-
1
-
-
48749126558
-
-
U.S. Patent Appl. 0135722 A1, 2006
-
(a) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. U.S. Patent Appl. 0135722 A1, 2006.
-
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
-
2
-
-
48749110171
-
-
U.S. Patent 7,018,949
-
(b) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. U.S. Patent 7,018,949, 2006.
-
(2006)
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
-
3
-
-
48749132620
-
-
U.S. Patent 6,750,345
-
(c) Boussie, T. R.; Diamond, G. M.; Goh, C.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. U.S. Patent 6,750,345, 2004.
-
(2004)
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
LaPointe, A.M.4
Leclerc, M.K.5
Lund, C.6
Murphy, V.7
-
4
-
-
48749116088
-
-
U.S. Patent 6,713,577
-
(d) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. U.S. Patent 6,713,577, 2004.
-
(2004)
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
-
5
-
-
48749100262
-
-
U.S. Patent 6,706,829
-
(e) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. U.S. Patent 6,706,829, 2004.
-
(2004)
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
-
6
-
-
48749108804
-
-
PCT Int. Appl. WO 046249
-
(f) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. PCT Int. Appl. WO 046249, 2002.
-
(2002)
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
-
7
-
-
48749111681
-
-
PCT Pat. Appl. WO 038628
-
(g) Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V. PCT Pat. Appl. WO 038628, 2002.
-
(2002)
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
-
8
-
-
0037675228
-
-
Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Lund, C.; Murphy, V.; Shoemaker, J. A. W.; Tracht, U.; Turner, H.; Zhang, J.; Uno, T.; Rosen, R. K.; Stevens, J. C. J. Am. Chem. Soc. 2003, 125, 4306.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 4306
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Lund, C.7
Murphy, V.8
Shoemaker, J.A.W.9
Tracht, U.10
Turner, H.11
Zhang, J.12
Uno, T.13
Rosen, R.K.14
Stevens, J.C.15
-
9
-
-
33746238079
-
-
Boussie, T. R.; Diamond, G. M.; Goh, C.; Hall, K. A.; LaPointe, A. M.; Leclerc, M. K.; Murphy, V.; Shoemaker, J. A. W.; Turner, H.; Rosen, R. K.; Stevens, J. C.; Alfano, F.; Busico, V.; Cipullo, R.; Talarico, G. Angew. Chem., Int. Ed. 2006, 45, 3278.
-
(2006)
Angew. Chem., Int. Ed
, vol.45
, pp. 3278
-
-
Boussie, T.R.1
Diamond, G.M.2
Goh, C.3
Hall, K.A.4
LaPointe, A.M.5
Leclerc, M.K.6
Murphy, V.7
Shoemaker, J.A.W.8
Turner, H.9
Rosen, R.K.10
Stevens, J.C.11
Alfano, F.12
Busico, V.13
Cipullo, R.14
Talarico, G.15
-
11
-
-
48749128667
-
-
U.S. Patent Appl. 0220050 A1, 2004
-
(b) Frazier, K. A.; Boone, H.; Vosejpka, P. C.; Stevens, J. C. U.S. Patent Appl. 0220050 A1, 2004.
-
-
-
Frazier, K.A.1
Boone, H.2
Vosejpka, P.C.3
Stevens, J.C.4
-
12
-
-
48749107247
-
-
U.S. Patent Appl. 0087751 A1, 2004
-
(c) Tau, L.-M.; Cheung, Y. W.; Diehl, C. F.; Hazlitt, L. G. U.S. Patent Appl. 0087751 A1, 2004.
-
-
-
Tau, L.-M.1
Cheung, Y.W.2
Diehl, C.F.3
Hazlitt, L.G.4
-
13
-
-
48749088726
-
-
U.S. Patent Appl. 0242784 A1, 2004
-
(d) Tau, L.-M.; Cheung, Y. W.; Diehl, C. F.; Hazlitt, L. G. U.S. Patent Appl. 0242784 A1, 2004.
