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Volumn 128, Issue 6, 2006, Pages 2005-2016

Kinetics and mechanism of methane, methanol, and dimethyl ether C-H activation with electrophilic platinum complexes

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; ETHERS; HYDROGEN; METHANOL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PLATINUM; REACTION KINETICS; SAPPHIRE; SINGLE CRYSTALS; SOLUTIONS;

EID: 33244484149     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja056387t     Document Type: Article
Times cited : (94)

References (59)
  • 1
    • 0035323783 scopus 로고    scopus 로고
    • Arakawa, H. et al. Chem. Rev. 2001, 101, 953-996.
    • (2001) Chem. Rev. , vol.101 , pp. 953-996
    • Arakawa, H.1
  • 33
    • 33244495466 scopus 로고    scopus 로고
    • note
    • 2, MeOD), produced by alcoholysis of the C-O bond in a hydroxymethyl complex cannot be ruled out.
  • 34
    • 33244462965 scopus 로고    scopus 로고
    • note
    • Crystallographic data have been deposited at the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK and copies can be obtained on request, free of charge, by quoting the publication citation and the deposition number 267189.
  • 41
    • 0343244983 scopus 로고
    • and references therein
    • Thorn, D. L. Organometallics 1986, 5, 1897-1903 and references therein.
    • (1986) Organometallics , vol.5 , pp. 1897-1903
    • Thorn, D.L.1
  • 47
    • 33244476169 scopus 로고    scopus 로고
    • note
    • It can he seen from eq 6 that the rate can also fall off when [methanol] is sufficiently high that [TFE] decreases significantly: however, the data in Tables 5 and 6 show that this factor alone cannot account for the magnitude of the rate decrease.
  • 48
    • 2042507954 scopus 로고
    • In Suzuki couplings, which similarly involve transfer of organic groups from boron to transition metal centers, the transmetalating boronic acids can be activated by anions. See: Miyaura, N.; Suzuki, A. Chem. Rev. 1995, 95, 2457-2483.
    • (1995) Chem. Rev. , vol.95 , pp. 2457-2483
    • Miyaura, N.1    Suzuki, A.2
  • 55
    • 33244466420 scopus 로고    scopus 로고
    • note
    • See the Supporting Information to ref 14d for a discussion.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.