On the mechanism of nitrosoarene-alkyne cycloaddition

Journal of the American Chemical Society

Volumn 131, Issue 2, 2009, Pages 653-661

  Penoni, Andrea ^a   Palmisano, Giovanni ^a   Zhao, Yi Lei ^b,c   Houk, Kendall N ^c   Volkman, Jerome ^d   Nicholas, Kenneth M ^a  

^a UNIVERSITY OF INSUBRIA   (Italy)

^b SHANGHAI JIAO TONG UNIVERSITY   (China)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d UNIVERSITY OF OKLAHOMA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; ARYLALKYNES; BOND FORMATION; C-C BONDS; CIS-TRANS ISOMERIZATION; COMPUTATIONAL RESULTS; COMPUTATIONAL STUDIES; CYCLOPROPYL; DIRADICAL; ELECTRON-DONATING; ELECTRONWITHDRAWING; ENERGY PATHWAY; FIRST ORDER; HYDROXYINDOLES; INDOLE DERIVATIVES; KINETIC ISOTOPE EFFECTS; LOW-YIELD; NITRONE; NITROSOARENES; NITROSOBENZENE; PHENYLACETYLENES; RADICAL CLOCKS; RATE LIMITING; RATE-LIMITING STEPS; REACTION MECHANISM; SUBSTITUTED INDOLES; TAUTOMERIZATION; THERMAL REACTIONS;

ACETYLENE; ACTIVATION ENERGY; BENZENE; CARRIER MOBILITY; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ELECTRONS; GROUP TECHNOLOGY; ISOMERIZATION; ISOTOPES; LIGHTING; OPTICAL SENSORS;

REACTION RATES;

ACETYLENE; AROMATIC NITROSO COMPOUND; INDOLE DERIVATIVE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; UNCLASSIFIED DRUG; BENZENE DERIVATIVE; DRUG DERIVATIVE; NITROSO DERIVATIVE; NITROSOBENZENE; PHENYLACETYLENE;

ARTICLE; CHEMICAL REACTION; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ISOMERIZATION; KINETICS; MATHEMATICAL COMPUTING; CHEMISTRY; CYCLIZATION; SYNTHESIS; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

ACETYLENE; BENZENE DERIVATIVES; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; INDOLES; KINETICS; NITROSO COMPOUNDS; THERMODYNAMICS;

EID: 62849106956     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja806715u     Document Type: Article

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