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note
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The origin of the low overall chemical yields for the longer homologues is not clear. However, on the basis of the appearance of a polar baseline material on the TLC even at the early stage of the reaction, we believe the starting material polymerizes under the reaction conditions.
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37
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29844434522
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note
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Although ethylene was found to be deleterious for the RCM of substrate 2a, it was used to minimize the formation of dimeric product 6a.
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38
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29844435573
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note
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Compound 5a contains roughly 5% of styryl-group-incorporated product.
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39
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0001721833
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Putative intermediates in the metaHotropic [1,3]-shift should have close analogy to the dehydrotungstenacyclobutadiene: McCullough, L. G.; Listemann, M. L.; Schrock, R. R.; Churchill, M. R.; Ziller, J. W. J. Am. Chem. Soc. 1983, 105, 6729.
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