S. Joshi, A. Sarkar, P. R. Rajamohanan, J. Organomet. Chem. 1991, 409, 341 and references cited therein;
7. b) V. S. Joshi, M. Nandi, H. Zhang, B. S. Haggerty, A. Sarkar, Inorg. Chem 1993, 32, 1301-1303;
8. c) T. C. Higgs, C. J. Carrano, Inorg. Chem. 1997, 36, 291-297;
9. d) T. C. Higgs, K. Spartalian, C. J. O'Connor, B. F. Matzanke, C. J. Carrano, Inorg. Chem. 1998, 37, 2263-2272;
10. e) S. Tsuji, D. C. Swenson, R. F. Jordan, Organometallics 1999, 18, 4758-4764.
11. a) S. D. Ittel, L. K. Johnson, M. Brookhart, Chem. Rev. 2000, 100, 1169-1203;
12. b) G. J. P. Britovsek, V. C. Gibson, D. F. Wass, Angew. Chem. Int. Ed. 1999, 38, 428-447.
13. a) R. F. Heck, J. P. Nolley, Jr., J. Org. Chem. 1972, 37, 2320;
14. b) R. F. Heck, Acc. Chem. Res. 1979, 12, 146-151;
15. c) R. F. Heck, Org. React. 1982, 27, 345-390;
16. d) A. de Meijere, F. E. Meyer, Angew. Chem. Int. Ed. Engl. 1994, 33, 2379-2411;
17. e) R. F. Heck, Palladium Reagents in Organic Synthesis Academic Press, London, 1985;
18. f) A. de Meijere, F. E. Meyer, Angew. Chem. 1994, 106, 2473-2506.
19. a) N. Miyaura, A. Sujuki, Chem. Rev. 1995, 95, 2457-2483;
20. b) A. Suzuki, J. Organomet. Chem. 1999, 576, 147-168.
21. F. Fache, E. Schulz, M. L. Tommasino, M. Lemaire, Chem. Rev. 2000, 100, 2159-2231 and references cited therein.
22. a) V. S. Joshi, V. K. Kale, K. M. Sathe, A. Sarkar, S. S. Tavale, C. G. Suresh, Organometallics 1991, 10, 2898-2907;
23. b) V. S. Joshi, S. K. Chowdhury, A. Sarkar, Proc. Indian Acad. Sci. 1995, 107, 447-458;
24. c) S. K. Chowdhury, V. S. Joshi, A. G. Samuel, V. G. Puranik, S. S. Tavale, A. Sarkar, Organometallics 1994, 13, 4092-4096.
25. a) A. Mukherjee, A. Sarkar, Arkivoc 2003, 87-95;
26. b) The crystal structure of ligand 2a is reported in ref. [9a].
27. T. Boullet, B. Klein, J. Hamelin, Synthesis 1986, 409-411.
28. a) D. M. T. Chan, K. L. Monaco, R. P. Wang, M. P. Winters, Tetrahedron Lett. 1998, 39, 2933-2936;
29. b) P. V. S. Lam, C. G. Clark, S. Saubern, J. Adams, M. P. Winters, D. M. T. Chan, A. Combs, Tetrahedron Lett. 1998, 39, 2941-2944;
30. c) S. Yu, J. Saenz, J. K. Srirangam, J. Org. Chem. 2002, 67, 1699-1702.
31. G. C. Lloyd-Jones, C. P. Butts, Tetrahedron 1998, 54, 901-914.
32. a) J. A. Bertrand, A. R. Kalyanaraman, Inorg. Chim. Acta 1971, 341-345;
33. b) M. M. Manigon, R. Smith, S. G. Shore, Cryst. Struct. Commun. 1979, 8, 261;
34. c) M. R. Churchill, F. J. Rotella, Inorg. Chem. 1979, 18, 166-171.
35. J. A. Bertrand, Inorg. Chem. 1967, 6, 495-497.
36. R. P. Hanzlik, D. Williamson, J. Am. Chem. Soc. 1976, 98, 6570-6573.
37. D. A. Buckingham, C. R. Clark, in Comprehensive Coordination Chemistry (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon Press, Oxford, New York, 1987, vol. 4, p. 724.
38. R. McCrindle, G. Ferguson, A. J. Mc Alees, P. J. Roberts, J. Chem. Soc., Dalton Trans. 1981, 1406-1414.
39. a) S. Mecking, Coord. Chem. Rev. 2000, 203, 325-351;
40. b) V. M. Mohring, G. Fink, Angew. Chem. Int. Ed. Engl. 1985, 24, 1001-1002.
41. M. J. Rachita, R. L. Huff, J. L. Bennett, M. Brookhart, J. Polym. Sci.: Part A, Polym. Chem. 2000, 38, 4627-4640.
42. a) L. K. Johnson, C. M. Killian, M. Brookhart, J. Am. Chem. Soc. 1995, 117, 6414-6415;
43. b) L. K. Johnson, S. Mecking, M. Brookhart, J. Am. Chem. Soc. 1996, 118, 267-268;
44. c) C. M. Killian, D. J. Tempel, L. K. Johnson, M. Brookhart, J. Am. Chem. Soc. 1996, 118, 11664-11665;
45. d) C. M. Killian, L. K. Johnson, M. Brookhart, Organometallics 1997, 16, 2005-2007;
46. e) S. Mecking, L. K. Johnson, L. Wang, M. Brookhart, J. Am. Chem. Soc. 1998, 120, 888-899;
47. f) F. A. Hicks, M. Brookhart, Organometallics 2001, 20, 3217-3219.
48. a) G. J. P. Britovsek, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. J. McTavish, G. A. Solan, A. J. P. White, D. J. Williams, Chem. Commun. 1998, 849-850;
49. b) G. J. P. Britovsek, V. C. Gibson, D. F. Wass, Angew. Chem. Int. Ed. 1999, 38, 428-447;
50. c) G. J. P. Britovsek, M. Bruce, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. Mastroianni, S. J. McTavish, C. Redshaw, G A. Solan, S. Stromberg, A. J. P. White, D. J. Williams, J. Am. Chem. Soc. 1999, 121, 8728-8740.
51. a) S. Tsuji, D. C. Swenson, R. F. Jordan, Organometallics 1999, 18, 4758-4764;
52. b) S. Murtuza, O. L. Casagrane, R. F. Jordan, Organometallics 2002, 21, 1882-1890.
53. F. W. Swamer, C. R. Hauser, J. Am. Chem. Soc. 1950, 72, 1352-1356.
54. G. M. Sheldrick, SHELX-97, program for crystal structure solution and refinement, University of Göttingen, Germany, 1997.