-
-
-
Tau, L.-M.1
Cheung, Y.W.2
Diehl, C.F.3
Hazlitt, L.G.4
-
14
-
-
48749093241
-
-
PCT Int. Appl. WO 040195 A1
-
(e) Coalter, J. N., III; Van Egmond, J. W.; Fouts, L. J., Jr.; Painter, R. B.; Vosejpka, P. C. PCT Int. Appl. WO 040195 A1, 2003.
-
(2003)
-
-
Coalter III, J.N.1
Van Egmond, J.W.2
Fouts Jr., L.J.3
Painter, R.B.4
Vosejpka, P.C.5
-
16
-
-
33646444730
-
-
Arriola, D. J.; Carnahan, E. M.; Hustad, P. D.; Kuhlman, R. L.; Wenzel, T. T. Science 2006, 312, 714.
-
(2006)
Science
, vol.312
, pp. 714
-
-
Arriola, D.J.1
Carnahan, E.M.2
Hustad, P.D.3
Kuhlman, R.L.4
Wenzel, T.T.5
-
17
-
-
34347244137
-
-
Froese, R. D. J.; Hustad, P. D.; Kuhlman, R. L.; Wenzel, T. T. J. Am. Chem. Soc. 2007, 129, 7831.
-
(2007)
J. Am. Chem. Soc
, vol.129
, pp. 7831
-
-
Froese, R.D.J.1
Hustad, P.D.2
Kuhlman, R.L.3
Wenzel, T.T.4
-
19
-
-
0033557814
-
-
Britovsek, G. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428.
-
(1999)
Angew. Chem., Int. Ed
, vol.38
, pp. 428
-
-
Britovsek, G.P.1
Gibson, V.C.2
Wass, D.F.3
-
22
-
-
15944365825
-
-
Axenov, K. V.; Martti, K.; Markku, L.; Repo, T. Organometallics 2005, 24, 1336.
-
(2005)
Organometallics
, vol.24
, pp. 1336
-
-
Axenov, K.V.1
Martti, K.2
Markku, L.3
Repo, T.4
-
23
-
-
0344206466
-
-
0 metals (values of 3-6 ppm indicate coordination; <3 ppm indicates non-coordination). See : Horton, A. D.; de With, J. Organometallics 1997, 16, 5424, and references therein.
-
0 metals (values of 3-6 ppm indicate coordination; <3 ppm indicates non-coordination). See : Horton, A. D.; de With, J. Organometallics 1997, 16, 5424, and references therein.
-
-
-
-
26
-
-
1042299850
-
-
Zuccaccia, C.; Stahl, N. G.; Macchioni, A.; Chen, M.-C.; Roberts, J. A.; Marks, T. J. J. Am. Chem. Soc. 2004, 126, 1448.
-
(2004)
Am. Chem. Soc
, vol.126
, pp. 1448
-
-
Zuccaccia, C.1
Stahl, N.G.2
Macchioni, A.3
Chen, M.-C.4
Roberts, J.A.5
Marks, T.J.J.6
-
29
-
-
0032481582
-
-
(b) Deck, P. A.; Beswick, C. L.; Marks, T. J. J. Am. Chem. Soc. 1998, 120, 1772.
-
(1998)
J. Am. Chem. Soc
, vol.120
, pp. 1772
-
-
Deck, P.A.1
Beswick, C.L.2
Marks, T.J.3
-
30
-
-
0037772311
-
-
Xu, Z.; Vanka, K.; Firman, T.; Michalak, A.; Zurek, E.; Zhu, C.; Ziegler, T. Organometallics 2002, 21, 2444.
-
(2002)
Organometallics
, vol.21
, pp. 2444
-
-
Xu, Z.1
Vanka, K.2
Firman, T.3
Michalak, A.4
Zurek, E.5
Zhu, C.6
Ziegler, T.7
-
31
-
-
48749094265
-
-
This value does not take into account the entropic effect. In fact, for the structure 3a we found two stable species with the same energy which differs for the relative configuration of the B(C6F5) 3 moiety. This is not true for 3a′
-
3 moiety. This is not true for 3a′.
