Clay profiling: The classification of montmorillonites

Clays and Clay Minerals

Volumn 57, Issue 1, 2009, Pages 104-114

  Emmerich, Katja ^a   Wolters, Felicitas ^b,e   Kahr, Guenter ^c   Lagaly, Gerhard ^d  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^c ETH ZURICH   (Switzerland)

^d UNIVERSITY OF KIEL   (Germany)

^e NONE   (Germany)

Author keywords

2:1 layer silicates; Cis vacant; Classification; Dioctahedral; Layer charge; Montmorillonite; Smectite; Trans vacant

Indexed keywords

2:1 LAYER SILICATES; CIS-VACANT; CLASSIFICATION; DIOCTAHEDRAL; LAYER CHARGE; MONTMORILLONITE; SMECTITE; TRANS-VACANT;

ALUMINUM; METALLIC COMPOUNDS; POLYETHYLENE TEREPHTHALATES; POSITIVE IONS; SILICATE MINERALS; STRUCTURAL ANALYSIS; THERMOANALYSIS; X RAY DIFFRACTION ANALYSIS;

CLAY MINERALS;

CHEMICAL COMPOSITION; CLASSIFICATION; CRYSTAL STRUCTURE; MONTMORILLONITE; X-RAY DIFFRACTION;

EID: 65549121268     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.2009.0570110     Document Type: Article

References (79)

