Mixed-valence and neutral framework inorganic-organic hybrid materials: Synthesis, characterization, and magnetic properties of [{Co(N(CH) 4N)}(V 2O 5) 2] and [{Co(N(CH) 4N)}V 2O 6]

Chemistry of Materials

Volumn 19, Issue 20, 2007, Pages 4890-4895

  Khan, M Ishaque ^a   Yohannes, Elizabeth ^a   Golub, Vladimir O ^b   O'Connor, Charles J ^b   Doedens, Robert J ^c  

^a Illinois Institute of Technology   (United States)

^b UNIVERSITY OF NEW ORLEANS   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATIONIC METAL; MANGANOMETRIC TITRATION; NEUTRAL FRAMEWORK;

INFRARED SPECTROSCOPY; INORGANIC COMPOUNDS; MAGNETIC SUSCEPTIBILITY; THERMAL EFFECTS; THERMOGRAVIMETRIC ANALYSIS; VANADIUM COMPOUNDS;

COBALT COMPOUNDS;

EID: 35348911518     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm071415n     Document Type: Article

References (63)

1. Hybrid Materials: Synthesis, Characterization, and Applications; Kickelbick, G., Ed.; Wiley-VCH: Weinheim, 2007.
2. (a) Horcajaba, P.; Serre, C.; Regi, M. V.; Sebban, M.; Taulelle, F.; Ferez, G. Angew. Chem., Int. Ed. 2006, 45, 5974-5978.
3. (b) Hupp, J. T.; Poeppelmeier, K. R. Science 2005, 309, 2008-2009.
4. Eddaoudi, M.; Moler, D.; Li, H.; Chen, B.; Reineke, T.; O'Keeffe, M.; Yaghi, O. Acc. Chem. Res. 2001, 34, 319-330 and references therein.
5. Kitagawa, S.; Kitaura, R. Comments Inorg. Chem. 2002, 23, 101-126.
6. Lee, E. Y.; Jang, S. Y.; Suh, M. P. J. Am. Chem. Soc. 2005, 127, 6374-6381.
7. Seo, J. S.; Whang, D.-M.; Lee, H.-Y.; Jun, S. I.; Oh, J.-H.; Jeon, Y.-J.; Kim, K. Nature 2000, 404, 982-986.
8. Wu, C.-D.; Hu, A.; Zang, L.; Lin, W. J. Am. Chem. Soc. 2005, 127, 8940-8941.
9. Albrecht, M.; Lutz, M.; Spek, A. L.; Van Koten, G. Nature 2000, 406, 970-974.
10. Modular Chemistry; Michl, J., Ed.; Kluwer Academic Publishers; Dordrecht, 1995 (and references therein).
11. Yaghi, O. M.; Li, H.; Davis, C.; Richardson, D.; Groy, T. L. Acc. Chem. Res. 1998, 31, 474-484 and references therein.
12. Eddaoudi, M.; Li, H.; M.; Yaghi, O. J. Am. Chem. Soc. 2000, 122, 1391-1397.
13. Chen, B.; Eddaoudi, M.; Hyde, S.; O', Keeffe, M.; Yaghi, O. Science 2001, 291, 1021-1023.
14. Hagrman, D.; Warren, C. J.; Haushalter, R. C.; Seip, C.; O' Connor, C. J.; Rarig, J. R. L.; Johnson, K. M.; Laduca, J. R. L.; Zubieta, J. Chem. Mater. 1998, 10, 3294-3297.
15. Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. 1999, 38, 2638-2684 and references therein.
16. Zapf, P. J.; Warren, C. J.; Haushalter, R. C.; Zubieta, J. Chem. Commun. 1997, 1543.
17. (a) Hagrman, D.; Haushalter, R. C.; Zubieta, J. Chem. Mater. 1998, 10, 361.
18. (b) Hagrman, D.; Zubieta, J. J. Solid State Chem. 2000, 152, 141.
19. (c) Hagrman, D.; Zubieta, C.; Rose, D. J.; Zubieta, J. Angew. Chem., Int. Ed. 1997, 36, 873.
20. (d) Hagrman, D.; Zubieta, J. Chem. Commun. 1998, 2005-2006.
21. (e) Zapf, P. J.; Hammond, R. P.; Haushalter, R. C.; Zubieta, J. Chem. Mater. 1998, 10, 1366-1373.
22. (a) Khan, M. I.; Cevik, S.; Doedens, R. In Polyoxometalate Chemistry for Nano-Composite Design; Yamase, T., Pope, M. T., Eds.; Kluwer Academic: New York, 2002; pp 27-38.
23. (b) Khan, M. I.; Yohannes, E.; Ayesh, S.; Doedens, R. J. J. Mol. Struct. 2003, 656, 45-53.
24. (c) Khan, M. I.; Yohannes, E.; Doedens, R. J. Inorg. Chem. 2003, 42, 3125-3129.
25. (a) Khan, M. I.; Cevik, S.; Powell, D.; Li, S.; O'Connor, C. J. Inorg. Chem. 1998, 37, 81-86.
26. (b) Khan, M. I.; Cevik, S.; Doedens. R. J. Chem. Soc., Chem. Commun. 2001, 1930-1931.
27. (a) Khan, M. I.; Tabussum, S.; Doedens, R. J. Chem. Commun. 2003, 532-533.
