Chemistry: Gas adsorption sites in a large-pore metal-organic framework

Science

Volumn 309, Issue 5739, 2005, Pages 1350-1354

  Rowsell, Jesse L C ^a   Spencer, Elinor C ^b   Eckert, Juergen ^c,d   Howard, Judith A K ^b   Yaghi, Omar M ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

^b DURHAM UNIVERSITY   (United Kingdom)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARGON; DATA ACQUISITION; NITROGEN; SINGLE CRYSTALS; X RAY DIFFRACTION ANALYSIS; ZINC OXIDE;

ANGSTROMS; CUBIC STRUCTURE; PHENYLENE; STRUCTURAL INTEGRITY;

GAS ADSORPTION;

ARGON; CARBON DIOXIDE; DICARBOXYLIC ACID DERIVATIVE; METAL; METAL OXIDE; NITROGEN; ZINC OXIDE;

ADSORPTION; ARGON; NITROGEN;

ADSORPTION; ARTICLE; CRYSTAL; GAS; PRIORITY JOURNAL; THERMOGRAVIMETRY; X RAY DIFFRACTION;

EID: 24044503751     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1113247     Document Type: Article

References (33)

1. M. Eddaoudi et al., Science 295, 469 (2002).
2. S. Kitagawa, R. Kitaura, S.-I. Noro, Angew. Chem. Int. Ed. Engl. 43, 2334 (2004).
3. O. M. Yaghi et al., Nature 423, 705 (2003).
4. H. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, Nature 402, 276 (1999).
5. H. K. Chae et al., Nature 427, 523 (2004).
6. G. Férey et al., Angew. Chem. Int. Ed. Engl. 43, 6296 (2004).
7. S.-I. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem. Int. Ed. Engl. 39, 2082 (2000).
8. K. Seki, W. Mori, J. Phys. Chem. B 106, 1380 (2002).
9. N. L. Rosi et al., Science 300, 1127 (2003).
10. C. Férey et al., Chem. Comm. 2003, 2976 (2003).
11. D. N. Dybtsev, H. Chun, S. H. Yoon, D. Kim, K. Kim, J. Am. Chem. Soc. 126, 32 (2004).
12. J. L. C. Rowsell, A. R. Millward, K. S. Park, O. M. Yaghi, J. Am. Chem. Soc. 126, 5666 (2004).
13. A. Zecchina, C. Otero Areán, Chem. Soc. Rev. 25, 187 (1996).
14. R. Kitaura et al., Science 298, 2358 (2002).
15. Y. Kubota et al., Angew. Cnem. Int. Ed. Engl. 44, 920 (2005).
16. 2-loaded structure varies between 25.794 ± 0.004 Å at 293 K and 25.898 ± 0.004 Å at 30 K. Results of the refinements of the evacuated,
17. 2-loaded crystal structures (in CIF format) have been deposited as CCDC 277428-277437. These data can be obtained free of charge via www.ccdc.cam.acuk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax, (+44)1223-336-033; or deposit@ccdc.cam.ac.uk].
18. A. E. Goeta, J. A. K. Howard, Chem. Soc. Rev. 33, 490 (2004).
19. C. S. Barrett, L. Meyer, J. Chem. Phys. 41, 1078 (1964).
20. A. F. Schuch, R. L. Mills, J. Chem. Phys. 52, 6000 (1970).
21. J. Eckert, W. D. Ellenson, J. B. Hastings, L. Passeli, Phys. Rev. Lett. 43, 1329 (1979).
22. M. Trabelsi, J. P. Coulomb, D. Degenhardt, H. Lauter, Surf. Sci. 377-379, 38 (1997).
23. E. D. Sloan Jr., Clathrate Hydrates of Natural Gases (Dekker, New York, ed. 2, 1998), ch. 2.
24. S. Takamizawa, E. I. Nakata, H. Yokoyama, K. Mochizuki, W. Mori, Angew. Chem. Int. Ed. Engl. 42, 4331 (2003).
25. J. L. Atwood, L. J. Barbour, A. Jerga, Science 296, 2367 (2002); published online 9 May 2002 (10.1126/ science.1072252).
26. C.-R. Anderson, D. F. Coker, J. Eckert, A. L. R. Bug, J. Chem. Phys. 111, 7599 (1999).
27. J. A. McKinnon, D. F. Coker, J, Eckert, A. L. R. Bug, J. Chem. Phys. 114, 10137 (2001).
28. R. Kahn, E. Cohen de Lara, E. Viennet, J. Chem. Phys. 91, 5097 (1989).
29. E. Cohen de Lara, R. Kahn, Zeolites 12, 256 (1992).
30. R. Nowak, J. A. Menapace, E. R. Bernstein, J. Chem. Phys. 89, 1309 (1988).
31. T. Weber, A. von Bargen, E. Riedle, H. J. Neusser, J. Chem. Phys. 92, 90 (1990).
32. J. S. O. Evans, Dalton Trans. 1999, 3317 (1999).
33. Supported by NSF, U.S. Department of Energy (O.M.Y.), the Link Foundation, Natural Sciences and Engineering Research Council of Canada (J.L.C.R.), the Institut Laue-Langevin (E.C.S.), and the Engineering and Physical Sciences Research Council (Senior Research Fellowship, J.A.K.H.). We thank C. J. McIntyre (Institut Laue-Langevin) for helpful discussions.