-
-
-
-
32
-
-
30344488757
-
-
5-transfer to the metal see:(a) Phomphrai, K.; Fenwick, A. E.; Sharma, S.; Fanwick, P. E.; Caruthers, J. M.; Delgass, W. N.; Abu-Omar, M. M.; Rothwell, J. P. Organometallics 2006, 25, 214.
-
5-transfer to the metal see:(a) Phomphrai, K.; Fenwick, A. E.; Sharma, S.; Fanwick, P. E.; Caruthers, J. M.; Delgass, W. N.; Abu-Omar, M. M.; Rothwell, J. P. Organometallics 2006, 25, 214.
-
-
-
-
33
-
-
0001208657
-
-
(b) Metcalfe, R. A.; Kreller, D. I.; Tian, J.; Kim, H.; Taylor, N. J.; Corrigan, J. F.; Collins, S. Organometallics 2002, 21, 1719.
-
(2002)
Organometallics
, vol.21
, pp. 1719
-
-
Metcalfe, R.A.1
Kreller, D.I.2
Tian, J.3
Kim, H.4
Taylor, N.J.5
Corrigan, J.F.6
Collins, S.7
-
34
-
-
0035904260
-
-
(c) Woodman, T. J.; Thornton-Pett, M.; Hughes, D. L.; Bochmann, M. Organometallics 2001, 20, 4080.
-
(2001)
Organometallics
, vol.20
, pp. 4080
-
-
Woodman, T.J.1
Thornton-Pett, M.2
Hughes, D.L.3
Bochmann, M.4
-
35
-
-
0037806798
-
-
(d) Guerin, F.; Stewart, J. C.; Beddie, C.; Stephan, D. W. Organometallics 2000, 19, 2994-3000.
-
(2000)
Organometallics
, vol.19
, pp. 2994-3000
-
-
Guerin, F.1
Stewart, J.C.2
Beddie, C.3
Stephan, D.W.4
-
36
-
-
0006366786
-
-
(e) Scollard, J. D.; McConville, D. H.; Rettig, S. J. Organometallics 1997, 16, 1810.
-
(1997)
Organometallics
, vol.16
, pp. 1810
-
-
Scollard, J.D.1
McConville, D.H.2
Rettig, S.J.3
-
37
-
-
0028761731
-
-
(f) Yang, X. M.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015.
-
(1994)
J. Am. Chem. Soc
, vol.116
, pp. 10015
-
-
Yang, X.M.1
Stern, C.L.2
Marks, T.J.3
-
38
-
-
4043095478
-
-
and references therein. For a recent theroretical work see: g
-
For a recent theroretical work see: (g) Wondimagegn, T.; Xu, Z.; Vanka, K.; Ziegler, T. Organometallics 2004, 23, 3847, and references therein.
-
(2004)
Organometallics
, vol.23
, pp. 3847
-
-
Wondimagegn, T.1
Xu, Z.2
Vanka, K.3
Ziegler, T.4
-
39
-
-
33646389554
-
-
Krempner, C.; Kolckerling, M.; Reinke, H.; Weichert, K. Inorg. Chem. 2006, 45, 3203.
-
(2006)
Inorg. Chem
, vol.45
, pp. 3203
-
-
Krempner, C.1
Kolckerling, M.2
Reinke, H.3
Weichert, K.4
-
40
-
-
85169252711
-
-
Although structures of the hafnium-containing decomposition products were difficult to assign, the appearance of high frequency resonances in the 19F NMR spectrum (around-120 ppm) suggests the formation of Hf-C 6F5 fragments, Tonzetich, Z. J, Schrock, R. R. Polyhedron 2006, 25, 469
-
5 fragments : Tonzetich, Z. J.; Schrock, R. R. Polyhedron 2006, 25, 469.
-
-
-
-
41
-
-
0034510217
-
-
Schrock, R. R.; Casado, A. L.; Goodman, J. T.; Liang, L-C.; Bonitatebus, P. J. J.; Davis, W. M. Organometallics 2000, 19, 5325.
-
(2000)
Organometallics
, vol.19
, pp. 5325
-
-
Schrock, R.R.1
Casado, A.L.2
Goodman, J.T.3
Liang, L.-C.4
Bonitatebus, P.J.J.5
Davis, W.M.6
-
42
-
-
48749091634
-
-
3] ion pair (see Supporting Information).
