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More exactly, eq 1 would hold for any situation where nucleophilic solvent participation is equal in both the substrate under consideration and the standard, tert-butyl chloride.
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T of solvent mixtures (v/v) from ref 2: 0.37 (E), 0.17 (M), 0.16 (90E10W). 0 (80E20W), -0.35 (90A10W), -0.37 (80A20W), -0.39 (60E40W), -0.58 (50E50W), -0.74 (40E60W), -1.16 (20E80W), -1.31 (10E90W), -1.38 (W), -1.71 (42T58W = 50T50W, w/w), -1.85 (52T48W = 60T40W, w/w), -1.98 (63T37W = 70T30W, w/w), -2.25 (87T13W = 90T10W, w/w), -3.93 (T).
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