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Mori, M.1
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Examples containing the putative alkynyl Ru-alkylidene intermediates: (a) van Otterlo. W. A. L.; Ngidi. E. L.; de Koning, C. B.; Fernandes, M. A. Tetrahedron Lett. 2004, 45, 659.
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A review of metallotropic shift: Kim. M.; Lee, D. Org. Biomol. Chem. 2007, 5, 3418.
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24
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67849113621
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See Supporting Information for details
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See Supporting Information for details.
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-
-
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25
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0035802146
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For a stoichiometric reaction of 4b and diphenvl-l,3-divne, see: Trnka, T. M.; Day, M. W.: Grubbs, R. H. Oreanometallics 2001, 20. 3845.
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For a stoichiometric reaction of 4b and diphenvl-l,3-divne, see: Trnka, T. M.; Day, M. W.: Grubbs, R. H. Oreanometallics 2001, 20. 3845.
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26
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Marino, J.P.; Nguyen, H. N. J Org., Chem. 2002, 67, 6841.
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23844506889
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Hoveyda-complex with vinyl group at the carbonic carbon
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Hoveyda-complex with vinyl group at the carbonic carbon: Furstner, A.; Davies, P. W.; Lehmann, C. W. Organometallics 2005, 24, 4065.
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Furstner, A.1
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28
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67849103176
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This behavior compares to that of Ru-methylidene, which is known as an ultimate thermodynamic sink, see ref lb
-
This behavior compares to that of Ru-methylidene, which is known as an ultimate thermodynamic sink, see ref lb.
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-
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29
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0001354464
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This result is in line with the lack of RCM reactivity of silyl substituted alkvnes. see: (a) Kim. S.-H, Zeurcher. W. J, Bowden, N. B, Grubbs, R. H. J. Org. Chem. 1996, 61, 1073
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This result is in line with the lack of RCM reactivity of silyl substituted alkvnes. see: (a) Kim. S.-H.: Zeurcher. W. J.; Bowden, N. B.; Grubbs, R. H. J. Org. Chem. 1996, 61, 1073.
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30
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