Chapter 12.10 Cation and Anion Exchange

Developments in Clay Science

Volumn 1, Issue C, 2006, Pages 979-1001

  Bergaya, F ^a   Lagaly, G ^b   Vayer, M ^a  

^a UNIVERSITÉ D'ORLÉANS   (France)

^b UNIVERSITY OF KIEL   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77957078792     PISSN: 15724352     EISSN: None     Source Type: Book Series    
DOI: 10.1016/S1572-4352(05)01036-6     Document Type: Review

References (122)

1. Abollino O., Aceto M., Malandrino M., Sarzanini C., and Mentasti E. Adsorption of heavy metals on Na-montmorillonite. Effect of pH and organic substances. Water Research 37 (2003) 1619-1627
2. Adams J.M., and Evans S. Determination of the cation-exchange capacity (layer charge) of small quantities of clays minerals by nephelometry. Clays and Clay Minerals 27 (1979) 137-139
3. Altin O., Özbelge H.O., and Doǧu T. Use of general purpose adsorption isotherms for heavy metal-clay mineral interactions. Journal of Colloid and Interface Science 198 (1998) 130-140
4. Amacher M.C., Henderson R.E., Breithaupt M.D., Seale C.L., and Labauve J.M. Unbuffered and buffered salt methods for exchangeable cations and effective cation exchange capacity by potentiometric titration using divalent cation electrodes. Soil Science Society of America Journal 54 (1990) 1036-1042
5. Ammann L., Bergaya F., and Lagaly G. Determination of the cation exchange capacity of clays with copper complexes revisited. Clay Minerals 40 (2005) 441-453
6. Anderson S.J., and Sposito G. Cesium-adsorption method for measuring accessible structural surface charge. Soil Science Society of America Journal 55 (1991) 1569-1576
7. API. Recommended practice standard procedure for laboratory testing drilling fluids. API Recommended Practice 13 (1990) 1
8. Auboiroux M., Melou F., Bergaya F., and Touray J.C. Hard and soft acid-base model applied to bivalent cation selectivity on a 2:1 clay mineral. Clays and Clay Minerals 46 (1998) 546-555
9. Bache B.W. Barium isotope method for measuring cation-exchange capacity of soils and clays. Journal of the Science of Food and Agriculture 21 (1970) 169-171
10. Bache B.W. The measurement of cation exchange capacity of soils. Journal of the Science of Food and Agriculture 27 (1976) 273-280
11. Bain D.C., and Smith B.F.L. Chemical analysis. In: Wilson M.J. (Ed). A Handbook of Determinative Methods in Clay Mineralogy (1987), Blackie, Glasgow 248-274
12. 4 and its organic derivatives. Clay Minerals 17 (1982) 175-183
13. Bereket G., Aroǧuz A.Z., and Özel M.Z. Removal of Pb(II), Cd(II), Cu(II), and Zn(II) from aqueous solutions by adsorption on bentonite. Journal of Colloid and Interface Science 187 (1997) 338-343
14. Bergaya F., and Vayer M. CEC of clays: measurement by adsorption of a copper ethylene-diamine complex. Applied Clay Science 12 (1997) 275-280
15. 2+. Acta Agricultura Scandinavica 30 (1980) 460-468
16. Bergseth H. Selektierungsvermögen eines Eisenoxidhydroxids und einiger Tonminerale gegenüber Phosphat und Sulfationen. Acta Agricultura Scandinavica 35 (1985) 375-388
17. Bowden J.W., Posner A.M., and Quirk J.P. Adsorption and charging phenomena in variable charge soils. In: Theng B.K.G. (Ed). Soils with Variable Charge (1980), New Zealand Society of Soil Science, Lower Hutt 147-166
