O-O bond activation in heterobimetallic peroxides: Synthesis of the peroxide [LNi(μ,η2:η2-O2)K] and its conversion into a bis(μ-Hydroxo) nickel zinc complex

Angewandte Chemie - International Edition

Volumn 48, Issue 43, 2009, Pages 8107-8110

  Yao, Shenglai ^b   Xiong, Yun ^b   Vogt, Matthias ^c   Grützmacher, Hansjörg ^c   Herwig, Christian ^a   Limberg, Christian ^a   Driess, Matthias ^b  

^a HUMBOLDT UNIVERSITY   (Germany)

^b TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^c LABORATORY OF INORGANIC CHEMISTRY   (Switzerland)

Author keywords

Dioxygen ligands; Nickel; Spin polarization; Triplet states

Indexed keywords

DIKETIMINATES; DIOXYGEN LIGANDS; HETERO BIMETALLIC COMPLEXES; HETEROBIMETALLICS; HYDROGEN ATOMS; O-O BOND ACTIVATION; REDOX-ACTIVE; SUPEROXIDES; TRIPLET STATES; ZINC COMPLEX;

HYDROGEN; LIGANDS; NICKEL; NICKEL COMPOUNDS; OXIDATION; OXYGEN; SPIN DYNAMICS; SPIN POLARIZATION; ZINC;

NICKEL ALLOYS;

EID: 70349972271     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200903772     Document Type: Article

References (52)

