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note
-
Quantitative reaction efficiencies as a function of collision energy and collision gas pressure were also recorded; over the range of conditions examined, the isotope effects and product branching ratios did not change appreciably, although the overall reaction efficiency, i.e., yield, increased monotonically with increasing collision energy.
-
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28
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0038590356
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note
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The error bound on the isotope effect is computed for 95% certainty and comes from 30 independent measurements.
-
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29
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0037576256
-
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note
-
The error bounds on the branching ratio is computed for 95% certainty and comes from 50 independent measurements. The branching ratios were also constant over the range of collision energies studied, i.e., nominally -2 to 14 eV in the laboratory frame.
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-
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30
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0037576255
-
-
note
-
v[tetrafluoroethanel] of 1.13, which we used to normalize the gauge readings.
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note
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In Scheme 2, the structures should not be understood to mean that we have assigned a particular stereochemistry to the five-coordinate intermediates. The structures are presumed to undergo facile pseudorotation. The present experiments make no prediction concerning the stereochemistry.
-
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42
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0037576254
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note
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The X-ray structure of 1 is given in the Supporting Information; for related complexes, the X-ray structure was given in ref 6.
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44
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0037914337
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note
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+ with benzene, 1 and 3 should not be expected to show gross mechanistic differences.
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0038590355
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note
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3Pt(II) complex stabilized by an agostic interaction at the formally empty fourth coordination site, one cannot lightly discount three-coordinate species on the reaction coordinate.
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58
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0346665759
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0038251864
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note
-
From PM3 calculations on optimized geometries, one finds for trifluoroethanol and 1,1,1,2-tetrafluoroethane dipole moments of 2.2 and 2.3 D, respectively.
-
-
-
-
60
-
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0037914336
-
-
note
-
It should be noted that DFT calculations on model complexes in ref 5 find no evidence that TFE coordinates to the metal center in four-coordinate Pt(II) complexes as a fifth ligand.
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62
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Transition metal alkane complexes have been reviewed: Hall, C.; Perutz, R. Chem. Rev. 1996, 96, 3125.
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