-
3] ion pair (see Supporting Information).
-
-
-
-
43
-
-
0035823885
-
-
H34/H8 = 0.35. The distance between H7 and H8, 2.47 Å, Zuccaccia, C.; Bellachioma, G.; Cardaci, G.; Macchioni, A. J. Am. Chem. Soc. 2001, 123, 11020, was used as reference distance, affording 2.44 and 2.94 Å for H34/H17 and H34/H8 distances, respectively.
-
H34/H8 = 0.35. The distance between H7 and H8, 2.47 Å, (Zuccaccia, C.; Bellachioma, G.; Cardaci, G.; Macchioni, A. J. Am. Chem. Soc. 2001, 123, 11020, was used as reference distance, affording 2.44 and 2.94 Å for H34/H17 and H34/H8 distances, respectively.
-
-
-
-
44
-
-
0034069007
-
-
(a) Deckers, P. J. W.; van der Linden, A. J.; Meetsma, A.; Hessen, B. Eur. J. Inorg. Chem. 2000, 929.
-
(2000)
Eur. J. Inorg. Chem
, pp. 929
-
-
Deckers, P.J.W.1
van der Linden, A.J.2
Meetsma, A.3
Hessen, B.4
-
45
-
-
0011027920
-
-
(b) Lancaster, S. J.; Robinson, O. B.; Bochmann, M.; Coles, S. J.; Hursthouse, M. B. Organometallics 1995, 14, 2456.
-
(1995)
Organometallics
, vol.14
, pp. 2456
-
-
Lancaster, S.J.1
Robinson, O.B.2
Bochmann, M.3
Coles, S.J.4
Hursthouse, M.B.5
-
48
-
-
48749133070
-
-
The 1H NMR spectrum allows us to individuate some resonances of MeB(C6F5)2 and Me2B(C 6F5, dH, 0.96 and 1.33 ppm, respectively, while the appearance of high frequency (around-120 ppm) resonances in the 19F NMR spectrum suggests the formation of Hf-C6F5 fragments
-
5 fragments.
-
-
-
-
49
-
-
48749101262
-
-
The decomposition product could not be completely characterized; 1H NMR data are consistent with formation of a mixed-methyl-chloride hafnium species having a structure similar to 5a, together with [ClCD2NMe2Ph][B(C6F5)4, 1H NMR for the Hf species (CD2Cl2, 298 K, J values in Hz, d 8.71 (d, 3JHH, 8.4, H5, 8.67 (td, 3JHH, 7.4, 4J HH, 1.1, H7, 8.58 (d, 3JHH, 8.4, H3, 8.42 (t, 3JHH, 8.0, H13, 8.33 (dd, 3JHH, 8.4, 4JHH, 7.3, H2, 8.21 (dd, 3JHH, 7.3, 4JHH, 1.1, H1, 8.14 (d, 3J HH, 8.0, H12, 8.12 td, 3JHH, 7.3, 4JHH, 1
-
2, 298 K): 7.72 (m, 3 protons), 7.42 (m, 2 protons), 3.48 (s, 6 protons).
-
-
-
-
50
-
-
20344403071
-
-
For examples of amine activation, see: (a) Krut'ko, D. P, Borzov, M. V, Kirsanov, R. S, Churakov, A. V, Kuz'mina, L. G. J. Organomet. Chem. 2005, 690, 3243
-
For examples of amine activation, see: (a) Krut'ko, D. P.; Borzov, M. V.; Kirsanov, R. S.; Churakov, A. V.; Kuz'mina, L. G. J. Organomet. Chem. 2005, 690, 3243.
-
-
-
-
51
-
-
0001392548
-
-
(b) Pflug, J.; Bertuleit, A.; Kehr, G.; Fröhlich, R.; Erker, G. Organometallics 1999, 18, 3818.