18. Brindley G.W., and Thompson T.D. Methylene blue adsorption by montmorillonite: determination of surface areas and exchange capacity with different initial cation saturations. Israel Journal of Chemistry 8 (1970) 409-415
19. Brouwer E., Baeyens B., Maes A., and Cremers A. Cesium and rubidium ion equilibria in illite clay. Journal of Physical Chemistry 87 (1983) 1213-1219
20. Burrafato G., and Miano F. Determination of the cation exchange of clays by surface tension measurements. Clay Minerals 28 (1993) 475-481
21. Busenberg E., and Clemency C.V. Determination of the cation exchange capacity of clays and soils using an ammonia electrode. Clays and Clay Minerals 21 (1973) 213-218
22. Chhabra R., Pleysier J., and Cremers A. The measurement of CEC and exchangeable cations in soils: a new method. In: Bailey S.W. (Ed). Proceedings of the International Clay Conference 1975 (1976), Applied Publishing, Wilmette, IL 439-449
23. Chiu Y.C., Huang N.L., Uang C.M., and Huang J.F. Determination of cation exchange capacity of clays minerals. Colloids and Surfaces 46 (1990) 327-337
24. Cornell R.M., and Aksoyoglu E.S. Simultaneous determination of the cation exchange capacity and the exchangeable cations on marl. Clay Minerals 26 (1991) 567-570
25. Dakshinamurti C., and Bhavanarayana M. An isoconductivity method for determining the cation exchange capacity of soils and clays. Catena 9 (1982) 175-179
26. Eberl D.D. Alkali cation selectivity and fixation by clay minerals. Clays and Clay Minerals 28 (1980) 161-172
27. El-Batouti M., Sadek O.M., and Assaad F.F. Kinetics and thermodynamic studies of copper exchange on Na-montmorillonite clay mineral. Journal of Colloid and Interface Science 259 (2003) 223-227
28. Ferris A.P., and Jepson W.B. The exchange capacities of kaolinite and the preparation of homoionic clays. Journal of Colloid and Interface Science 51 (1975) 245-259
29. Fletcher P., and Sposito G. The chemical modelling of clay-electrolyte interactions for montmorillonite. Clay Minerals 24 (1989) 375-391
30. Fox R.L. Soils with variable charge: agronomic and fertility aspects. In: Theng B.K.G. (Ed). Soils with Variable Charge (1980), New Zealand Society of Soil Science, Lower Hutt 195-224
31. Francis C.W., and Grigal D.F. A rapid and simple procedure using Sr 85 for determining cation exchange capacities of soils and clays. Soil Science 112 (1971) 17-21
32. Fraser A.R., and Russell J.D. A spectrophotometric method for determination of cation exchange capacity of clay minerals. Clay Minerals 8 (1969) 229-230
33. Gast R.G. Alkali metal exchange on Chambers montmorillonite. Soil Sience Society of America Proceedings 36 (1972) 14-19
34. Gast R.G. Surface and colloid chemistry. In: Dixon J.B., and Weed S.B. (Eds). Minerals in Soil Environments (1977), Soil Science Society of America, Madison, WI 27-73
35. Gast R.G., and Klobe D. Sodium-lithium exchange equilibria on vermiculite at 25 °C and 50 °C. Clays and Clay Minerals 19 (1971) 311-319
36. Gillmann G.P., Bruce R.C., Davey B.G., Kimble J.M., Searle P.L., and Skjemstad J.O. A comparison of methods used for determination of cation exchange capacity. Communications in Soil Science and Plant Analysis 14 (1983) 1005-1014
37. Glaeser, R., 1946. Détermination de la capacité d'échange de base dans la montmorillonite. Comptes Rendus de l′Académie des Sciences, Paris, vol. 222, pp. 1179-1181.
