Tetrakis(alkylthio)-substituted lutetium bisphthalocyanines for sensing NO2 and O3

Sensors and Actuators, B: Chemical

Volumn 142, Issue 1, 2009, Pages 73-81

  Kilinç, Necmettin ^a   Atilla, Devrim ^a   Gürek, Ayşe Gül ^a   Öztürk, Zafer Ziya ^a,b   Ahsen, Vefa ^a,b  

^a GEBZE TECHNICAL UNIVERSITY   (Turkey)

^b MATERIALS INSTITUTE   (Turkey)

Author keywords

Liquid crystal; Lutetium phthalocyanine; NO2 and O3 sensing; Oxygen doping; Thin films

Indexed keywords

ALKYL CHAIN LENGTHS; CONCENTRATION RANGES; CONDUCTION MECHANISM; DOPING EFFECTS; DRY AIR; HIGH PURITY; LIQUID CRYSTAL PHASE; LUTETIUM PHTHALOCYANINE; NITROGEN DIOXIDES; NO2 AND O3 SENSING; OHMIC BEHAVIOR; OPERATION TEMPERATURE; OXIDIZING GAS; OXYGEN DOPING; RESPONSE TIME; ROOM TEMPERATURE; SENSING PROPERTY; SENSOR RESPONSE; SOLID-PHASE; SPACE-CHARGE-LIMITED; TEMPERATURE RANGE; TETRAKIS;

LIQUID CRYSTALS; MICROCOMPUTERS; NITROGEN OXIDES; OZONE; SENSORS; THIN FILMS;

LUTETIUM;

EID: 70349241518     PISSN: 09254005     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.snb.2009.07.015     Document Type: Article

References (56)

