Mild, aqueous, aerobic, catalytic oxidation of methane to methanol and acetaldehyde catalyzed by a supported bipyrimidinylplatinum-polyoxometalate hybrid compound

Journal of the American Chemical Society

Volumn 126, Issue 33, 2004, Pages 10236-10237

  Bar Nahum, Itsik ^a   Khenkin, Alexander M ^a   Neumann, Ronny ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ACETALDEHYDE; ACETIC ACID; ALCOHOL; BIPYRIMIDINYLPLATINUM POLYOXOMETALATE COMPOUND; BISULFITE; CARBON DIOXIDE; CARBON MONOXIDE; FORMALDEHYDE; METAL DERIVATIVE; METHANE; METHANOL; OXYGEN; PLATINUM DERIVATIVE; PYRIMIDINE DERIVATIVE; SILICON DIOXIDE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; CATALYST SUPPORT; CHEMICAL REACTION KINETICS; OXIDATION; REACTION ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY;

EID: 4143151730     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0493547     Document Type: Article

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25. 3OH.
26. 18OH was observed.
27. 11 species. In such a scenario, the hydride may be oxidized by the polyoxometalate (ref 9) along with the nucleophilic cleavage step.
28. 2, 50 °C, 4 h. TON = 31.
29. 2, 50 °C, 4 h.