Dialkyl and methyl-alkyl zirconocenes: Synthesis and characterization of zirconocene-alkyls that model the polymeryl chain in alkene polymerizations

Organometallics

Volumn 26, Issue 12, 2007, Pages 3018-3030

  Klamo, Sara B ^a,b   Wendt, Ola F ^a,c   Henling, Larry M ^a   Day, Michael W ^a   Bercaw, John E ^a,b  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b DOW CHEMICAL COMPANY   (United States)

^c LUND UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUPS; POLYMERYL; ZIRCONOCENE PRECATALYSTS; ZIRCONOCENES;

ALKYLATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; SANDWICH STRUCTURES; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

ORGANOMETALLICS;

EID: 34250766055     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0601302     Document Type: Article

References (44)

1. Jordan, R. F. Adv. Organomet. Chem. 1991, 32, 325-387.
2. Brintzinger, H. H.; Fischer, D.; Mulhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143-1170.
3. Wendt, O. F.; Bercaw, J. E. Unpublished results.
4. Landis, C. R.; Rosaaen, K. A.; Sillars, D. R. J. Am. Chem. Soc. 2003, 125, 1710-1711.
5. Mehrkhodavandi, P.; Bonitatebus, P. J.; Schrock, R. R. J. Am. Chem. Soc. 2000, 122, 7841-7842.
6. Chen, E. Y. X.; Marks, T. J. Chem. Rev. 2000, 100, 1391-1434.
7. Beswick, C. L.; Marks, T. J. J. Am. Chem. Soc. 2000, 122, 10358-10370.
8. Negishi, E.; Nguyen, T.; Maye, J. P.; Choueiri, D.; Suzuki, N.; Takahashi, T. Chem. Lett. 1992, 2367-2370.
9. Wendt, O. F.; Bercaw, J. E. Organometallics 2001, 20, 3891-3895.
10. Horton, A. D. Organometallics 1996, 15, 2675-2677.
11. Chirik, P. J.; Dalleska, N. F.; Henling, L. M.; Bercaw, J. E. Organometallics 2005, 24, 2789-2794.
12. Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025-1032.
13. Mehrkhodavandi, P.; Schrock, R. R. J. Am. Chem. Soc. 2001, 123, 10746-10747.
14. Mehrkhodavandi, P.; Schrock, R. R.; Pryor, L. L. Organometallics 2003, 22, 4569-4583.
15. Mehrkhodavandi, P. Ph.D. Thesis, Massachusetts Institute of Technology, 2002.
16. Collier, M. R.; Lappert, M. F.; Pearce, R. J. Chem. Soc., Dalton Trans. 1973, 445-451.
17. Jeffery, J.; Lappert, M. F.; Luongthi, N. T.; Webb, M.; Atwood, J. L.; Hunter, W. E. J. Chem. Soc., Dalton Trans. 1981, 1593-1605.
18. Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757-1762.
19. Jeffery, J.; Lappert, M. F.; Luongthi, N. T.; Atwood, J. L.; Hunter, W. E. J. Chem. Soc., Chem. Commun. 1978, 1081-1083.
20. Bochmann, M.; Lancaster, S. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 1634-1637.
21. Zuckerman, R. L.; Krska, S. W.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 751-761.
22. Brandow, C. G.; Bercaw, J. E. Unpublished results.
23. Wailes, P. C.; Weigold, H.; Bell, A. P. J. Organomet. Chem. 1972, 34, 155-164.
24. Jordan, R. F. J. Organomet. Chem. 1985, 294, 321-326.
25. Mehrkhodavandi, P.; Schrock, R. R.; Bonitatebus, P. J. Organometallics 2002, 21, 5785-5798.
26. (a) Chirik, P. J.; Bercaw, J. E. Unpublished results.
27. (b) For related synthetic strategy utilizing Grignard reagents see: Song, F. Q.; et al. Organometallics 2005, 24, 1315-1328.
28. Rogers, R. D.; Benning, M. M.; Kurihara, L. K.; Moriarty, K. J.; Rausch, M. D. J. Organomet. Chem. 1985, 293, 51-60.
29. Reynolds, K. A.; Ohagan, D.; Gani, D.; Robinson, J. A. J. Chem. Soc., Perkin Trans. 1 1988, 3195-3207.
30. Hajela, S. H.; Bercaw, J. E. Organometallics 1994, 13, 1147-1154.
31. Vogel, A. I. Vogel's Textbook of Practical Organic Chemistry, 5th ed.; Longman: New York, 1989.
32. Crossland, R. K.; Servis, K. L. J. Org. Chem. 1970, 35, 3195-3196.
33. Stevens, R. V.; Gaeta, F. C. A.; Lawrence, D. S. J. Am. Chem. Soc. 1983, 105, 7713-7719.
34. Bailey, W. F.; Punzalan, E. R. J. Org. Chem. 1990, 55, 5404-5406.
35. Negishi, E.; Swanson, D. R.; Rousset, C. J. J. Org. Chem. 1990, 55, 5406-5409.
36. Klamo, S. B.; Wendt, O. F.; Bercaw, J. E. Manuscript in preparation.
37. Burger, B. J.; Bercaw, J. E. New Developments in the Synthesis, Manipulation, and Characterization of Organometallic Compounds; American Chemical Society: Washington, DC, 1987; Vol. 357.
38. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520.
39. Marvich, R. H.; Brintzinger, H. H. J. Am. Chem. Soc. 1971, 93, 2046-2048.
40. Wolczanski, P. T.; Bercaw, J. E. Organometallics 1982, 1, 793-799.
41. Surtees, J. R. Chem. Commun. 1965, 567.
42. Schrock, R. R.; Fellmann, J. D. J. Am. Chem. Soc. 1978, 100, 3359-3370.
43. Tessier-Youngs, C.; Beachley, O. T., Jr. Inorg. Synth. 1986, 24, 95-97.
44. Coates, G. E.; Heslop, J. A. J. Chem. Soc. A 1968, 514-518.