1. Snow A.W., and Barger W.R. In: Lever A.B.P. (Ed). Phthalocyanines: Properties and Applications vol. 1 (1989), John Wiley and Sons, New York p. 341
2. Wilson A., and Collins R.A. Electrical characteristics of planar phthalocyanine thin-film gas sensors. Sens. Actuators 12 (1987) 389-403
3. Armstrong N.R. Phthalocyanines and porphyrins as materials. J. Porphyrins Phthalocyanines 4 (2000) 414-417
4. Guillaud G., Simon J., and Germain J. Metallophthalocyanines - gas sensors, resistors and field effect transistors. Coord. Chem. Rev. 178 (1998) 1433-1484
5. Simon J., and Bassoul P. Design of Molecular Materials: Supramolecular Engineering (2000), John Wiley & Sons, New York pp. 256-291 (Chapter 6)
6. Simon J., and Andre J.J. Molecular Semiconductors Photoelectrical Properties and Solar Cells (1985), Springer-Verlag, Berlin pp. 28-63 (Chapter 2)
7. Albert K.J., Lewis N.S., Schauer C.L., Sotzing G.A., Stitzel S.E., Vaid T.P., and Walt D.R. Cross-reactive chemical sensor arrays. Chem. Rev. 100 (2000) 2595-2626
8. Gürek A.G., and Bekaroǧlu O. Octakis(alkylthio)-substituted phthalocyanines and their interactions with silver(I) and palladium(II) ions. J. Chem. Soc. - Dalton Trans. 9 (1994) 1419-1423
9. Piechocki C., Simon J., Skoulios A., Guillon D., and Weber P. Discotic mesophases obtained from substituted metallophthalocyanines-toward liquid-crystalline one-dimensional conductors. J. Am. Chem. Soc. 104 (1982) 5245-5247
10. Turek P., Petit P., Andre J.J., Simon J., Even R., Boudjema B., Guillaud G., and Maitrot M. A new series of molecular semiconductors - phthalocyanine radicals 2. J. Am. Chem. Soc. 109 (1987) 5119-5122
11. Trometer M., Even R., Simon J., Dubon A., Lava1 J.Y., Germain J.P., Maleysson C., Pauly A., and Robert H. Lutetium bisphthalocyanine thin-films for gas-detection. Sens. Actuators B: Chem. 8 (1992) 129-135
12. Komatsu T., Ohta K., Watanabe T., Ikemoto H., Fujimoto T., and Yamamoto I. Discotic liquid-crystals of transition-metal complexes. 18. Discotic liquid-crystalline behavior in phthalocyanine compounds substituted by steric hindrance groups at the core. J. Mater. Chem. 4 (1994) 537-540
13. Gürek A.G., Basova T., Luneau D., Lebrun C., Kol'tsov E., Hassan A.K., and Ahsen V. Synthesis, structure, and spectroscopic and magnetic properties of mesomorphic octakis(hexylthio)-substituted phthalocyanine rare-earth metal sandwich complexes. Inorg. Chem. 45 (2006) 1667-1676
14. Bouvet M., and Pauly A. In: Grimes C.A., Dickey E.C., and Pishko M.V. (Eds). The Encyclopedia of Sensors vol. 6 (2006), American Scientific Publishers, Stevenson Ranch, CA, USA p. 227
15. Rodríguez-Méndez M.L. In: Grimes C.S., Dickey E.C., and Pishko MV (Eds). Encyclopedy of Sensors vol. 9 (2006), American Scientific Publishers, CA, USA p. 111
16. 2 with lutetium bisphthalocyanine thin-films. Synth. Met. 55-57 (1993) 3754-3759
17. Passard M., Blanc J.P., and Maleysson C. Gaseous oxidation and compensating reduction of lutetium bis-phthalocyanine and lutetium phthalo-naphthalocyanine films. Thin Solid Films 271 (1995) 8-14
18. 2 on the electrical conductivity of lutetium phthalo-naphthalocyanine thin films. Synth. Met. 80 (1996) 25-28
19. Zhou Q., and Gould R.D. The effects of oxygen doping and annealing on the surface and bulk electrical conductivity in planar copper phthalocyanine thin films for gas-sensing applications. Thin Solid Films 317 (1998) 432-435
20. van Faassen E., and Kerp H. Explanation of the low oxygen sensitivity of thin film phthalocyanine gas sensors. Sens. Actuators B: Chem. 88 (2003) 329-333
21. Varghese C., and Menon C.S. Electrical properties of nickel phthalocyanine thin films using gold and lead electrodes. J. Mater. Sci.: Mater. Electron. 17 (2006) 149-153
22. Anthopoulos T.D., and Shafai T.S. Low frequency capacitance characterization of alpha-phase nickel phthalocyanine/lead interfaces: effects of temperature and oxygen doping. J. Phys. Chem. Solids 65 (2004) 1345-1348
23. Anthopoulos T.D., and Shafai T.S. Alternating current conduction properties of thermally evaporated alpha-nickel phthalocyanine thin films: effects of oxygen doping and thermal annealing. J. Appl. Phys. 94 (2003) 2426-2433
24. Anthopoulos T.D., and Shafai T.S. Oxygen induced p-doping of alpha-nickel phthalocyanine vacuum sublimed films: Implication for its use in organic photovoltaics. Appl. Phys. Lett. 82 (2003) 1628-1630
25. Anthopoulos T.D., and Shafai T.S. Influence of oxygen doping on the electrical and photovoltaic properties of Schottky type solar cells based on alpha-nickel phthalocyanine. Thin Solid Films 441 (2003) 207-213
26. Varghese C., and Menon C.S. Conduction in magnesium phthalocyanine thin films with aluminium electrodes. Eur. Phys. J. B 52 (2006) 465-468
27. Rajesh K.R., and Menon C.S. Investigation of electrical properties of organic Schottky diodes using MgPc - the effect of oxygen absorption and post deposition annealing. Semicond. Sci. Technol. 20 (2005) 464-468
28. 2. Thin Solid Films 474 (2005) 301-305