1. Bailey, S.W. (1980) Summary of recommendations of AIPEA nomenclature committee. Clays and Clay Minerals, 28, 73-78.
2. Bailey, S.W. (1982) Nomenclature for regular interstratifications. American Mineralogist, 67, 394-398.
3. Bergaya, F., Lagaly, G., and Vayer, M. (2006) Cation and anion exchange. Pp. 979-1001 in: Handbook of Clay Science (F. Bergaya, B.K.G. Theng, and G. Lagaly, editors). Elsevier, Amsterdam.
4. Brigatti, M.F. (1983) Relationship between composition and structure in Fe-rich smectites. Clay Minerals, 18, 177-186.
5. Brigatti, M.F. and Poppi, L. (1981) A mathematical model to distinguish the members of the dioctahedral smectite series. Clay Minerals, 16, 81-89.
6. Brindley, G.W. and Brown, G., editors (1980) Crystal Structures of Clay Minerals and their X-ray Identification. Monograph 5, Mineralogical Society, London, 495 pp.
7. Brindley, G.W. and Pedro, G. (1972) Report of the AIPEA Nomenclature Committee, AIPEA Newsletter, 4, 8-13.
8. Brown, G. (1955) Report of the clay minerals group subcommittee on nomenclature of clay minerals. Clay Minerals Bulletin, 2, 294-301.
9. Carrado, K.A., Decarreau, A., Petit, S., Bergaya, F., and Lagaly, G. (2006) Synthetic clay minerals and purification of natural clays. Pp. 115-139 in: Handbook of Clay Science (F. Bergaya, B.K.G. Theng, and G. Lagaly, editors). Elsevier, Amsterdam.
10. Christidis, G.E. and Eberl, D.D. (2003) Determination of layer-charge characteristics. Clays and Clay Minerals, 51, 644-655.
11. Čičel, B. and Komadel, P. (1994) Structural formulae of layer silicates. Pp. 114-136 in: Quantitative Methods in Soil Mineralogy. Miscellaneous Publication, Soil Science Society of America, Madison, Wisconsin, USA.
12. Cole, W.F. (1955) Interpretation of differential thermal curves of mixed-layer minerals of illite and montmorillonite. Nature, 175, 384-385.
13. Cole, W.F. and Hosking, J.S. (1957) Clay mineral mixtures and interstratified minerals. Pp. 248-274 in: The Differential Thermal Investigation of Clays (R.C. Mackenzie, editor). Monograph 2, Mineralogical Society, London.
14. Dohrmann, R. (1999) Aufbereitung der Tonminerale - Von der Probezum Präparat In 2. European Workshop on Clay Mineralogy (A. Bauer, editor). Jena.
15. Drits, V.A. (2003) Structural and chemical heterogeneity of layer silicates and clay minerals. Clay Minerals, 38, 403-432.
16. Drits, V.A., Besson, G., and Muller, F. (1995) An improved model for structural transformations of heat-treated aluminous dioctahedral 2:1 layer silicates. Clays and Clay Minerals, 43, 718-731.
17. Drits, V.A., Lindgreen, H., Salyn, A.L., Ylagan, R., and McCarty, D.K. (1998) Semiquantitative determination of trans-vacant and cis-vacant 2:1 layers in illites and illitesmectites by thermal analysis and X-ray diffraction. American Mineralogist, 83, 1188-1198.
18. Drits, V.A., Lindgreen, H., Sakharov, B.A., Jakobsen, H.J., and Zviagina, B.B. (2004) The detailed structure and origin of clay minerals at the Cretaceous/Tertiary boundary, Stevns Klint (Denmark). Clay Minerals, 39, 367-390.
19. Drits, V.A., McCarty, D.K., and Zviagina, B.B. (2006) Crystal-chemical factors responsible for the distribution of octahedral cations over trans- or cis-cites in dioctahedral 2:1 layer silicates. Clays and Clay Minerals, 54, 131-152.
20. Emmerich, K. (2000) Spontaneous rehydroxylation of a dehydroxylated cis-vacant montmorillonite. Clay and Clay Minerals, 48, 405-408.
21. Emmerich, K., Madsen, F.T., and Kahr, G. (1999) Dehydroxylation behavior of heat-treated and steam treated homoionic cis-vacant montmorillonites. Clays and Clay Minerals, 47, 591-604.
22. Emmerich, K. and Wolters, F. (2005) The role of cross-checks for the classification of montmorillonites. Berichte der Deutschen Ton- und Tonmineralgruppe, 11, 14.
23. Ferrage, E., Lanson, B., Sakharov, B.A., and Drits, V.A. (2005) Investigation of smectite hydration properties by modeling experimental X-ray diffraction patterns: Part I. Montmorillonite hydration properties. American Mineralogist, 90, 1358-1374.
24. Ferrage, E., Lanson, B., Sakharov, B.A., Geoffroy, N., Jacquot, E., and Drits, V.A. (2007) Investigation of smectite hydration properties by modeling experimental X-ray diffraction patterns: Part II. Influence of layer charge and charge location. American Mineralogist, 92, 1731-1743.
25. Greene-Kelly, R. (1955) Dehydration of montmorillonite minerals. Mineralogical Magazine, 30, 604-615.
26. Grim, R.E. and Kulbicki, G. (1961) Montmorillonite: High temperature reactions and classification. American Mineralogist, 46, 1329-1369.
