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3 were employed, isotope exchange was observed in the backbone methyl groups of the domine ligand; see ref 10a.
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Bromberg, S.E.1
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(f) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734-15735.
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Castro-Rodriguez, I.1
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82
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22944459007
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note
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13C, etc.; all values (Tables 2, 3, 5) are corrected for the values observed in unexchanged substrates.
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83
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22944457018
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note
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With the sterically smaller platinum methyl complex 2c (Ar = 3,5-di-tert-butylbenzene), similar trends were observed. For presentation of these data, refer to the Supporting Information.
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84
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22944454319
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note
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The distribution of platinum methyl cation isotopologs was estimated from comparison of the Pt-Me resonance with an aryl proton resonance. See the Supporting Information for more details.
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85
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2942735580
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3-complex via a palladocycle, see: Jones, G. D.; Anderson, T. J.; Chang, N.; Brandon, R. J.; Ong, G. L.; Vicic, D. A. Organometallics 2004, 23, 3071-3074.
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(2004)
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Jones, G.D.1
Anderson, T.J.2
Chang, N.3
Brandon, R.J.4
Ong, G.L.5
Vicic, D.A.6
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86
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22944451933
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note
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3-benzyl complex was proposed by Brookhart and co-workers; see ref 17b.
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87
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22944486139
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note
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When a sterically smaller ligand was employed (Ar = 3,5-dialkylbenzene), substantially more isotope exchange was observed in the recovered 1,4-diethylbenzene isotopologs.
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