29. Kerp H.R., Westerduin K.T., van Veen A.T., and van Faassen E.E. Quantification and effects of molecular oxygen and water in zinc phthalocyanine layers. J. Mater. Res. 16 (2001) 503-511
30. Kerp H.R., and van Faassen E.E. Effects of oxygen on exciton transport in zinc phthalocyanine layers. Chem. Phys. Lett. 332 (2000) 5-12
31. Rajesh K.R., and Menon C.S. Influence of oxygen and post deposition annealing on the electrical properties of MnPc and MnPcCl Schottky barrier devices. J. Mater. Sci. 40 (2005) 1115-1120
32. Samuel M., Menon C.S., and Unnikrishnan N.V. The influence of oxygen doping on the transport properties of aluminium phthalocyanine chloride Schottky-barrier devices. Semicond. Sci. Technol. 21 (2006) 677-680
33. Zhou R., Jose F., Gopel W., Ozturk Z.Z., and Bekaroglu O. Phthalocyanines as sensitive materials for chemical sensors. Appl. Organometall. Chem. 10 (1996) 557-577
34. Atilla D., Ki{dotless}li{dotless}nç N., Yüksel F., Gürek A.G., Öztürk Z.Z., and Ahsen V. Synthesis, characterization, mesomorphic and electrical properties of tetrakis(alkylthio)-substituted lutetium(III) bisphthalocyanines. Synth. Met. 159 (2009) 13-21
35. Gould R.D. Structure and electrical conduction properties of phthalocyanine thin films. Coord. Chem. Rev. 156 (1996) 237-274
36. Ki{dotless}li{dotless}nç N., Ahsen A.S., Atilla D., Gürek A.G., San S.E., Öztürk Z.Z., and Ahsen V. Electrical properties of mesomorphic phthalocyanine-carbon nanotube composites. Sens. Lett. 6 (2008) 607-612
37. Clarisse C., Riou M.T., and Robinet S. Evidence for intrinsic and extrinsic semiconducting properties of lutetium diphthalocyanine thin films. Synth. Met. 38 (1990) 121-126
38. Rodriguez-Mendez M.L., Aroca R., DeSaja J.A., and Electrochromic. gas adsorption properties of Langmuir-Blodgett films of lutetium bisphthalocyanine complexes. Chem. Mater. 5 (1993) 933-937
39. Bouvet M. Phthalocyanine-based field-effect transistors as gas sensors. Anal. Bioanal. Chem. 384 2 (2006) 366-373
40. Bouvet M., Guillaud G., Leroy A., Maillard A., Spirkovitch S., and Tournilhaca F.-G. Phthalocyanine-based feld-effect transistor as ozone sensor. Sens. Actuators B: Chem. 73 (2001) 63-70
41. Ki{dotless}li{dotless}nç N., Atilla D., Öztürk S., Gürek A.G., Öztürk Z.Z., and Ahsen V. Oxidizing gas sensing properties of mesogenic copper octakisalkylthiophthalocyanine chemoresistive sensors. Thin Solid Films 517 (2009) 6206-6210
42. Campbell D., and Collins R.A. A study of the interaction between nitrogen dioxide and lead phthalocyanine using electrical conduction and optical absorption. Thin Solid Films 295 1-2 (1997) 277-282
43. Zhou Q., and Gould R.D. A study of the response rate to nitrogen dioxide exposure in metal phthalocyanine thin film sensors. Thin Solid Films 317 1-2 (1998) 436-439
44. Rella R., Serra A., Siciliano A., Tepore A., Valli L., and Zocco A. Applications in gas-sensing devices of a new macrocyclic copper complex. Sens. Actuators B: Chem. 42 1 (1997) 53-58
45. Fernandes A.N., and Richardson T.H. Characterisation and gas-sensing properties of tert-butyl silicon-[bis ethyloxy]-phthalocyanine LB films. Colloids Surf.-Physicochem. Eng. Aspects 284 (2006) 335-338
46. Ho K.C., and Tsou Y.H. Chemiresistor-type NO gas sensor based on nickel phthalocyanine thin films. Sens. Actuators B: Chem. 77 1-2 (2001) 253-259
47. Maggioni G., Carturan S., Tonezzer M., Quaranta A., and Della Mea G. Plasma-deposited copper phthalocyanine: a single gas-sensing material with multiple responses. Sens. Actuators B: Chem. 131 2 (2008) 496-503
48. 2 sensing characteristics of copper phthalocyanine films: effects of low temperature annealing and doping time. Sens. Actuators B: Chem. 119 1 (2006) 174-179
49. Lee Y.L., Hsiao C.Y., Chang C.H., and Yang Y.M. Effects of sensing temperature on the gas sensing properties of copper phthalocyanine and copper tetra-tert-butyl phthalocyanine films. Sens. Actuators B: Chem. 94 2 (2003) 169-175
50. 2-sensing properties of octa-iso-pentyloxymetallonaphthalocyanine spin-coated films. Sens. Actuators B: Chem. 123 1 (2007) 94-100
51. Ding X.M., and Xu H.J. Gas-sensing properties of asymmetrically substituted amphiphilic phthalocyanines. Sens. Actuators B: Chem. 65 1-3 (2000) 108-110
52. Dooling C.M., Richardson T.H., Valli L., Rella R., and Jiang J. NO2 sensitivity of gadolinium bis-phthalocyanine assemblies prepared by ultra-fast LB deposition. Colloids Surf.-Physicochem. Eng. Aspects 198 (2002) 791-796
53. 2 doping on the gas sensing properties of copper phthalocyanine thin film devices. Thin Solid Films 360 1-2 (2000) 10-12
54. 2 detection. Sens. Actuators B: Chem. 118 1-2 (2006) 249-254
55. Dogo S., Germain J.P., Maleysson C., and Pauly A. Gas-sensing properties of metallo-phthalocyanine thin-films as a function of their crystalline-structure. Sens. Actuators B: Chem. 8 3 (1992) 257-259
56. Wang B., Zuo X., Wu Y.Q., and Chen Z.M. Preparation, characterization and gas sensing properties of lead tetra-(tert-butyl)-5,10,1 5,20-tetraazaporphyrin spin-coating films. Sens. Actuators B: Chem. 125 1 (2007) 268-273