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Volumn 40, Issue 1, 2007, Pages 1-7

Dynamic processes leading to covalent bond formation for SN1 reactions

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EID: 33846446745     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar0681124     Document Type: Article
Times cited : (20)

References (32)
  • 1
    • 33947090643 scopus 로고
    • Nucleophilic Reactivities towards Cations
    • Ritchie, C. D. Nucleophilic Reactivities towards Cations. Acc. Chem. Res. 1972, 5, 348-354.
    • (1972) Acc. Chem. Res , vol.5 , pp. 348-354
    • Ritchie, C.D.1
  • 2
    • 14744269754 scopus 로고    scopus 로고
    • Kinetics of the Reaction of Halide Anions with Carbocations: Quantitative Energy Profiles for SN1 Reactions
    • Minegishi, S.; Loos, R.; Kobayashi, S.; Mayr, H. Kinetics of the Reaction of Halide Anions with Carbocations: Quantitative Energy Profiles for SN1 Reactions. J. Am. Chem. Soc. 2005, 127, 2641-2649.
    • (2005) J. Am. Chem. Soc , vol.127 , pp. 2641-2649
    • Minegishi, S.1    Loos, R.2    Kobayashi, S.3    Mayr, H.4
  • 5
    • 0000341206 scopus 로고
    • The Application of the Marcus Relation to Reactions in Solution
    • Albery, W. J. The Application of the Marcus Relation to Reactions in Solution. Ann. Rev. Phys. Chem. 1980, 31, 227-263.
    • (1980) Ann. Rev. Phys. Chem , vol.31 , pp. 227-263
    • Albery, W.J.1
  • 6
    • 0033568228 scopus 로고    scopus 로고
    • Intrinsic Barriers for the Reactions of an Oxocarbenium Ion in Water
    • Richard, J. P.; Williams, K. B.; Amyes, T. L. Intrinsic Barriers for the Reactions of an Oxocarbenium Ion in Water. J. Am. Chem. Soc. 1999, 121, 8403-8404.
    • (1999) J. Am. Chem. Soc , vol.121 , pp. 8403-8404
    • Richard, J.P.1    Williams, K.B.2    Amyes, T.L.3
  • 7
    • 0034049212 scopus 로고    scopus 로고
    • Richard, J. P.; Toteva, M. M.; Crugeiras, J. Structure-Reactivity Relationships and Intrinsic Barriers for Nucleophile Additions to a Quinone Methide: A Strongly Resonance-Stabilized Carbocation. J. Am. Chem. Soc. 2000, 122, 1664-1674.
    • Richard, J. P.; Toteva, M. M.; Crugeiras, J. Structure-Reactivity Relationships and Intrinsic Barriers for Nucleophile Additions to a Quinone Methide: A Strongly Resonance-Stabilized Carbocation. J. Am. Chem. Soc. 2000, 122, 1664-1674.
  • 8
    • 0035543101 scopus 로고    scopus 로고
    • Formation and Stability of Carbocations and Carbanions in Water and Intrinsic Barriers to Their Reactions
    • Richard, J. P.; Amyes, T. L.; Toteva, M. M. Formation and Stability of Carbocations and Carbanions in Water and Intrinsic Barriers to Their Reactions. Acc. Chem. Res. 2001, 34, 981-988.
    • (2001) Acc. Chem. Res , vol.34 , pp. 981-988
    • Richard, J.P.1    Amyes, T.L.2    Toteva, M.M.3
  • 9
    • 0000739690 scopus 로고
    • Mechanism of Ionic Reactions
    • Ogg, R. A.; Polanyi, M. Mechanism of Ionic Reactions. Trans. Faraday Soc. 1935, 31, 604-620.
    • (1935) Trans. Faraday Soc , vol.31 , pp. 604-620
    • Ogg, R.A.1    Polanyi, M.2
  • 10
    • 5244320947 scopus 로고
    • The Reactions of Organic Halides in Solution
    • Evans, A. G. The Reactions of Organic Halides in Solution. Trans. Faraday Soc. 1948, 42, 719-742.
