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W. H. Saunders, Jr., R. H. Paine, J. Am. Chem. Soc. 1961, 83, 882-885. The formolysis of neophyl tosylate was carried out in boiling formic acid (∼100°C). If the observed product ratios were corrected to 25 °C, the temperature of the carbene fragmentations, there would presumably be an even greater product selectivity of formolysis versus fragmentation.
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0003887404
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Lowry, T.H.1
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0013191182
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J. P. Pezacki, D. Shukla, J. Lusztyk, J. Warkentin, J. Am. Chem. Soc. 1999, 121, 6589-6598.
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J. P. Pezacki, D. Shukla, J. Lusztyk, J. Warkentin, J. Am. Chem. Soc. 1999, 121, 6589-6598.
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84982076269
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The substitution products from 38 and 39 are menthol and neomenthol
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H. Feltkamp, F. Koch, T. N. Thanh, Annalen 1967, 707, 95-99. The substitution products from 38 and 39 are menthol and neomenthol.
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Feltkamp, H.1
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27
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65949116120
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For leading references, see notes 3 and 4 in reference 28
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For leading references, see notes 3 and 4 in reference 28.
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28
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0034834144
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R. A. Moss, F. Zheng, R. R. Sauers, J. Toscano, J. Am. Chem. Soc. 2001, 123, 8109-8116.
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65949108999
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See the discussion and citations in reference 19, 463-478
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See the discussion and citations in reference 19, 463-478.
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30
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0009670240
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For examples of ROCCl isomers, see M. A. Kesselmayer, R. S. Sheridan, J. Am. Chem. Soc. 1986, 108, 99-107; 844-845
-
For examples of ROCCl isomers, see M. A. Kesselmayer, R. S. Sheridan, J. Am. Chem. Soc. 1986, 108, 99-107; 844-845.
-
-
-
-
31
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65949113572
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The cations of ion pairs 59 and 60 are very likely delocalized (i.e., 52); only exo-2-norbornyl methyl ether is formed; see reference 28.
-
The cations of ion pairs 59 and 60 are very likely delocalized (i.e., 52); only exo-2-norbornyl methyl ether is formed; see reference 28.
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32
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0000936841
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0001207564
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R. H. Mazur, W. N. White, D. A. Seminow, C. C. Lee, M. S. Silver, J. D. Roberts, J. Am. Chem. Soc. 1959, 81, 4390-4398.
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36
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47349114207
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For a recent discussion of the electronic structure of the cyclopro-pylcarbinyl cation, see
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For a recent discussion of the electronic structure of the cyclopro-pylcarbinyl cation, see: G. A. Olah, G. K. Surya Prakash, G. Rasul, J. Am. Chem. Soc. 2008, 130, 9168-9172.
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65949105888
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See reference 19, 345f
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See reference 19, 345f.
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0037184463
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53
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5044242928
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• is only ∼2 kcal/mol: J. M. Nicovich, K. D. Kreutter, P. H. Wine, J. Chem. Phys. 1990, 92, 3539-3544.
-
• is only ∼2 kcal/mol: J. M. Nicovich, K. D. Kreutter, P. H. Wine, J. Chem. Phys. 1990, 92, 3539-3544.
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54
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19544363976
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55
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0032483755
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P. C. Venneri, J. Warkentin, J. Am. Chem. Soc. 1998, 120, 11182-11183.
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P. C. Venneri, J. Warkentin, J. Am. Chem. Soc. 1998, 120, 11182-11183.
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0034014603
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N. Merkley, M. El-Saidi, J. Warkentin, Can. J. Chem. 2000, 78, 356-361.
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0347916939
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J.-M. Fedé, S. Jockusch, N. Lin, R. A. Moss, N. J. Turro, Org. Lett. 2003, 5, 5027-5030.
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58
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65949096790
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-
For this usage, see M. S. Platz, In Advances in Carbene Chemistry 2 (Ed.: U. H. Brinker) JAI Press: Stamford, CT 1998, 165f-168f.
-
For this usage, see M. S. Platz, In Advances in Carbene Chemistry Vol. 2 (Ed.: U. H. Brinker) JAI Press: Stamford, CT 1998, 165f-168f.
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59
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33750328822
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X. Fu, R. A. Moss, P. Piotrowiak, M. Myahkostupov, I. R. Gould, Org. Lett. 2006, 8, 4807-4809.
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