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64349086095
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We also examined other biphenyl-based phosphine ligands, such as S-Phos, Ru-Phos, and Dm-Phos with the reaction of 1k; however, better results were not obtained Table 2, entry 13
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We also examined other biphenyl-based phosphine ligands, such as S-Phos, Ru-Phos, and Dm-Phos with the reaction of 1k; however, better results were not obtained (Table 2, entry 13).
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20
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64349117651
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1H) -quinolinone was generated when the reaction of 1j or 1p was quenched with water.
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1H) -quinolinone was generated when the reaction of 1j or 1p was quenched with water.
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21
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48849113342
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(a) Watanabe, T.; Oishi, S.; Fujii, N.; Ohno, H. Org. Lett. 2008, 10, 1759.
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0037433240
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This rearrangement is considered to be a heteroanalogue of a cyclopropylcarbinylpalladium to homoallylpalladium sigma complex transformation. For cyclopropylmethylpalladium to homoallylpalladium rearrangements, see: (a) Zhao, L, de Meijere, A. Adv. Synth. Catal. 2006, 248, 2484
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This rearrangement is considered to be a heteroanalogue of a cyclopropylcarbinylpalladium to homoallylpalladium sigma complex transformation. For cyclopropylmethylpalladium to homoallylpalladium rearrangements, see: (a) Zhao, L.; de Meijere, A. Adv. Synth. Catal. 2006, 248, 2484.
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25
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0037123792
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(b) Nüske, H.; Bräse, S.; Kozhushkov, S. I.; Noltemeyer, M; Es-Sayed, M.; de Meijere, A. Chem.-Eur. J. 2002, 8, 2350.
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de Meijere, A.6
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32144431909
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A similar type of this palladium-catalyzed intramolecular N-arylation was reported by Junjappa: Venkatesh, C.; Sundaram, G. S. M.; Ha, H.; Junjappa, H. J. Org. Chem. 2006, 71, 1280.
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A similar type of this palladium-catalyzed intramolecular N-arylation was reported by Junjappa: Venkatesh, C.; Sundaram, G. S. M.; Ha, H.; Junjappa, H. J. Org. Chem. 2006, 71, 1280.
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