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Volumn 48, Issue 43, 2009, Pages 8086-8089

T-shaped three-coordinate copper(II) heptaphyrin complexes

Author keywords

Copper; Macrocycles; Metal arene interactions; Oxygenation; Porphyrinoids

Indexed keywords

ARENE INTERACTIONS; COPPER COMPLEXES; MACROCYCLES; PLANAR SYMMETRY; PORPHYRINOIDS;

EID: 70349976637     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200902901     Document Type: Article
Times cited : (31)

References (41)
  • 27
    • 70349928612 scopus 로고    scopus 로고
    • Complex Math equation.
    • Complex Math equation.
  • 31
    • 70349959859 scopus 로고    scopus 로고
    • Gaussian03, revisionB.05, Gaussian, Inc. Pittsburgh, PA
    • Gaussian03, revisionB.05, M. J. Frisch, et al. Gaussian, Inc. Pittsburgh, PA, 2003.
    • (2003)
    • Frisch, M.J.1
  • 32
    • 70349948800 scopus 로고    scopus 로고
    • 4 and actually confirmed the demetalation of copper ion(s) (see the Supporting Information).
    • 4 and actually confirmed the demetalation of copper ion(s) (see the Supporting Information).
  • 33
    • 70349941130 scopus 로고    scopus 로고
    • II d-d or MLCT transitions in the UV/ Vis absorption spectra because of large absorption coefficients of the heptaphyrin ligands, the absorption bands of which reach the near-IR region (see the Supporting Information).
    • II d-d or MLCT transitions in the UV/ Vis absorption spectra because of large absorption coefficients of the heptaphyrin ligands, the absorption bands of which reach the near-IR region (see the Supporting Information).
  • 41
    • 70349939434 scopus 로고    scopus 로고
    • 2 symmetry, with Cu1···C2 and Cu1···C1 distances of 2.81 and 2.93 Å. The d-π orbital overlap in the selected MOs is smaller than that in 4 (see the Supporting Information).
    • 2 symmetry, with Cu1···C2 and Cu1···C1 distances of 2.81 and 2.93 Å. The d-π orbital overlap in the selected MOs is smaller than that in 4 (see the Supporting Information).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.