28. (b) Khan, M. I.; Tabussum, S. and Doedens, R. J.; Golub, V. O.; O'Connor, C. J. Inorg. Chem. Commun. 2004, 7, 54.
29. (a) Khan, M. I.; Yohannes, E.; Doedens, R. J. Angew. Chem., Int. Ed. 1999, 38, 1292.
30. (b) Khan, M. I.; Hope, T.; Cevik, S.; Zheng, C.; Powell, D. J. Cluster Sci. 2000, 11, 433-447.
31. (a) Khan, M. I.; Ayesh, S.; Yohannes, E.; Doedens, R. J. Front. Biosci. 2003, 8, 177-183.
32. (b) Khan, M. I.; Giri, S.; Ayesh, S.; Doedens, R. J. Inorg. Chem. Commun. 2004, 7/6, 721-724.
33. Khan, M. I.; Yohannes, E.; Nome, R.; Ayesh, S.; Golub, V. O.; O'Connor, C. J.; Doedens, R. J. Chem. Mater. 2004, 16, 5273-5279.
34. (a) Khan, M. I.; Yohannes, E.; Doedens, R. J.; Golub, V. O.; O'Connor, C. J. Inorg. Chem. Commun. 2005, 8, 841-845.
35. (b) Khan, M. I.; Deb S.; Golub, V. O.; O'Connor, C. J.; Doedens, R. J. Inorg. Chem. Commun. 2006, 9, 25-28.
36. Khan, M. I.; Deb S.; Nome, R.; Yohannes, E.; Cevik, S.; Doedens, R. Unpublished work.
37. (a) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer: Berlin, 1983.
38. (b) Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. 1991, 30, 34-48.
39. (c) Pope, M. T. In Comprehensive Coordination Chemistry II: From Biology to Nanotechnology; Wedd, A. G., Ed.; Elsevier: Oxford, 2004; Vol. 4, pp 635-678.
40. (d) Hill, C. L. In Comprehensive Coordination Chemistry II: From Biology to Nanotechnology; Wedd, A. G., Ed.; Elsevier: Oxford, 2004; Vol. 4, pp 679-759.
41. (a) Bjornberg, A.; Hedman, B. Acta Chem. Scand. 1977, A31, 579-584.
42. (b) Hawthorne, F. C. J. Solid State Chem. 1997, 22, 157-170.
43. (c) Baudrin, E.; Touboul, M.; Nowogrocki, G. J. Solid State Chem. 2000, 152, 511-516.
44. (a) Koene, B.; Taylor, N.; Nazar, L. Angew. Chem., Int. Ed. 1999, 38, 2888-2891 and references therein.
45. (b) Shan, Y.; Huang, R.; Huang, S. Angew. Chem., Int. Ed. 1999, 38, 1751-1754.
46. Dyer, A. An Introduction to Zeolite Molecular Sieves; Wiley: New York, 1988.
47. Barrer, R. M. Hydrothermal Chemistry of Zeolites; Academic Press: London, 1982.
48. O'Connor, C. J. Prog. Inorg. Chem. 1979, 29, 203.
49. SMART, Version 4.210; Simens Analytical X-Ray Systems: Madison, WI, 1997
50. SAINT, Version 4.050; Simens Analytical X-Ray Systems: Madison, WI, 1995.
51. Sheldrick, G. M. SADABS; University of Gottingen: Gottingen, Germany, 1997.
52. Sheldrick, G. M. SHELXTL, Version 5.1; Siemens Industrial Automation, Inc.; Madison, WI, 1995.
53. Bellamy, L. J. The Infrared Spectra of Complex Molecules; John Wiley & Sons: New York, 1975; pp 279-320.
54. Lord, R. C.; Warston, A. L.; Miller, F. A. Spectrochim. Acta 1957, 9, 113-125.
55. Ferraro, J. R. Low-Frequency Vibration of Inorganic and Coordination Compounds; Plenum Press: New York, 1971; pp 191-246.
56. Topacli, A. Spectrochim. Acta 1995, 51A, 633-641.
57. Waal, D.; Heyns, A. M. Mater. Res. Bull. 1992, 27, 129-136.
58. Wery, A. S. J.; Zorrilla, J. M. G.; Luque, A.; Ugalde, M.; Roman, P. Chem. Mater. 1996, 5, 408-413.
59. Brown, I. D.; Wu, K. K. Acta Crystallogr. 1976, B32, 1957-1959.
60. Enjalbert, R.; Gaily, J. Acta Crystallogr. 1986, C42, 1467-1469.
61. 1 showed typical problems associated with attempted refinement of a centrosymmetric structure in a noncentrosymmetric subgroup: large correlations, large parameter shifts, higher R-values, and non-positive definite displacement parameters.
62. Shan, Y.; Huang, R.; Huang, S. D. Angew. Chem., Int. Ed. 1999, 38, 1751-1754.
63. Kanatzidis, M. G.; Wu, C.-G. J. Am. Chem. Soc. 1989, 111, 4139-4141.