38. Goldberg S. Use of surface complexation models in soil chemical systems. Advances in Agronomy 47 (1992) 233-329
39. Goulding K.W.T., and Talibudeen O. Heterogeneity of cation-exchange sites for K-Ca exchange in aluminosilicates. Journal of Colloid and Interface Science 78 (1980) 15-24
40. Greenhill N.B., and Peverill K.I. Determination of cation exchange capacity of soils using ammonia and chloride electrodes. Communications in Soil Science and Plant Analysis 8 (1977) 579-589
41. Grim R.E. Clay Mineralogy. 2nd edition (1968), McGraw-Hill, New York
42. Hang P.T., and Brindley G.W. Methylene blue adsorption by clay minerals. Determination of surface areas and cation exchange capacities (Clay-organic studies XVIII). Clays and Clay Minerals 18 (1970) 203-212
43. Hanna M.T., Zaghloul A.A., El-Batouti M., and El-Shazly S.A. Solvent effect on the kinetics of the exchange of copper ions on Na-montmorillonite. Journal of Colloid and Interface Science 176 (1995) 418-421
44. Hillier S., and Clayton T. Cation exchange 'staining ' of clay minerals in thin-section for electron microscopy. Clay Minerals 27 (1992) 379-384
45. Hirsch D., Nir S., and Banin A. Prediction of cadmium complexation in solution and adsorption to montmorillonite. Soil Science Society of America Journal 53 (1989) 716-721
46. Hissink D.J. Base exchange in soils. Transactions of the Faraday Society 20 (1924) 550-566
47. Inoue A., and Minato H. Ca-K exchange reaction and interstratification in montmorillonite. Clays and Clay Minerals 27 (1979) 393-401
48. Ioannou A., and Dimirkou A. Phosphate adsorption on hematite, kaolinite, and kaolinite-hematite systems as described by a constant capacitance model. Journal of Colloid and Interface Science 192 (1997) 119-128
49. Janek M., and Lagaly G. Interaction of a cationic surfactant with bentonite: a colloid chemistry study. Colloid and Polymer Science 281 (2003) 293-301
50. Jasmund, K., Lagaly, G. (Eds.), 1993, Tonminerale und Tone. Struktur, Eigenschaften, Anwendung und Einsatz in Industrie und Umwelt. Steinkopff Verlag, Darmstadt.
51. Johnson S.W. On some points of agricultural science. American Journal of Science and Arts, Series 2 28 (1859) 71-85
52. Kahr G., and Madsen F.T. Determination of the cation exchange capacity and the surface area of bentonite, illite and kaolinite by methylene blue adsorption. Applied Clay Science 9 (1995) 327-336
53. Kjellander R. Ion-ion correlations and effective charges in electrolyte and macroion systems. Berichte der Bunsengesellschaft für Physikalische Chemie 100 (1996) 894-904
54. Klobe W.D., and Gast R.G. Reactions affecting cation exchange kinetics in vermiculite. Soil Science Society of America Proceedings 31 (1967) 744-749
55. Kodama H., Ross G.J., Toshimichi J., and Robert J.W. Effect of layer charge location on potassium exchange and hydration of mica. American Mineralogist 59 (1974) 491-495
56. 2+ ion exchange. Journal of Materials Chemistry 9 (1999) 533-539
57. 2EDTA system. Colloids and Surfaces A136 (1998) 299-310
58. 2EDTA system. Colloids and Surfaces 136 (1998) 311-319
59. Köster H.M., Kohler E.E., Krahl J., Kröger J., and Vogt K. Veränderungen am Montmorillonit durch Einwirkung von 0,1 m AeDTE-Lösungen, 1 n NaCl-Lösung und 0.1 n Salzsäure. Neues Jahrbuch Mineralogische Abhandlungen 119 (1973) 83-100
60. Kraepiel A.M.L., Keller K., and Morel F.M.M. A model for metal ion adsorption on montmorillonite. Journal of Colloid and Interface Science 210 (1999) 43-54
61. Lagaly G. Characterization of clays by organic compounds. Clay Minerals 16 (1981) 1-21
