The first μ6-peroxide transition-metal complex: [Ni 8(L)12(O2)]2+

Angewandte Chemie - International Edition

Volumn 44, Issue 9, 2005, Pages 1392-1395

  Brown, Emma J ^a   Duhme Klair, Anne K ^a   Elliott, Matthew I ^a   Thomas Oates, Jane E ^a   Timmins, Phillipa L ^a   Walton, Patil H ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

Author keywords

Cluster compounds; Coordination modes; Hydroxypyridinones; Nickel; Peroxides

Indexed keywords

COORDINATION REACTIONS; ORGANIC COMPOUNDS; OXYGEN; PEROXIDES;

COORDINATION MODE; OCTANUCLEAR NICKEL COMPLEX; PEREXO LIGANDS;

NICKEL COMPOUNDS;

COORDINATION COMPOUND; METAL COMPLEX; NICKEL; PEROXIDE; TRANSITION ELEMENT;

ARTICLE; BINDING KINETICS; BINDING SITE; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; MASS SPECTROMETRY; MOLECULAR DYNAMICS; STRUCTURE ANALYSIS; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

CRYSTALLOGRAPHY, X-RAY; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NICKEL; ORGANOMETALLIC COMPOUNDS; PEROXIDES; PYRIDINES; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; SPECTRUM ANALYSIS, RAMAN;

EID: 14844335651     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461892     Document Type: Article

References (41)