-
(1999)
Organometallics
, vol.18
, pp. 3818
-
-
Pflug, J.1
Bertuleit, A.2
Kehr, G.3
Fröhlich, R.4
Erker, G.5
-
52
-
-
0037433240
-
-
For examples of N,N-bis-alkyl-aniline ortho-metallation see: (a) Solé, D, Vallverdù, L, Solans, X, Font-Bardìa, M, Bonjock, J. J. Am. Chem. Soc. 2003, 125, 1587
-
For examples of N,N-bis-alkyl-aniline ortho-metallation see: (a) Solé, D.; Vallverdù, L.; Solans, X.; Font-Bardìa, M.; Bonjock, J. J. Am. Chem. Soc. 2003, 125, 1587.
-
-
-
-
53
-
-
0033583543
-
-
(b) Drost, C.; Hitchcock, P. B.; Lappert, M. F. Angew. Chem., Int. Ed. 1999, 38, 1113.
-
(1999)
Angew. Chem., Int. Ed
, vol.38
, pp. 1113
-
-
Drost, C.1
Hitchcock, P.B.2
Lappert, M.F.3
-
54
-
-
0001045969
-
-
(c) Edema, J. J. H.; Gambarotta, S.; Meetsma, A.; Speks, A. L. Organometallics 1992, 11, 2452.
-
(1992)
Organometallics
, vol.11
, pp. 2452
-
-
Edema, J.J.H.1
Gambarotta, S.2
Meetsma, A.3
Speks, A.L.4
-
56
-
-
48749126557
-
-
m-H′, p-H and o-H interact with H35.
-
m-H′, p-H and o-H interact with H35.
-
-
-
-
57
-
-
24944548233
-
-
For similar isopropyl C-H activation reactions, see for example
-
(a) For similar isopropyl C-H activation reactions, see for example: Otten, E.; Dijkstra, P.; Visser, C.; Meetsma, A.; Hessen, B. Organometallics 2005, 24, 4374.
-
(2005)
Organometallics
, vol.24
, pp. 4374
-
-
Otten, E.1
Dijkstra, P.2
Visser, C.3
Meetsma, A.4
Hessen, B.5
-
58
-
-
0037467077
-
-
(b) Volkis, V.; Nelkenbaum, E.; Lisovskii, A.; Hasson, G.; Semiat, R.; Kapon, M.; Botoshansky, M.; Eishen, M.; Eisen, M. S. J. Am. Chem. Soc. 2003, 125, 2179.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 2179
-
-
Volkis, V.1
Nelkenbaum, E.2
Lisovskii, A.3
Hasson, G.4
Semiat, R.5
Kapon, M.6
Botoshansky, M.7
Eishen, M.8
Eisen, M.S.9
-
59
-
-
0034686736
-
-
(c) Tempel, D. J.; Johnson, L. K.; Huff, R. L.; White, P. S.; Brookhart, M. J. Am. Chem. Soc. 2000, 122, 6686.
-
(2000)
J. Am. Chem. Soc
, vol.122
, pp. 6686
-
-
Tempel, D.J.1
Johnson, L.K.2
Huff, R.L.3
White, P.S.4
Brookhart, M.5
-
60
-
-
48749099447
-
-
Reactions of 8b and 12 with molecular hydrogen at room temperature did not afford any reaction after several hours.
-
Reactions of 8b and 12 with molecular hydrogen at room temperature did not afford any reaction after several hours.
-
-
-
-
61
-
-
34248581879
-
-
Domski, G. J.; Lobkovsky, E. B.; Coates, G. W. Macromolecules 2007, 40, 3510-3513.
-
(2007)
Macromolecules
, vol.40
, pp. 3510-3513
-
-
Domski, G.J.1
Lobkovsky, E.B.2
Coates, G.W.3
-
62
-
-
48749090807
-
-
Unpublished results
-
Hustad, P. D.; Froese, R. D. J.; Zuccaccia, C.; Macchioni, A.; Busico, V.; Cipullo, R.; Talarico, G. Unpublished results.
-
-
-
Hustad, P.D.1
Froese, R.D.J.2
Zuccaccia, C.3
Macchioni, A.4
Busico, V.5
Cipullo, R.6
Talarico, G.7
|