62. Lagaly G. Layer charge determination by alkylammonium ions. In: Mermut A.R. (Ed). Layer Charge Characteristics of 2:1 Silicate Clay Minerals. CMS Workshop Lectures, vol. 6 (1994), The Clay Minerals Society, Boulder, CO 1-46
63. Laudelout H., van Bladel R., Bolt G.H., and Page A.L. Thermodynamics of heterovalent cation exchange reactions in a montmorillonite clay. Transactions of the Faraday Society 64 (1968) 1477-1488
64. Mackenzie R.C. A micromethod for determination of cation exchange capacity of clay. Journal of Colloid Science 6 (1951) 219-221
65. Maes A., and Cremers A. Charge density effects in ion exchange, part I-heterovalent exchange equilibria. Journal of the Chemical Society, Faraday Transactions I 73 (1977) 1807-1814
66. Maes A., Rasquin E., and Cremers A. Thermodynamic study of the influence of complexation on exchange equilibria in Wyoming bentonite clay. Journal of the Chemical Society, Faraday Transactions I 78 (1982) 2041-2049
67. Maes A., Verheyden D., and Cremers A. Formation of highly selective cesium-exchange sites in montmorillonite. Clays and Clay Minerals 33 (1985) 251-257
68. Malcolm R.L., and Kennedy V.C. Rate of cation exchange on clay minerals as determined by specific ion electrode techniques. Soil Science Society of America Proceedings 33 (1969) 247-253
69. Manning B.A., and Goldberg S. Modeling arsenate competitive adsorption on kaolinite, montmorillonite and illite. Clays and Clay Minerals 44 (1996) 609-623
70. Mantin, I., 1969. Mesure des capacités d'échange par l'éthylene diamine et les ions complexes de l'éthylène. Comptes Rendus de l′Académie des Sciences, Paris, vol. 269, pp. 815-818.
71. Mantin I., and Glaeser R. Fixation des ions cobaltihexamines par les montmorillonites acides. Bulletin du Groupe Français des Argiles 12 (1960) 83-88
72. Margulies L., Rozen H., and Nir S. Model for competitive adsorption of organic cations on clays. Clays and Clay Minerals 36 (1988) b270-b276
73. Martin H., and Laudelout H. Thermodynamique de l′échange des cations alcalins dans les argiles. Journal de Chimie Physique (1963) 1086-1099
74. + exchange on clays. Clays and Clay Minerals 27 (1979) 417-422
75. Meier L., and Kahr G. Determination of cation exchange capacity (CEC) of clay minerals using the complexes of copper (II) ion with triethylenetetramine and tetraethylenepentamine. Clays and Clay Minerals 47 (1999) 386-388
76. Mortland M.M., and Mellor J.L. Conductimetric titration of soils for cation exchange capacity. Soil Science Society of America Proceedings 18 (1954) 363-364
77. Muljadi D., Posner A.M., and Quirk J.P. The mechanism of phosphate adsorption by kaolinite, gibbsite, and pseudoboehmite. Part I. The isotherms and the effect of pH on adsorption. Journal of Soil Science 17 (1966) 212-229
78. Muljadi D., Posner A.M., and Quirk J.P. The mechanism of phosphate adsorption by kaolinite, gibbsite, and pseudoboehmite. Part II. The location of the adsorption sites. Journal of Soil Science 17 (1966) 230-237
79. Muljadi D., Posner A.M., and Quirk J.P. The mechanism of phosphate adsorption by kaolinite, gibbsite, and pseudoboehmite. Part III. The effect of temperature on adsorption. Journal of Soil Science 17 (1966) 238-247
80. Nagy N.M., and Kónya J. The interfacial processes between calcium-bentonite and zinc ion. Colloids and Surfaces 32 (1988) 223-235
81. Nir S., Hirsch D., Navrot J., and Banin A. Specific adsorption of lithium, sodium, potassium, and strontium to montmorillonite: observations and predictions. Soil Science Society of America Journal 50 (1986) 40-45
