Spectroscopic and computational studies of nitrite reductase: Proton induced electron transfer and backbonding contributions to reactivity

Journal of the American Chemical Society

Volumn 131, Issue 1, 2009, Pages 277-288

  Ghosh, Somdatta ^a   Dey, Abhishek ^a   Sun, Yan ^b   Scholes, Charles P ^b   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b STATE UNIVERSITY OF NEW YORK   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION REACTIONS; COPPER; ELECTRON TRANSITIONS; ELECTRONIC STRUCTURE; PROBABILITY DENSITY FUNCTION; PROTONS; SULFUR COMPOUNDS;

BACK-BONDING; BOND CLEAVAGES; COMPUTATIONAL STUDIES; COPPER SITES; DFT CALCULATION; ELECTRON TRANSFER; HIGH PH; NITRITE REDUCTASE; NITRITE REDUCTION; REACTION COORDINATES; REDUCTIVE CLEAVAGE; RHODOBACTER SPHAEROIDES;

PROTON TRANSFER;

COPPER; NITRIC OXIDE; NITRITE; NITRITE REDUCTASE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; NONHUMAN; PH; PROTON TRANSPORT; RHODOBACTER SPHAEROIDES; SPECTROSCOPY; CHEMICAL MODEL; CHEMISTRY; CIRCULAR DICHROISM; ELECTRON; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYMOLOGY; METABOLISM; PROTEIN CONFORMATION; ULTRAVIOLET SPECTROPHOTOMETRY;

CATALYTIC DOMAIN; CIRCULAR DICHROISM; COPPER; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; HYDROGEN-ION CONCENTRATION; MODELS, CHEMICAL; MODELS, MOLECULAR; NITRITE REDUCTASES; NITRITES; PROTEIN CONFORMATION; RHODOBACTER SPHAEROIDES; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 62649090829     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja806873e     Document Type: Article

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