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Volumn 6, Issue 5, 2004, Pages 743-746

Theoretical evidence for oxygenated intermediates in the reductive cyclization of nitrobenzenes

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC NITRO COMPOUND; BIPHENYL DERIVATIVE; NITROBENZENE DERIVATIVE; NITROGEN DERIVATIVE; STILBENE DERIVATIVE; STYRENE DERIVATIVE;

EID: 1642370535     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0364273     Document Type: Article
Times cited : (82)

References (34)
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    • A significant study of the chemistry of biphenylnitrenes by laser flash photolysis, time-resolved IR, and by B3LYP and CASPT2 calculations has recently been published. The mechanism of cyclization proceeds via an open shell structure with essentially diradical character to form isocarbazole and a 1,5-hydrogen shift to form carbazole. Tsao, M.-L.; Gristan, N.; James, T. R.; Plattz, M. S.; Hrovat, D. A.; Borden, W. T. J. Am. Chem. Soc. 2003, 125, 9343.
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 9343
    • Tsao, M.-L.1    Gristan, N.2    James, T.R.3    Plattz, M.S.4    Hrovat, D.A.5    Borden, W.T.6
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    • Cadogan, J.I.G.1    Mackie, R.K.2
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    • Isomerization is solvent dependent. In DMF, the equilibrium is 100% 8, whereas in MeOH, the equilibrium is 100% 7. Nagayoshi, T.; Saeki, S.; Hamana, M. Chem. Pharm. Bull. 1981, 29, 1827.
    • (1981) Chem. Pharm. Bull. , vol.29 , pp. 1827
    • Nagayoshi, T.1    Saeki, S.2    Hamana, M.3
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    • George, M. V.; Mitra, A.; Sukurmaran, K. B. Angew. Chem. 1980, 92, 1005. K. B. Taylor, E. C.; Turchi, I. J. Chem. Rev. 1979, 79, 181. Huisgen, R.; Fukushima, K.; Ibata, T. Heterocycles 1995, 40, 149.
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    • George, M. V.; Mitra, A.; Sukurmaran, K. B. Angew. Chem. 1980, 92, 1005. K. B. Taylor, E. C.; Turchi, I. J. Chem. Rev. 1979, 79, 181. Huisgen, R.; Fukushima, K.; Ibata, T. Heterocycles 1995, 40, 149.
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    • George, M. V.; Mitra, A.; Sukurmaran, K. B. Angew. Chem. 1980, 92, 1005. K. B. Taylor, E. C.; Turchi, I. J. Chem. Rev. 1979, 79, 181. Huisgen, R.; Fukushima, K.; Ibata, T. Heterocycles 1995, 40, 149.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.