A new inorganic-organic hybrid material containing a neutral three-dimensional open framework: Synthesis and characterization of [{Co 2(4,4′-tmdp)4}V4O12] (4,4′-tmdp = 4,4′-trimethylenedipyridine)

Inorganic Chemistry Communications

Volumn 9, Issue 1, 2006, Pages 25-28

  Khan, M Ishaque ^a   Deb, Sangita ^a   Doedens, Robert J ^b  

^a Illinois Institute of Technology   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Crystal structure; Framework structure; Hybrid material; Hydrothermal synthesis; Solid state NMR model compound

Indexed keywords

EID: 29544438052     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2005.09.033     Document Type: Article

References (34)

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27. 2 is 1.123. Further details of the structure determination are available on request from the Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, UK (e-mail: deposit@ccdc.camac.uk ) by quoting the depository number CCDC 272579 (http://www.ced.cam.uk ).
28. The infrared spectrum was recorded from a KBr pellet by use of a Thermonicolet Nexus 470 spectrometer.
29. A Mettler Toledo TGA/SDTA 851E thermogravimetric analyzer (TGA) was used to obtain TGA curves. A 10 mg sample of 1 was placed in a 70 ml alumina pan and heated from 25 to 1000°C at a rate of 5°C/min in nitrogen atmosphere with a flow rate of 60-90 ml/min.
30. Room temperature magnetic susceptibility measurement was made on a 137 mg sample of 1 using a Johnson Matthey MSB-Auto magnetic susceptibility balance.
31. 2O (555.5 mmol) and ethanol (85.6 mmol) was sealed in a 23 ml teflon-lined Parr reaction vessel and heated to 80°C for 7 days (initial pH 4.65). The reaction vessel was cooled to room temperature and crystals of 1, obtained in pure form and higher yield, were filtered from the mother liquor and dried in air at the room temperature. Anal. Calcd.: C, 47.75; H, 4.52; N, 8.98. Found: C, 46; H, 4.49; N, 8.16.
32. The temperature dependent magnetic susceptibility studies of 1 and other materials of this series (which are at various stages of their characterization) is in progress and the results will be reported in a future publication.
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