    • (1948) Trans. Faraday Soc , vol.42 , pp. 719-742
    • Evans, A.G.1
  • 11
    • 0001625966 scopus 로고    scopus 로고
    • Pross, A.; Shaik, S. S. A Qualitative Valence-Bond Approach to Organic Reactivity. Acc. Chem. Res. 1983, 16, 363-370.
    • Pross, A.; Shaik, S. S. A Qualitative Valence-Bond Approach to Organic Reactivity. Acc. Chem. Res. 1983, 16, 363-370.
  • 13
    • 0000143634 scopus 로고    scopus 로고
    • Kim, H. J.; Hynes, J. T. A Theoretical Model for SN1 Ionic Dissociation in Solution. 1. Activation Free Energetics and Transition-State Structure. J. Am. Chem. Soc. 1992, 114.
    • Kim, H. J.; Hynes, J. T. A Theoretical Model for SN1 Ionic Dissociation in Solution. 1. Activation Free Energetics and Transition-State Structure. J. Am. Chem. Soc. 1992, 114.
  • 14
    • 0001230084 scopus 로고    scopus 로고
    • Mathis, J. R.; Kim, H. J.; Hynes, J. T. A Theoretical Model for SN1 Ionic Dissociations in Solution. 3. Analysis of tert-Butyl Halides. J. Am. Chem. Soc. 1993, 115, 8248-8262.
    • Mathis, J. R.; Kim, H. J.; Hynes, J. T. A Theoretical Model for SN1 Ionic Dissociations in Solution. 3. Analysis of tert-Butyl Halides. J. Am. Chem. Soc. 1993, 115, 8248-8262.
  • 15
    • 5244245983 scopus 로고    scopus 로고
    • Hammond, G. S. A Correlation of Reaction Rates. J. Am. Chem. Soc. 1955, 77, 334-338.
    • Hammond, G. S. A Correlation of Reaction Rates. J. Am. Chem. Soc. 1955, 77, 334-338.
  • 16
    • 0842287054 scopus 로고    scopus 로고
    • Zichi, D. A.; Hynes, J. T. A Dynamical Theory for Unimolecular Ionic Dissociation Reactions in Polar Solvents. J. Chem. Phys. 1988, 88, 2513-2525.
    • Zichi, D. A.; Hynes, J. T. A Dynamical Theory for Unimolecular Ionic Dissociation Reactions in Polar Solvents. J. Chem. Phys. 1988, 88, 2513-2525.
  • 17
    • 0001018677 scopus 로고
    • Dynamical Polar Solvent Effects on Solution Reactions: A Simple Continuum Model
    • Zwan, G. v. d.; Hynes, J. T. Dynamical Polar Solvent Effects on Solution Reactions: A Simple Continuum Model. J. Chem. Phys. 1983, 76, 2993-3001.
    • (1983) J. Chem. Phys , vol.76 , pp. 2993-3001
    • Zwan, G.V.D.1    Hynes, J.T.2
  • 18
    • 0000091704 scopus 로고
    • Picosecond Dynamics of Contact Ion Pairs and Solvent-Separated Ion Pairs in the Photolysis of Diphenylmethyl Chloride
    • Peters, K. S.; Li, B. Picosecond Dynamics of Contact Ion Pairs and Solvent-Separated Ion Pairs in the Photolysis of Diphenylmethyl Chloride. J. Phys. Chem. 1994, 98, 401-403.
    • (1994) J. Phys. Chem , vol.98 , pp. 401-403
    • Peters, K.S.1    Li, B.2
  • 19
    • 0000195764 scopus 로고
    • Role of Polarization Caging in the SN1 Reaction of Diphenylmethyl Chloride: A Picosecond Kinetic Study
    • Deniz, A. A.; Li, B.; Peters, K. S. Role of Polarization Caging in the SN1 Reaction of Diphenylmethyl Chloride: A Picosecond Kinetic Study. J. Phys. Chem. 1995, 99, 12209-12213.