1. See, for example: A. G. Blackman, W. B. Tolman, Struct. Bonding (Berlin) 2000, 97, 179.
2. E. Kim, M. E. Helton, I. M. Wasser, K. D. Karlin, S. Lu, H. W. Huang, P. Moenne-Loccoz, C. D. Incarvito, A. L. Rheingold, M. Honecker, S. Kaderli, A. D. Zuberbuhler, Proc. Natl. Acad. Sci. USA 2003, 100, 3623, and references therein.
3. U. M. Sundaram, H. H. Zhang, B. Hedman, K. O. Hodgson, E. I. Solomon, J. Am. Chem. Soc. 1997, 119, 12 525.
4. N. Hakulinen, L. L. Kiiskinen, K. Kruus, M. Saloheimo, A. Paananen, A. Koivula, J. Rouvinen, Nat. Struct. Biol. 2002, 9, 601.
5. J. Reim, R. Werner, W. Haase, B. Krebs, Chem. Eur. J. 1998, 4, 289.
6. F. Meyer, H. Pritzkow, Angew. Chem. 2000, 112, 2199; Angew. Chem. Int. Ed. 2000, 39, 2112.
7. F. Meyer, H. Pritzkow, Angew. Chem. 2000, 112, 2199; Angew. Chem. Int. Ed. 2000, 39, 2112.
8. I. Shweky, L. E. Pence, G. C. Papaefthymiou, R. Sessoli, J. W. Yun, A. Bino, S. J. Lippard, J. Am. Chem. Soc. 1997, 119, 1037.
9. R. Çelenligil-Çetin, R. J. Staples, P. Stavropoulos, Inorg. Chem. 2000, 39, 5838.
10. W. Micklitz, S. G. Bott, J. G. Bentsen, S. J. Lippard, J. Am. Chem. Soc. 1989, 11, 372.
11. T. Ozeki, T. Yamase, Bull. Chem. Soc. Jpn. 1997, 70, 2101.
12. E. I. Tolis, M. Helliwell, S. Langley, J. Raftery, R. E. P. Winpenny, Angew. Chem. 2003, 115, 3934; Angew. Chem. Int. Ed. 2003, 42, 3804.
13. E. I. Tolis, M. Helliwell, S. Langley, J. Raftery, R. E. P. Winpenny, Angew. Chem. 2003, 115, 3934; Angew. Chem. Int. Ed. 2003, 42, 3804.
14. R. Stomberg, L. Trysberg, I. Larking, Acta Chem. Scand. 1970, 24, 2678.
15. O. W. Howarth, Dalton Trans. 2004, 476; H. J. Breunig, T Krüger, E. Lork, Angew. Chem. 1997, 109, 654; Angew. Chem. Int. Ed. Engl. 1997, 36, 615.
16. O. W. Howarth, Dalton Trans. 2004, 476; H. J. Breunig, T Krüger, E. Lork, Angew. Chem. 1997, 109, 654; Angew. Chem. Int. Ed. Engl. 1997, 36, 615.
17. O. W. Howarth, Dalton Trans. 2004, 476; H. J. Breunig, T Krüger, E. Lork, Angew. Chem. 1997, 109, 654; Angew. Chem. Int. Ed. Engl. 1997, 36, 615.
18. N. Hovnanian, J. Galloy, P. Miele, Polyhedron 1995, 14, 297.
19. J. Auld, A. C. Jones, A. B. Leese, B. Cockayne, P. J. Wright, P. O'Brien, M. Motevalli, J. Mater. Chem. 1993, 3, 1203.
20. E. J. Brown, A.-K. Duhme-Klair, P. H. Walton, Dalton Trans. 2004, 2458.
21. A. E. V. Gorden, J. D. Xu, K. N. Raymond, P. Durbin, Chem. Rev. 2003, 103, 4207.
22. E. K. Brechin, W. Clegg, M. Murrie, S. Parsons, S. J. Teat, R. E. P. Winpenny, J. Am. Chem. Soc. 1998, 120, 7365.
23. G. Aromi, A. R. Bell, M. Helliwell, J. Raftery, S. J. Teat, G. A. Timco, O. Roubeau, R. E. P. Winpenny., Chem. Eur. J. 2003, 9, 3024, and references therein.
24. Full experimental and analytical details are available as Supporting Information.
25. Kα radiation (λ = 0.71073 Å) using a SMART CCD camera. Diffractometer control, data collection and initial unit cell determination was performed using SMART. [22] Frame integration and unit-cell refinement software was carried out with the SAINT + [22] software. Structures were solved by direct methods using SHELXS-97 and refined by full-matrix least squares using SHELXL-97. [23] One of the side chains of the ligand, L, was assumed to be disordered over two positions. All non-hydrogen atoms were refined anisotropically, except for the disordered atoms, which were refined isotropically. Hydrogen atoms were placed using a "riding model" and included in the refinement at calculated positions. CCDC 252525 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
26. a) SMART Control software (v.5.625), Bruker-AXS Inc, Madison, USA;
27. b) SAINT + Integration software (v.6.22), Bruker-AXS Inc, Madison, USA;
28. c) SADABS, G. M. Sheldrick, University of Göttingen, Germany.
29. a) SHELXS-97: Program for the Solution of Crystal Structures, G. M. Sheldrick, University of Göttingen, Germany, 1997;
30. b) SHELXL-97: Program for the Refinement of Crystal Structures, G. M. Sheldrick, University of Göttingen, Germany, 1997.
31. C. W. W. Hoffman, R. C. Ropp, R. W. Mooney, J. Chem. Soc. 1959, 81, 3830.
32. G. B. Jameson, J. A. Ibers in Bioinorganic Chemistry (Eds.: I. Bertini, H. B. Gray, S. J. Lippard, J. S. Valentine), University Science Books, Mill Valley, 1994, pp. 167-252.
33. M. V. George, K. S. Balachandran, Chem. Rev. 1975, 75, 491.
34. M. Matsumoto, K. Nakatsu, Acta Crystallogr. B 1975, 31, 2711.
35. J. Cho, H. Furutachi, S. Fujinami, M. Suzuki, Angew. Chem. 2004, 116, 3362; Angew. Chem. Int. Ed. 2004, 43, 3300.
36. J. Cho, H. Furutachi, S. Fujinami, M. Suzuki, Angew. Chem. 2004, 116, 3362; Angew. Chem. Int. Ed. 2004, 43, 3300.
37. K. Shiren, S. Ogo, S. Fujinami, H. Hayashi, M. Suzuki, A. Uehara, Y. Watanabe, Y. Moro-oka, J. Am. Chem. Soc. 2000. 122, 254.
38. K. Fujita, R. Schenker, W. Gu, T. C. Brunold, S. P. Cramer, C. G. Riordan, Inorg. Chem. 2004, 43, 3324.
39. G. Aullón, M. Hamidi, A Lledós, S. Alvarez, Inorg. Chem. 2004, 43, 3702.
40. Note added in proof (January 12, 2005). The following article concerning peroxo-bridged nickel species has recently been published: M. T. Kieber-Emmons, R. Schenker, G. P. A. Yap, T. C. Bunold, C. G. Riordan, Angew. Chem. 2004, 116, 6884; Angew. Chem. Int. Ed. 2004, 43, 6716.
41. Note added in proof (January 12, 2005). The following article concerning peroxo-bridged nickel species has recently been published: M. T. Kieber-Emmons, R. Schenker, G. P. A. Yap, T. C. Bunold, C. G. Riordan, Angew. Chem. 2004, 116, 6884; Angew. Chem. Int. Ed. 2004, 43, 6716.