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Volumn 108, Issue 40, 2004, Pages 8333-8340

Drastic changes in the lifetime and electron transfer and energy transfer reactivity of the triplet excited state of p-benzoquinone by complex formation with scandium ion salts

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; CHEMICAL REACTIONS; COMPLEXATION; CONCENTRATION (PROCESS); ELECTRIC EXCITATION; ENERGY TRANSFER; IONS; PHOSPHORESCENCE; PHOTOLYSIS; REACTION KINETICS;

EID: 6444238213     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp047748e     Document Type: Article
Times cited : (6)

References (92)
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    • For examples of metal ions involved in excimer formation, see: (a) Xu, F. B.; Li, Q. S.; Wu, L. Z.; Leng, X. B.; Li, Z. C.; Zeng, X. S.; Chow, Y. L.; Zhang, Z. Z. Organometallics 2003, 22, 633. (b) Xin, H.; Guang, M.; Li, F. Y.; Bian, Z. Q.; Huang, C. H.; Ibrahim, K.; Liu, F. Q. Phys. Chem. Chem. Phys. 2002, 4, 5895. Burshtein, A. I. J. Chem. Phys. 2002, 117, 7640. Hicks, C.; Ye, G.; Levi, C.; Gonzales, M.; Rutenburg, I.; Fan, J.; Helmy, R.; Kassis, A.; Gafney, H. D. Coord. Chem. Rev. 2001, 207.
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    • The lifetime of the singlet excited state of p-benzoquinone derivatives such as p-chloranil is reported to be extremely short (8 ps). See: (a) Rathore, R.; Hubig, S. M.; Kochi, J. K. J. Am. Chem. Soc. 1997, 119, 11468.(b) Hubig, S. M.; Bookman, T. M.; Kochi, J. K. J. Am. Chem. Soc. 1997, 119, 2926.
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    • The lifetime of the singlet excited state of p-benzoquinone derivatives such as p-chloranil is reported to be extremely short (8 ps). See: (a) Rathore, R.; Hubig, S. M.; Kochi, J. K. J. Am. Chem. Soc. 1997, 119, 11468.(b) Hubig, S. M.; Bookman, T. M.; Kochi, J. K. J. Am. Chem. Soc. 1997, 119, 2926.
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    • note
    • 3 is destabilized due to the desolvation associated with the complex formation.
  • 74
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    • note
    • 3 in the ground state.
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    • note
    • 45
  • 79
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    • max = 465 nm. See: (a) Zhang, G.; Thomas, J. K. J. Phys. Chem. B 2003, 107, 7254.(b) Dreyer, J.; Peters, K. S. J. Phys. Chem. 1996, 100, 19412.
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    • max = 465 nm. See: (a) Zhang, G.; Thomas, J. K. J. Phys. Chem. B 2003, 107, 7254.(b) Dreyer, J.; Peters, K. S. J. Phys. Chem. 1996, 100, 19412.
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    • note
    • 3 complex because of the faster electron transfer rate of the former, although no product of electron transfer can be seen due to the endothermicity of electron transfer in both cases (Supporting Information Figure S4).
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