Suppression of common-ion return by amines: A method to measure rates of fast SN1 reactions

Journal of Organic Chemistry

Volumn 74, Issue 19, 2009, Pages 7328-7334

  Streidl, Nicolas ^a   Antipova, Anna ^a   Mayr, Herbert ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS ACETONE; CARBOCATIONS; CHEMICAL EQUATIONS; CHLORIDE ANIONS; CONDUCTOMETERS; CONDUCTOMETRY; CORRELATION EQUATION; ELECTROPHILES; ION RATES; ION RECOMBINATION; IONIZATION RATES; SOLVOLYSES; STOPPED-FLOW TECHNIQUES; TERTIARY AMINE; TIME-SCALES;

ACETONE; ACETONITRILE; AMINATION; AMINES; CHLORINE COMPOUNDS; IONS; NUCLEOPHILES;

RATE CONSTANTS;

4 METHOXY 4' METHYLBENZHYDRYL CHLORIDE; 4 METHOXY 4' PHENOXYBENZHYDRYL CHLORIDE; 4 METHOXYBENZHYDRYL CHLORIDE; 4,4' DIMETHOXYBENZHYDRYL CHLORIDE; ACETONE; ACETONITRILE; AMINE; ANION; BENZHYDRYL CHLORIDE; BENZHYDRYL DERIVATIVE; CATION; ELECTROPHILE; ION; NUCLEOPHILE; SECONDARY AMINE; TERTIARY AMINE; UNCLASSIFIED DRUG;

ARTICLE; CONDUCTOMETRY; CONTROLLED STUDY; IONIZATION; KINETICS; SOLVOLYSIS;

AMINES; IONS; MOLECULAR STRUCTURE; STEREOISOMERISM; TIME FACTORS;

EID: 70349443545     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo901410b     Document Type: Article

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59. - at the end of the solvolysis reactions shown in Table 3, i.e. the maximum concentration of Cl- during the measurement.