82. Nir S., Rytwo G., Yermiyahu U., and Margulies L. A model for cation adsorption to clays and membranes. Colloid and Polymer Science 272 (1994) 619-632
83. Parfitt R.L. Anion adsorption by soils and soil materials. Advances in Agronomy 30 (1978) 1-50
84. Peech M. Determination of exchangeable cations and exchange capacity of soils. Soil Science 59 (1945) 25
85. Pleysier J., Janssens J., and Cremers A. A clay suspension stability end point titration method for measuring cation exchange capacity of soils. Soil Science Society of America Journal 50 (1986) 887-891
86. Pleysier J., and Juo A.S.R. A single extraction method using silver-thiourea for measuring exchangeable cations and effective CEC in soils with variable charges. Soil Science 129 (1980) 205-211
87. Quirk J.P. The significance of the threshold and turbidity concentrations in relation to sodicity and microstructure. Australian Journal of Soil Research 39 (2001) 1185-1217
88. Rao K.P.C., and Krishna Murti G.S.R. Influence of noncrystalline material on phosphate adsorption by kaolin and bentonite clays. In: Schultz L.G., van Olphen H., and Mumpton F.A. (Eds). Proceedings of the International Clay Conference, Denver 1985 (1987), The Clay Minerals Society, Bloomington, IN 179-185
89. Reichenbach H., and Graf von. Exchange equilibria of interlayer cations in different particle size fractions of biotite and phlogopite. In: Serratosa J.M. (Ed). Proceedings of the International Clay Conference, Madrid 1972 (1973), Division de Ciencias, CSIC, Madrid 457-466
90. Reichenbach H., Graf von, and Rich C.I. Potassium release from muscovite as influenced by particle size. Clays and Clay Minerals 17 (1969) 23-29
91. Rhodes C.N., and Brown D.R. Rapid determination of the cation exchange capacity of clays using Co(II). Clay Minerals 29 (1994) 799-801
92. Rytwo G., Banin A., and Nir S. Exchange reactions in the Ca-Mg-Na- montmorillonite system. Clays and Clay Minerals 44 (1996) 276-285
93. Rytwo G., Serban C., Nir S., and Margulies L. Use of methylene blue and crystal violet for the determination of exchangeable cations in montmorillonite. Clays and Clay Minerals 39 (1991) 551-555
94. Sawhney B.L. Selective sorption and fixation of cations by clay minerals: a review. Clays and Clay Minerals 20 (1972) 93-100
95. Schlegel M.L., Charlet L., and Manceau A. Sorption of metal ions on clay minerals II. Mechanism of Co sorption on hectorite at high and low ionic strength and impact on the sorbent stability. Journal of Colloid and Interface Science 220 (1999) 392-405
96. Schlegel M.L., Manceau A., Chateigner D., and Charlet L. Sorption of metal ions on clay minerals I. Polarized EXAFS evidence for the adsorption of Co on the edges of hectorite particles. Journal of Colloid and Interface Science 215 (1999) 140-158
97. Schofield R.K., and Samson H.R. Flocculation of kaolinite due to the attraction of oppositely charge crystal faces. Discussions of the Faraday Society 18 (1954) 135-145
98. Schwertmann U. Die selektive Kationenadsorption der Tonfraktion einiger Böden aus Sedimenten. Zeitschrift für Pflanzenernährung und Bodenkunde 97 (1962) 9-25
99. Scott A.D., Ismail F.T., and Locaties R.R. Changes in interlayer potassium exchangeability induced by heating micas. In: Serratosa J.M. (Ed). Proceedings of the International Clay Conference, Madrid, 1972 (1973), Division de Ciencias, CSIC, Madrid 467-479
100. Searle P.L. The measurement of soil cation exchange properties using the single extraction, silver thiourea method: an evaluation using a range of New Zealand soils. Australian Journal of Soil Research 24 (1986) 193-200
