On the first Insertion of α-olefins in hafnium pyridyl-amido polymerization catalysts

Organometallics

Volumn 28, Issue 18, 2009, Pages 5445-5458

  Zuccaccia, Cristiano ^a   Busico, Vincenzo ^b   Cipullo, Roberta ^b   Talarico, Giovanni ^b   Froese, Robert D J ^c   Vosejpka, Paul C ^c   Hustad, Phillip D ^c   Macchioni, Alceo ^a  

^a UNIVERSITY OF PERUGIA   (Italy)

^b UNIVERSITY OF NAPLES FEDERICO II   (Italy)

^c DOW CHEMICAL COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1-BUTENE; 1-HEXENE; 2-VINYLPYRIDINE; ACTIVE POLYMERIZATION; ACTIVE SPECIES; BUTYL GROUP; CLOSE PROXIMITY; COMPLICATED REACTIONS; COMPUTATIONAL DATA; DFT STUDY; DIASTEREOMERS; FAST POLYMERIZATION; HIGH MOLECULAR WEIGHT; HYDRIDE ABSTRACTION; IN-SITU; INITIATION AND PROPAGATION; ISOTACTICS; LOW TEMPERATURES; METHYL CATIONS; MIGRATORY INSERTION; ORDERS OF MAGNITUDE; POLYMER CHAINS; POLYMERIZATION CATALYSTS; PRECATALYSTS; PYRIDYL; SINGLE MONOMERS; TRIS(PENTAFLUOROPHENYL) BORANE;

BUTENES; CATALYSIS; CATALYSTS; HYDROCARBONS; MOLECULAR WEIGHT; MONOMERS; OLIGOMERS; POLYMERIZATION; POLYMERS; POSITIVE IONS; PROPYLENE; QUENCHING; RATE CONSTANTS;

HAFNIUM;

EID: 70349305680     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900705v     Document Type: Article

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