27. Guggenheim, S., Adams, J.M., Bain, D.C., Bergaya, F., Brigatti, M.F., Drits, V., Formoso, M.L., Galán, E., Kogure, T., and Stanjek, H. (2006) Summary of recommendations of nomenclature committees relevant to clay mineralogy: report of the Association Internationale pour l'Etude des Argiles (AIPEA) Nomenclature Committee for 2006. Clays and Clay Minerals, 54, 761-772.
28. Güven, N. (1988) Smectites. Pp. 497a552 in: Hydrous Phyllosilicates (S.W. Bailey, editor). Reviews in Mineralogy, 19, Mineralogical Society of America, Washington, D.C.
29. Harvey, C. and Lagaly, G. (2006) Conventional applications. Pp. 501-540 in: Handbook of Clay Science (F. Bergaya, B.K.G. Theng, and G. Lagaly, editors). Elsevier Amsterdam.
30. Heller, L., Farmer, V.C., Mackenzie, R.C., Mitchell, B.D., and Taylor, H.F.W. (1962) The dehydroxylation and rehydroxylation of triphormic dioctahedral clay minerals. Clay Minerals Bulletin, 5, 56-72.
31. Hofmann, U., Endell, K., and Wilm, D. (1933) Kristallstruktur und Quellung von Montmorillonit. Zeitschrift für Kristallographie, 86, 340-349.
32. Hofmann, U. and Klemen, R. (1950) Verlust der Austauschfähigkeit von Lithiumionen aus Bentonit durch Erhitzung. Zeitschrift für Anorganische und Allgemeine Chemie, 262, 95-99.
33. Janek, M., Komadel, P., and Lagaly, G. (1997) Effect of autotransformation on the layer charge of smectites determined by the alkylammonium method. Clay Minerals, 32, 623-632.
34. Jasmund, K. and Lagaly, G. (editors) (1993) Tonminerale und Tone. Steinkopff Verlag, Darmstadt, Germany.
35. Kaufhold, S., Dohrmann, R., Ufer, K., and Meyer, F.M. (2002) Comparison of methods for the quantification of montmorillonite in bentonites. Applied Clay Science, 22, 145-151.
36. Köster, H.M. (1977) Die Berechnung kristallchemischer Strukturformeln von 2:1 a Schichtsilikaten unter Berücksichtigung der gemessenen Zwischenschichtladungen und Kationenumtauschkapazitäten, sowie der Darstellung der Ladungsverteilung in der Struktur mittels Dreieckskoordinaten. Clay Minerals, 12, 45-54.
37. Köster, H.M. (1979) Die chemische Silikatanalyse. Springer-Verlag, Heidelberg, Germany, pp. 61-62.
38. Köster, H.M. and Schwertmann, U. (1993) Dreischichtminerale. Pp. 33-58 in: Tonminerale und Tone (K. Jasmund and G. Lagaly, editors). Steinkopf Verlag, Darmstadt, Germany.
39. Lagaly, G. (1981) Characterization of clays by organic compounds. Clay Minerals, 16, 1-21.
40. Lagaly, G. (1994) Layer charge determination by alkylammonium ions. Pp. 1-46 in: Layer Charge Characteristics of 2:1 Silicate Clay Minerals (A.R. Mermut, editor). Workshop Lecture Volume, 6, The Clay Minerals Society, Boulder, Colorado, USA.
41. Lagaly, G. (2006) Colloid clay science. Pp. 141-245: Handbook of Clay Science (F. Bergaya, B.K.G. Theng, and G. Lagaly, editors). Elsevier, Amsterdam.
42. Lagaly, G. and Weiss, A. (1970a) Anordnung und Orientierung kationischer Tenside auf ebenen Silicatoberflächen Teil I. Kolloid-Zeitschrift und Zeitschrift für Polymere, 237, 266-272.
43. Lagaly, G. and Weiss, A. (1970b) Anordnung und Orientierung kationischer Tenside auf ebenen Silicatoberflächen Teil II. Kolloid-Zeitschrift und Zeitschrift für Polymere, 237, 364-368.
44. Lagaly, G. and Weiss, A. (1970c) Anordnung und Orientierung kationischer Tenside auf ebenen Silicatoberflächen Teil III. Kolloid-Zeitschrift und Zeitschrift für Polymere, 238.
45. Lagaly, G. and Weiss, A. (1971) Anordnung und Orientierung kationischer Tenside auf ebenen Silicatoberflächen Teil IV. Kolloid-Zeitschrift und Zeitschrift für Polymere, 243, 48-55.
46. Laird, D.A., Scott, A.D., and Fenton, T.E. (1989) Evaluation of the alkylammonium method of determining layer charge. Clays and Clay Minerals, 37, 41-46.
47. MacEwan, D.M.C., Ruiz Amil, A., and Brown, G. (1961) Interstratified clay minerals. Pp. 393-445 in: The X-ray Identification and Crystal Structures of Clay Minerals (G. Brown, editor). Mineralogical Society, London.
48. Mackenzie, R.C. (1959) The classification and nomenclature of clay minerals. Clay Minerals Bulletin, 4, 52-66.
49. Mackenzie, R.C. and Bishui, B.M. (1958) The montmorillonite differential thermal curve. II. Effect of exchangable cations on the dehydroxylation of normal montmorillonite. Clay Minerals Bulletin, 20, 276-286.
50. Maes, A., Stuhl, M.S., and Cremers, A. (1979) Layer charge-cation exchange capacity relationships in montmorillonite. Clay and Clay Minerals, 27, 387-392.
51. Malfoy, C., Pantet, A., Monnet, P., and Righi, D. (2003) Effects of thenat ureof the exchangeable cation and clay concentration on the rheological properties of smectite suspensions. Clays and Clay Minerals, 51, 656-663.
52. Martin, R.T., Bailey, S.W., Eberl, D.D., Fanning, D.S., Guggenheim, S., Kodama, H., Pevear, D.R., Środoń, J., and Wicks, F.J. (1991) Report of the Clay Minerals Society nomenclature committee: Revised classification of clay materials. Clays and Clay Minerals, 39, 333-335.