101. Shainberg I., Alperovitch N.I., and Keren R. Charge density and Na-K-Ca exchange on smectites. Clays and Clay Minerals 35 (1987) 68-73
102. Siantar D., and Fripiat J.J. Lead retention and complexation in a magnesium smectite (hectorite). Journal of Colloid and Interface Science 169 (1995) 400-407
103. 137Cs on montmorillonite and illite: effect of charge compensating cation, ionic strength, concentration of Cs, K and fulvic acid. Clays and Clay Minerals 45 (1997) 251-260
104. Strawn D., and Sparks D.L. The use of XAFS to distinguish between inner- and outer-sphere lead adsorption complexes on montmorillonite. Journal of Colloid and Interface Science 216 (1999) 257-269
105. Theng B.K.G., Greenland D.J., and Quirk J.P. Adsorption of alkylammonium cations by montmorillonite. Clay Minerals 7 (1967) 1-17
106. Theng B.K.G., Russell M., Churchman G.J., and Parfitt R.L. Surface properties of allophane, halloysite, and imogolite. Clays and Clay Minerals 30 (1982) 143-149
107. Thomson H.S. On the adsorbent power of soils. Journal of the Royal Agricultural Society of England 11 (1850) 68-74
108. Tournassat C., Ferrage E., Poinsignon C., and Charlet L. The titration of clay minerals II. Structure-based model and implications for clay reactivity. Journal of Colloid and Interface Science 273 (2004) 234-246
109. van Bemmelen J.M. Über die Absorptionsverbindungen und das Absorptionsvermögen der Ackererde. Landwirtschaftliche Versuchsstation 35 (1888) 69-136
110. van Olphen H. A tentative method for determination of the base exchange capacity of small samples of clay minerals. Clay Minerals Bulletin 1 (1951) 169-170
111. van Olphen H. Rheological phenomena of clay sols in connection with the charge distribution on the micelles (sic!). Discussions of the Faraday Society 11 (1951) 82-84
112. van Olphen H. An Introduction to Clay Colloid Chemistry. 2nd edition (1977), Wiley, New York
113. van Olphen H., and Fripiat J.J. Data Handbook for Clay Materials and other Non-metallic Minerals (1979), Pergamon Press, Oxford
114. Verburg K., and Baveye P. Hysteresis in the binary exchange of cations on 2:1 clay minerals: a critical review. Clays and Clay Minerals 42 (1994) 207-220
115. Violante A., and Pigna M. Competitive sorption of arsenate and phosphate on different clay minerals and soils. Soil Science Society of America Journal 66 (2002) 1788-1796
116. Way J.T. On the power of soils to absorp (sic!) manure. Journal of the Royal Agricultural Society of England 13 (1852) 123-143
117. Weiss A. Über das Kationenaustauschvermögen der Tonminerale. I. Vergleich der Untersuchungsmethoden. Zeitschrift für Anorganische und Allgemeine Chemie 297 (1958) 232-256
118. Weiss A. Über das Kationenaustauschvermögen der Tonminerale. II. Kationenaustausch bei den Mineralen der Glimmer-, Vermiculit- und Montmorillonitgruppe. Zeitschrift für Anorganische und Allgemeine Chemie 297 (1958) 257-286
119. Weiss A. Über äquimolaren Kationenaustausch bei niedrig geladenen Ionenaustauschern. Kolloid-Zeitschrift 158 (1958) 22-28
120. Weiss A., Mehler A., Koch G., and Hofmann U. Über das Anionenaustauschvermögen der Tonminerale. Zeitschrift für Anorganische und Allgemeine Chemie 284 (1956) 247-271
121. Wendelbo R., and Rosenqvist I.T. Effects of anion adsorption on mechanical properties of clay-water sytems. In: Schultz L.G., van Olphen H., and Mumpton F.A. (Eds). Proceedings of the International Clay Conference, Denver 1985 (1987), The Clay Minerals Society, Bloomington, IN 422-426
122. Xu S., and Harsh J.B. Alkali cation selectivity and surface charge of 2.1 clay minerals. Clays and Clay Minerals 40 (1992) 567-574