Fine-tuning catalytic activity and selectivity-[Rh(amino acid thioamide)] complexes for efficient ketone reduction

Tetrahedron Letters

Volumn 50, Issue 46, 2009, Pages 6321-6324

  Ahlford, Katrin ^a   Livendahl, Madeleine ^a   Adolfsson, Hans ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

2 PROPANOL; KETONE; LIGAND; RHODIUM; THIOAMIDE;

ARTICLE; ASYMMETRIC CATALYSIS; CARBOXY TERMINAL SEQUENCE; HYDROGENATION; REDUCTION; STEREOCHEMISTRY; SYNTHESIS;

EID: 70349483850     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.08.116     Document Type: Article

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41. See Supplementary data for detailed information on ligand formation.
42. Reaction conditions according to Scheme 2. Conversions and enantioselectivities were determined by GLC analysis (CP Girasil DEX CB). A table for Figure 1 is available in the Supplementary data.
43. 2-Propanol (1 mL) was exchanged for THF in order to dissolve the substrate.