메뉴 건너뛰기




Volumn 43, Issue 25, 2004, Pages 3300-3303

A bis(μ-alkylperoxo)dinickel(II) complex as a reaction intermediate for the oxidation of the methyl groups of the Me2-tpa ligand to carboxylate and alkoxide ligands

Author keywords

Nickel; Oxidation; Peroxides; Reaction mechanisms

Indexed keywords

CARBOXYLATION; HYDROGEN PEROXIDE; OXIDATION;

EID: 4544231478     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353637     Document Type: Article
Times cited : (35)

References (29)
  • 4
    • 0037007237 scopus 로고    scopus 로고
    • b) L. Que, Jr, W. B. Tolman, Angew. Chem. 2002, 114, 1160; Angew. Chem. Int. Ed. 2002, 41, 1114;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1114
  • 13
    • 85007228644 scopus 로고    scopus 로고
    • K. Haas, H. Dialer, H. Piotrowski, J. Schapp, W. Beck, Angew. Chem. 2002, 114, 1969; Angew. Chem. Int. Ed. 2002, 41, 1879.
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1879
  • 14
    • 4544232181 scopus 로고    scopus 로고
    • note
    • 3-tpa = tris[(6-methyl-2-pyridyl)methyl]amine.
  • 23
    • 1942496535 scopus 로고    scopus 로고
    • J. Lewinski, Z. Ochal, E. Bojarski, E. Tratkiewicz, I. Justyniak, J. Lipkowski, Angew. Chem. 2003, 115, 4791; Angew. Chem. Int. Ed. 2003, 42, 4643.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 4643
  • 24
    • 4544294959 scopus 로고    scopus 로고
    • note
    • The crystal data and ORTEP diagram for 1 are given in the Supporting Information.
  • 25
    • 4544361495 scopus 로고    scopus 로고
    • note
    • Although there is a possibility of a peroxonickel(III) species as an alternative formulation, it is not clear which is correct at present.
  • 26
    • 4544325634 scopus 로고    scopus 로고
    • note
    • Surprisingly, it was found that the thermal decomposition of 3 was very slow in the presence of a small amount of water (> 2 days).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.