53. Mehra, O.P. and Jackson, M.L. (1960) Iron oxide removal from soils and clays by a dithionite-citrate-system buffered with sodium bicarbonate. Pp. 317-327 in: 7th National conference on Clays and Clay Minerals (A. Swineford, editor). Pergamon Press, Washington, D.C.
54. Moore, D.M. and Reynolds Jr., R.C. (1997) X-ray diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, New York.
55. Nickel, E.H. and Grice, J.D. (1998) The IMA Commission on new minerals and mineral names: Procedures and guidelines on nomenclature. The Canadian Mineralogist, 36, 3-16.
56. Olis, A.C., Malla, P.B., and Douglas, L.A. (1990) The rapid estimation of the layer charges of 2:1 expanding clays from a single alkylammonium ion expansion. Clay Minerals, 25, 39-50.
57. Plötze, M. and Kahr, G. (2005) Diagnostic intercalation in clay minerals. Berichte der Deutschen Ton- und Tonmineralgruppe, 11, 51-55.
58. Rieder, M., Cavazzini, G., D'Yakanov, Y., Frank-Kamenetskii, V.A., Gottardi, G., Guggenheim, S., Koval, P.V., Müller, G., Neiva, A.M.R., Radoslovich, E.W., Robert, J.-L., Sassi, F.P., Takeda, H., Weiss, Z., and Wones, D.R. (1998) Nomenclature of micas. The Canadian Mineralogist, 36, 41-48.
59. Ross, C.S. and Hendricks, S.B. (1945) Minerals of the Montmorillonite Group. United States Geological Survey Professional Paper, No. 205-B, 79 pp.
60. Sainz-Diaz, C.I., Palin, E.J., Hernández-Laguna, A., and Dove, M.T. (2004) Effect of the tetrahedral charge on the order-disorder of the cation distribution in the octahedral sheet of smectites and illites by computional methods. Clays and Clay Minerals, 52, 357-374.
61. Schultz, L.G. (1969) Lithium and potassium absorption, dehydroxylation temperature and structural water content of aluminous smectites. Clays and Clay Minerals, 17, 115-149.
62. Smith, D.K., Roberts, A.C., Bayliss, P., and Liebau, F. (1998) A systematic approach to general and structure-type formulas for minerals and other inorganic phases. American Mineralogist, 83, 126-132.
63. Steudel, A., Batenburg, L., Fischer, H., and Emmerich, K. Structural modifications of several clay minerals during acid treatment. Euroclay '07, Aveiro, Portugal.
64. Stevens, R.E. (1945) A system for calculating analyses of micas and related minerals to end members. U.S. Geological Survey Bulletin, 950, 101-119.
65. Tributh, H. and Lagaly, G.A. (1986) Aufbereitung und Identifizierung von Boden- und Lagerstättentonen. I. Aufbereitung der Proben im Labor. GIT Fachzeitschrift für das Laboratorium, 30, 524-529.
66. Tsipursky, S.I. and Drits, V.A. (1984) The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique texture electron diffraction. Clay Minerals, 19, 177-192.
67. Ufer, K., Roth, G., Kleeberg, R., Stanjek, H., Dohrmann, R., and Bergmann, J. (2004) Description of X-ray powder pattern of turbostratically disordered layer structures with a Rietveld compatible approach. Zeitschrift für Kristallographie, 219, 519-527.
68. Ufer, K., Stanjek, H., Roth, G., Dohrmann, R., Kleeberg, R., and Kaufhold, S. (2008) Quantitative phase analysis of bentonites by the Rietveld method. Clays and Clay Minerals, 56, 272-282.
69. van Olphen, H. (1963) An Introduction to Clay Colloid Chemistry. Interscience Publisher, New York.
70. Vogt, K. and Köster, H.M. (1978) Zur Mineralogie, Kristallchemie und Geochemie einiger Montmorillonite aus Bentoniten. Clay Minerals, 13, 25-43.
71. Wagner, F.E. and Wagner, U. (2004) Mössbauer Spectra of Clays and Ceramics. Kluwer Academic Publishers, The Netherlands.
72. Walker, G.F. (1958) Reactions of expanding lattice minerals with glycerol and ethylene glycol. Clay Minerals Bulletin, 3, 302-313.
73. Warshaw, C.M. and Roy, R. (1961) Classification and a scheme for the identification of layer silicates. Geological Society of American Bulletin, 72, 1455-1492.
74. Wiewióra, A. (1990) Crystallochemical classifications of phyllosilicates based on the unified system of projection of chemical composition. I. The mica group. Clay Minerals, 25, 23-81.
75. 3+-montmorillonite. Proceedings of the 1st Latin American Clay Conference, Funchal 2000, Volume 1 aInvited lectures, pp. 237-244.
76. Wolters, F. (2005) Classification of montmorillonites. PhD thesis, Universität Karlsruhe, Germany, 98 pp.
77. Wolters, F. and Emmerich, K. (2007) Thermal reactions of smectites a relation of dehydroxylation temperature to octahedral structure. Thermochimica Acta, 462, 80-88.
78. Wolters, F., Lagaly, G., Kahr, G., Nuesch, R., and Emmerich, K. (2009) A comprehensive characterisation of dioctahedral smectites. Clays and Clay Minerals, 57, 115-133.
79. Zvyagin, B.B. (2001) Current problems with the nomenclature of phyllosilicates. Clays and Clay Minerals, 49, 492-499.