    • (1995) J. Phys. Chem , vol.99 , pp. 12209-12213
    • Deniz, A.A.1    Li, B.2    Peters, K.S.3
  • 20
    • 0001211538 scopus 로고    scopus 로고
    • Picosecond Kinetic. Study of the Photoinduced Homolysis and Heterolysis of Diphenylmethyl Bromide. 2. Role of Polarization Caging in Contact Ion Pair Recombination
    • Dreyer, J.; Lipson, M.; Peters, K. S. Picosecond Kinetic. Study of the Photoinduced Homolysis and Heterolysis of Diphenylmethyl Bromide. 2. Role of Polarization Caging in Contact Ion Pair Recombination. J. Phys. Chem. 1996, 100, 15162-15164.
    • (1996) J. Phys. Chem , vol.100 , pp. 15162-15164
    • Dreyer, J.1    Lipson, M.2    Peters, K.S.3
  • 21
    • 0000580483 scopus 로고    scopus 로고
    • Picosecond Kinetic Study of the Photo-induced Homolysis and Heterolysis of Diphenylmethyl Bromide. 1. The Nature of the Conversion from Radical Pairs to Ion Pairs
    • Dreyer, J.; Peters, K. S. Picosecond Kinetic Study of the Photo-induced Homolysis and Heterolysis of Diphenylmethyl Bromide. 1. The Nature of the Conversion from Radical Pairs to Ion Pairs. J. Phys. Chem. 1996, 100, 15156-15161.
    • (1996) J. Phys. Chem , vol.100 , pp. 15156-15161
    • Dreyer, J.1    Peters, K.S.2
  • 22
    • 0010057277 scopus 로고    scopus 로고
    • Picosecond Kinetic Study of the Dynamics for Photoinduced Homolysis and Heterolysis in Diphenylmethyl Chloride
    • Lipson, M.; Deniz, A. A.; Peters, K. S. Picosecond Kinetic Study of the Dynamics for Photoinduced Homolysis and Heterolysis in Diphenylmethyl Chloride. J. Phys. Chem. 1996, 100, 3580-3586.
    • (1996) J. Phys. Chem , vol.100 , pp. 3580-3586
    • Lipson, M.1    Deniz, A.A.2    Peters, K.S.3
  • 23
    • 33846404821 scopus 로고    scopus 로고
    • Lipson, M.; Deniz, A. A.; Peters, K. S. Nature of the Potential Energy Surfaces for the SN1 Reaction: A Picosecond Kinetic Study of Homolysis and Heterolysis for Diphenylmethyl Chlorides. J. Am. Chem. Soc. 1996, 118, 2992-2997.
    • Lipson, M.; Deniz, A. A.; Peters, K. S. Nature of the Potential Energy Surfaces for the SN1 Reaction: A Picosecond Kinetic Study of Homolysis and Heterolysis for Diphenylmethyl Chlorides. J. Am. Chem. Soc. 1996, 118, 2992-2997.
  • 24
    • 25144513468 scopus 로고    scopus 로고
    • Dynamic Nature of the Transition State for the SN1 Reaction Mechanism of Diphenylmethyl Acetates
    • Peters, K. S.; Gasparrini, S.; Heeb, L. R. Dynamic Nature of the Transition State for the SN1 Reaction Mechanism of Diphenylmethyl Acetates. J. Am. Chem. Soc. 2005, 127, 13039-13047.
    • (2005) J. Am. Chem. Soc , vol.127 , pp. 13039-13047
    • Peters, K.S.1    Gasparrini, S.2    Heeb, L.R.3
  • 25
    • 0032577094 scopus 로고    scopus 로고
    • The Sub-Picosecond Dynamics of Diphenylmethyl chloride Ion Pairs and Radical Pairs
    • Lipson, M.; Deniz, A. A.; Peters, K. S. The Sub-Picosecond Dynamics of Diphenylmethyl chloride Ion Pairs and Radical Pairs. Chem. Phys. Letts. 1998, 288, 781-784.
