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Volumn 9, Issue 6, 2009, Pages 2848-2852

Inorganic - Organic hybrid materials with novel framework structures: Synthesis, structure, and magnetic properties of [Ni(py) 4] 2V 10O 29 and [Ni 2(py) 5(H 2O) 3]V 4O 12

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EID: 66849095462     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg9001237     Document Type: Article
Times cited : (23)

References (48)
  • 40
    • 84868977691 scopus 로고    scopus 로고
    • A Mettler Toledo TGA/SDTA 851E thermogravimetric analyzer (TGA) was used to obtain TGA curves. A 10 mg sample of 1-2 was placed in a 70 mL alumina pan and heated from 25 to 1000 °C at a rate of 5 °C/min in nitrogen atmosphere with a flow rate of 60-90 mL/min.
    • A Mettler Toledo TGA/SDTA 851E thermogravimetric analyzer (TGA) was used to obtain TGA curves. A 10 mg sample of 1-2 was placed in a 70 mL alumina pan and heated from 25 to 1000 °C at a rate of 5 °C/min in nitrogen atmosphere with a flow rate of 60-90 mL/min.
  • 41
    • 66849100034 scopus 로고    scopus 로고
    • SMART, Version 4.210; Siemens Analytical X-Ray Systems: Madison, WI, 1997
    • SMART, Version 4.210; Siemens Analytical X-Ray Systems: Madison, WI, 1997.
  • 42
    • 66849126367 scopus 로고    scopus 로고
    • SAINT, Version 6.36A; Bruker AXS: Madison, WI, 2001
    • SAINT, Version 6.36A; Bruker AXS: Madison, WI, 2001.
  • 43
    • 84868980368 scopus 로고    scopus 로고
    • Sheldrick, G. M. SADABS, Version 2.10; University of Göttingen: Gottingen, Germany, 2002
    • Sheldrick, G. M. SADABS, Version 2.10; University of Göttingen: Gottingen, Germany, 2002.
  • 44
    • 66849092054 scopus 로고    scopus 로고
    • Sheldrick, G. M. SHELXTL Version 6.12; Broker AXS, Madison, WI, 2001
    • Sheldrick, G. M. SHELXTL Version 6.12; Broker AXS, Madison, WI, 2001.
  • 45
    • 84868977689 scopus 로고    scopus 로고
    • A reaction mixture consisting of V2O5 (0.45 mmol, NiCl2 · 6H2O (0.25 mmol, 1,4-C6H 4(COOH)2 (0.55 mmol, H2O (555.6 mmol, and C5H5N (12.2 mmol) was placed in a 23 mL Teflon-lined Parr autoclave. After the mixture was stirred for 30 seconds, the reaction vessel was closed and heated in a furnace maintained at 145 °C for 6 days. The furnace was then turned off, and the reaction vessel, which was left inside the furnace, was cooled slowly to room temperature over a period of 24 h. Dark green needle-like crystals of 1, which were mixed with a brown powdery impurity, were filtered from the yellow mother liquor. The crystals were separated from the powder mechanically and dried in air at room temperature to give ∼50 mg of 1 yield ∼ 22.5% based on vanadium
    • 5N (12.2 mmol) was placed in a 23 mL Teflon-lined Parr autoclave. After the mixture was stirred for 30 seconds, the reaction vessel was closed and heated in a furnace maintained at 145 °C for 6 days. The furnace was then turned off, and the reaction vessel, which was left inside the furnace, was cooled slowly to room temperature over a period of 24 h. Dark green needle-like crystals of 1, which were mixed with a brown powdery impurity, were filtered from the yellow mother liquor. The crystals were separated from the powder mechanically and dried in air at room temperature to give ∼50 mg of 1 (yield ∼ 22.5% based on vanadium).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.