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33
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II d-d or MLCT transitions in the UV/ Vis absorption spectra because of large absorption coefficients of the heptaphyrin ligands, the absorption bands of which reach the near-IR region (see the Supporting Information).
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II d-d or MLCT transitions in the UV/ Vis absorption spectra because of large absorption coefficients of the heptaphyrin ligands, the absorption bands of which reach the near-IR region (see the Supporting Information).
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2 symmetry, with Cu1···C2 and Cu1···C1 distances of 2.81 and 2.93 Å. The d-π orbital overlap in the selected MOs is smaller than that in 4 (see the Supporting Information).
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2 symmetry, with Cu1···C2 and Cu1···C1 distances of 2.81 and 2.93 Å. The d-π orbital overlap in the selected MOs is smaller than that in 4 (see the Supporting Information).
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