    • (1998) Chem. Phys. Letts , vol.288 , pp. 781-784
    • Lipson, M.1    Deniz, A.A.2    Peters, K.S.3
  • 26
    • 0040232920 scopus 로고
    • Photoisomerization Dynamics of Stilbenes
    • Waldeck, D. H. Photoisomerization Dynamics of Stilbenes. Chem. Rev. 1991, 91, 415-436.
    • (1991) Chem. Rev , vol.91 , pp. 415-436
    • Waldeck, D.H.1
  • 27
    • 0347929642 scopus 로고    scopus 로고
    • Ciccotti, G.; Ferrario, M.; Hynes, J. T.; Kapral, R. Constrained Molecular Dynamics and the Mean Potential For an Ion Pair in A Polar Solvent. Chem. Phys. 1989, 129, 241-251.
    • Ciccotti, G.; Ferrario, M.; Hynes, J. T.; Kapral, R. Constrained Molecular Dynamics and the Mean Potential For an Ion Pair in A Polar Solvent. Chem. Phys. 1989, 129, 241-251.
  • 28
    • 0000282776 scopus 로고
    • Dynamics of Ion Pair Interconversion in a Polar Solvent
    • Ciccotti, G.; Ferrario, M.; Hynes, J. T.; Kapral, R. Dynamics of Ion Pair Interconversion in a Polar Solvent. J. Chem. Phys. 1990, 93, 7137-7147.
    • (1990) J. Chem. Phys , vol.93 , pp. 7137-7147
    • Ciccotti, G.1    Ferrario, M.2    Hynes, J.T.3    Kapral, R.4
  • 29
    • 0004705649 scopus 로고
    • Application of Kramers Theory to the Diffusional Separation of the trans-Stilbene/Fumaronitrile Contact Radical Ion Pair in Alkyl Nitrile Solvents
    • Li, B.; Peters, K. S. Application of Kramers Theory to the Diffusional Separation of the trans-Stilbene/Fumaronitrile Contact Radical Ion Pair in Alkyl Nitrile Solvents. J. Phys. Chem. 1993, 97, 7648-7651.
    • (1993) J. Phys. Chem , vol.97 , pp. 7648-7651
    • Li, B.1    Peters, K.S.2
  • 30
    • 0000887822 scopus 로고
    • Time-Resolved Resonance Raman Study of the Rate of Separation of a Geminate Ion Pair into Free Ions in a Medium Polarity Solvent
    • Vauthey, E.; Parker, A. W.; Nohova, B.; Phillips, D. Time-Resolved Resonance Raman Study of the Rate of Separation of a Geminate Ion Pair into Free Ions in a Medium Polarity Solvent. J. Am. Chem. Soc. 1994, 116, 9182-9186.
    • (1994) J. Am. Chem. Soc , vol.116 , pp. 9182-9186
    • Vauthey, E.1    Parker, A.W.2    Nohova, B.3    Phillips, D.4
  • 31
    • 4344716318 scopus 로고    scopus 로고
    • Solvent-Separated Radical Ion Pairs and Free Ion Yields. 1. Effect of Temperature on Free Ion Formation in Solution
    • Zhong, C.; Zhou, J.; Braun, C. L. Solvent-Separated Radical Ion Pairs and Free Ion Yields. 1. Effect of Temperature on Free Ion Formation in Solution. J. Phys. Chem. A 2004, 108, 6842-6849.
    • (2004) J. Phys. Chem. A , vol.108 , pp. 6842-6849
    • Zhong, C.1    Zhou, J.2    Braun, C.L.3
  • 32
    • 0642337274 scopus 로고
    • Dynamics of Interconversion of Contact and Solvent-Separated Radical-Ion Pairs
    • Arnold, B. R.; Noukakis, D.; Farid, S.; Goodman, J. L.; Gould, I. R. Dynamics of Interconversion of Contact and Solvent-Separated Radical-Ion Pairs. J. Am. Chem. Soc. 1995, 117, 4399-4400.
    • (1995) J. Am. Chem. Soc , vol.117 , pp. 4399-4400
    • Arnold, B.R.1    Noukakis, D.2    Farid, S.3    Goodman, J.L.4    Gould, I.R.5


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