1. a) L. Que, Jr., W. B. Tolman, Angew. Chem. 2002, 114 1160
2. Angew. Chem. Int. Ed. 2002, 41 1114
3. Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations (Ed.: B. Meunier), Springer, Berlin, 2000
4. Biomimetic Oxidations Catalyzed by Transition Metal Complexes (Ed.: B. Meunier), Imperial College Press, London, 2000.
5. L. M. Mirica, X. Ottenwaelder, T. D. P. Stack, Chem. Rev. 2004, 104 1013.
6. Nickel and cobalt
7. a) S. Hikichi, M. Yoshizawa, Y. Sasakura, M. Akita, Y. More-oka, J. Am. Chem. Soc. 1998, 120 10567
8. S. Hikichi, M. Yoshizawa, Y. Sadakura, H. Komatsuzaki, Y. Moro-oka, M. Akita, Chem. Eur. J. 2001, 7 5011Ni
9. c) K. Shiren, S. Ogo, S. Fujinami, H. Hayashi, M. Suzuki, A. Uehara, Y. Watanabe, Y. Moro-oka, J. Am. Chem. Soc. 2000, 122 254
10. B. S. Mandimutsira, J. L. Yamarik, T. C. Brunold, W. Gu, S. P. Cramer, C. G. Riordan, J. Am. Chem. Soc. 2001, 123 9194
11. R. Schenker, B. S. Manimutsira, C. G. Riordan, T. C. Brunold, J. Am. Chem. Soc. 2002, 124 13842
12. S. Itoh, H. Bandoh, M. Nakagawa, S. Nagatomo, T. Kitagawa, K. D. Karlin, S. Fuku-zumi, J. Am. Chem. Soc. 2001, 123 11168.
13. For H-atom abstraction reactivity in copper and iron chemistry, compare for instance
14. T. Osako, K. Ohkubo, M. Taki, Y. Tachi, S. Fukuzumi, S. Itoh, J. Am. Chem. Soc. 2003, 125 11027
15. J. Shearer, C. X. Zhang, L. N. Zakharov, A. L. Rheingold, K. D. Karlin, J. Am. Chem. Soc. 2005, 127 5469
16. S. Mahapatra, J. A. Halfen, W. B. Tolman, J. Am. Chem. Soc. 1996, 118 11575
17. A. P. Cole, V. Mahadevan, L. M. Mirica, X. Ottenwaelder, T. D. P. Stack, Inorg. Chem. 2005, 44 7345
18. A. J. Skulan, M. A. Hanson, H.-f. Hsu, L. Que Jr., E. I. Solomon, J. Am. Chem. Soc. 2003, 125 7344
19. C. Kim, Y. Dong, L. Que, Jr., J. Am. Chem. Soc. 1997, 119 3635
20. Y. Dai, T. H. Warren, Chem. Commun. 2001, 1998.
21. a) E. Kim, E. E. Chufan, K. Kamaraj, K. D. Karlin, Chem. Rev. 2004, 104 1077
22. J. P. Collman, R. Boulatov, C. J. Sunderland, L. Fu, Chem. Rev. 2004, 104 561
23. R. Boulatov, Pure Appl. Chem. 2004, 76 303.
24. J. T. York, A. Llobet, C. J. Cramer, W. B. Tolman, J. Am. Chem. Soc. 2007, 129, 7990-7999.
25. a) N. W. Aboelella, J. T. York, A. M. Reynolds, K. Fujita, C. R. Kinsinger, C. J. Cramer, C. G. Riordan, W. B. Tolman, Chem. Commun. 2004, 1716
26. J. T. York, V. G. Young, W. B. Tolman, Inorg. Chem. 2006, 45 4191
27. P. L. Alsters, J. Boersma, G. Van Koten, Organometallics 1993, 12 1629
28. Z. T. Cygan, J. E. Bender, K. E. Litz, J. W. Kampf, M. M. Banaszak-Holl, Organo-metallics 2002, 21 5373
29. K. E. Litz, M. M. Banaszak-Holl, J. W. Kampf, G. B. Carpenter, Inorg. Chem. 1998, 37 6461.
30. S. Yao, E. Bill, C. Milsmann, K. Wieghardt, M. Driess, Angew. Chem. 2008, 120 7218
31. Angew. Chem. Int. Ed. 2008, 47 7110.
32. a) K. Nakagawa, R. Konake, T. Nakata, J. Org. Chem. 1962, 27 1597
33. M. V. George, K. S. Balachandran, Chem. Rev. 1975, 75 491
34. H. Ji, T. Wang, M. Zhang, Y. She, L. Wang, Appl. Catal. A 2005, 282 25
35. J. M. Grill, J. W Ogle, S. A. Miller, J. Org. Chem. 2006, 71 9291
36. Y. Sun, B. Gaten, B. Mayers, V. Xia, Nano Lett. 2002, 2 167
37. C. Faure, C. Delmas, M. Fouassier, J. Power Sources 1991, 35 279.
38. a) D. Chen, A. E. Martell, J. Am. Chem. Soc. 1990, 112 9411
39. C. C. Cheng, J. Gulia, S. E. Rokita, C. J. Burrows, J. Mol. Catal. A 1996, 113 379
40. G. Aullon, M. Hamidi, A Lledos, S. Alvarez, Inorg. Chem. 2004, 43 3702
41. S. Takahashi, K. Sonogashira, N. Hagihara, J. Chem. Soc. Jpn. 1966, 87 610
42. G. Wilke, H. Schott, P. Heimbach, Angew. Chem. 1967, 79 62
43. Angew. Chem. Int. Ed. Engl. 1967, 6 92
44. S. Otsuka, A. Nakamura, Y. Tatsuno, J. Am. Chem. Soc. 1969, 91 6994
45. E. J. Brown, A.-K. Duhme-Klair, M. I. Elliott, J. E. Thomas-Oates, P. L. Timmins, P. H. Walton, Angew. Chem. 2005, 117 1416
46. Angew. Chem. Int. Ed. 2005, 44 1392
47. J. Cho, H. Furutachi, S. Fujinami, M. Suzuki, Angew. Chem. 2004, 116 3362
48. Angew. Chem. Int. Ed. 2004, 43 3300
49. K. Shiren, S. Ogo, S. Fujinami, H. Hayashi, M. Suzuki, A. Uehara, Y. Watanabe, Y. Moro-oka, J. Am. Chem. Soc. 2000, 122 254.
50. a) M. H. Gubelmann, A. F. Williams, Struct. Bonding (Berlin) 1983, 55 1
51. M. Suzuki, T. Ishiguro, M. Kozuka, K. Nakamoto, Inorg. Chem. 1981, 20, 1993.
52. M. S. Varonka, T. H. Warren, Inorg. Chim. Acta 2007, 360 317.