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Volumn 46, Issue 10, 2007, Pages 3916-3933

Synthesis and spectroscopic characterization of copper(II)-nitrito complexes with hydrotris(pyrazolyl)borate and related coligands

Author keywords

[No Author keywords available]

Indexed keywords

BORIC ACID; COPPER; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; HYDROTRIS(PYRAZOLYL)BORATE; LIGAND; NITRITE; PYRAZOLE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 34249705142     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0619355     Document Type: Article
Times cited : (93)

References (57)
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    • This coordination geometry is supported by the structural parameter τ; τ, α, β/60°, where α and β are the largest angles (α > β) around a five-coordinate metal center. The parameter τ is equal to 0 for an ideal square-planar geometry, while for a perfect trigonal-bipyramidal geometry it becomes 1. Addison, A. W, Rao, T. N, Reedijk, J, van Rijn, J, Verschoor, G. C. J. Chem. Soc, Dalton Trans. 1984, 1349
    • This coordination geometry is supported by the structural parameter τ; τ = (α - β)/60°, where α and β are the largest angles (α > β) around a five-coordinate metal center. The parameter τ is equal to 0 for an ideal square-planar geometry, while for a perfect trigonal-bipyramidal geometry it becomes 1. Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349.
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    • For, purely inorganic compounds, see, for example
    • (b) For, purely inorganic compounds, see, for example: Klanderman, K. A.; Hamilton, W. C.; Bernal, I. Inorg. Chim. Acta 1977, 23, 117-129.
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    • x2-y2 ground state for this coordination geometry.
    • x2-y2 ground state for this coordination geometry.
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    • We have not obtained any charged complexes such as [Cu(L1 or L3)(ONO)(NO2, or [Cu(L1′)(ONO, in this reaction. Therefore, using charged ligands is a very useful strategy for controlling the coordination number of a rather weak ligand in a transition metal complex using nonpolar solvents
    • + in this reaction. Therefore, using charged ligands is a very useful strategy for controlling the coordination number of a rather weak ligand in a transition metal complex (using nonpolar solvents).


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