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This coordination geometry is supported by the structural parameter τ; τ, α, β/60°, where α and β are the largest angles (α > β) around a five-coordinate metal center. The parameter τ is equal to 0 for an ideal square-planar geometry, while for a perfect trigonal-bipyramidal geometry it becomes 1. Addison, A. W, Rao, T. N, Reedijk, J, van Rijn, J, Verschoor, G. C. J. Chem. Soc, Dalton Trans. 1984, 1349
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x2-y2 ground state for this coordination geometry.
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We have not obtained any charged complexes such as [Cu(L1 or L3)(ONO)(NO2, or [Cu(L1′)(ONO, in this reaction. Therefore, using charged ligands is a very useful strategy for controlling the coordination number of a rather weak ligand in a transition metal complex using nonpolar solvents
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+ in this reaction. Therefore, using charged ligands is a very useful strategy for controlling the coordination number of a rather weak ligand in a transition metal complex (using nonpolar solvents).
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